A roomerature sodium rechargeable battery using an so 2 -based nonflammable inorganic liquid catholyte

Scientific Reports

Volumn 5, Issue , 2015, Pages

  Jeong, Goojin ^a   Kim, Hansu ^b   Sug Lee, Hyo ^c   Han, Young Kyu ^d   Hwan Park, Jong ^a,e   Hwan Jeon, Jae ^a,b   Song, Juhye ^a,b   Lee, Keonjoon ^d   Yim, Taeeun ^a   Jae Kim, Ki ^a   Lee, Hyukjae ^e   Kim, Young Jun ^a   Sohn, Hun Joon ^f  

^a Korea Electronic Technology Institute (KETI)   (South Korea)

^b Hanyang University   (South Korea)

^c Samsung Advanced Institute of Technology (SAIT)   (South Korea)

^d Dongguk University   (South Korea)

^e Andong National University   (South Korea)

^f Seoul National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84938911661     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep12827     Document Type: Article

References (31)

1. Slater, M. D., Kim, D., Lee, E. & Johnson, C. S. Sodium-ion batteries. Adv. Funct. Mater. 23, 947-958 (2013).
2. Palomares, V. et al. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 5, 5884-5901 (2012).
3. Ellis, B. L. & Nazar, L. F. Sodium and sodium-ion energy storage batteries. Curr. Opin. Solid State Mater. Sci. 16, 168-177 (2012).
4. Hueso, K. B., Armand, M. & Rojo, T. High temperature sodium batteries: Status, challenges and future trends. Energy Environ. Sci. 6, 734-749 (2013).
5. Palomares, V., Casas-Cabanas, M., Castillo-Martinez, E., Han, M. H. & Rojo, T. Update on Na-based battery materials: A growing research path. Energy Environ. Sci. 6, 2312-2337 (2013).
6. Hartmann, P. et al. A rechargeable room-temperature sodium superoxide (NaO2) battery. Nat. Mater. 12, 228-232 (2013).
7. Yabuuchi, N. et al. P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries. Nat. Mater. 11, 512-517 (2012).
8. Song, J. et al. Chemically bonded phosphorus/graphene hybrid as a high performance anode for sodium-ion batteries. Nano Lett. 14, 6329-6335 (2014).
9. Fey, G. T.-K. Li/SO2 rechargeable batteries. J. Power Sources 35, 153-162 (1991).
10. Schlaikjer, C. R. Liquid cathode primary batteries. J. Power Sources 14, 111-122 (1985).
11. Xing, H. C. et al. Ambient lithium-SO2 batteries with ionic liquids as electrolytes. Angew. Chem. Int. Ed. 53, 2099-2103 (2014).
12. Dey, A. N., Kuo, H. C., Piliero, P. & Kallianidis, M. Inorganic electrolyte Li/SO2 rechargeable system: Development of a prototype hermetic C cell and evaluation of its performance and safety characteristics. J. Electrochem. Soc. 135, 2115-2120 (1988).
13. Hill, I. R., Anderson, B. G., Goledzinowski, M. & Dore, R. J. Investigations of the chemistry of rechargeable Li/SO2 cells containing tetrachlorometallate: SO2 electrolytes. J. Electrochem. Soc. 142, 3267-3273 (1995).
14. Mammone, R. J. & Binder, M. Electrochemical characterization of LiAlCl4-SO2 electrolyte. J. Electrochem. Soc. 133, 1312-1315 (1986).
15. Goledzinowski, M., Dore, R. J. & Hill, I. R. Cyclic voltammetric and Raman spectroscopic studies of the Li/LiAlCl4/SO2 and Li/LiGaCl4/SO2 rechargeable systems. J. Power Sources 54, 356-361 (1995).
16. Hossain, S., Harris, P., McDonald, R. & Goebel, F. Performance of lithium-sulfur dioxide rechargeable cells. Proceedings of the 34th International Power Sources Symposium, New Jersey, the Hyatt Cherry Hill, IEEE Industry Applications Society, 185-190 (1990, June 25-28).
17. Foster, D. L., Kuo, H. C., Schlaikjer, C. R. & Dey, A. N. New highly conductive inorganic electrolytes. J. Electrochem. Soc. 135, 2682-2686 (1988).
18. Hartl, R., Neueder, R. & Gores, H. J. Temperature dependence of association constants of LiAlCl4 in liquid sulfur dioxide. Acta Chim. Slov. 56, 109-114 (2009).
19. Brandt, K. Historical development of secondary lithium batteries. Solid State Ionics 69, 173-183 (1994).
20. Mews, R., Lork, E., Watson, P. G. & Gortler, B. Coordination chemistry in and of sulfur dioxide. Coord. Chem. Rev. 197, 277-320 (2000).
21. Kühnl, Von H. & Strumpf, A. Als akkumulator verwendbares galvanisches element. German Patent No. 2, 140, 146 (1973).
22. Kühnl, Von H., Strumpf, A. & Gladziwa, M. Die systeme des typs MCl/AlCl3/SO2 (M = Li, Na, K, NH4). Z. Anorg. Allg. Chem. 449, 145-156 (1979).
23. Liu, Y.-C. et al. The discharge rate capability of rechargeable Li? O2 batteries. Energy Environ. Sci. 4, 2999-3007 (2011).
24. Girishkumar, G., McCloskey, B., Luntz, A. C., Swanson, S. & Wilcke, W. Lithium? air battery: Promise and challenges. J. Phys. Chem. Lett. 1, 2193-2203 (2010).
25. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J.-M. Li? O2 and Li? S batteries with high energy storage. Nat. Mater. 11, 19-29 (2012).
26. Sun, Q., Yang, Y. & Fu, Z.-W. Electrochemical properties of room temperature sodium? air batteries with non-aqueous electrolyte. Electrochem. Commun. 16, 22-25 (2012).
27. Dey, A. N. et al. Inorganic electrolyte Li/CuCl2 rechargeable cell. J. Electrochem. Soc. 136, 1618-1621 (1989).
28. Lee, S.-B., Pyun, S.-I. & Lee, E.-J. Effect of the compactness of the lithium chloride layer formed on the carbon cathode on the electrochemical reduction of SOCl2 electrolyte in Li-SOCl2 batteries. Electrochim. Acta 47, 855-864 (2001).
29. Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169-11186 (1996).
30. Blöchl, P. Projector augmented-wave method. Phys. Rev. B 50, 17953-17979 (1994).
31. Perdew, J. P., Ernzerhof, M. & Burke, K. Rationale for mixing exact exchange with density functional approximations. J. Chem. Phys. 105, 9982-9985 (1996).