Surface Chemistry of "unprotected" Nanoparticles: A Spectroscopic Investigation on Colloidal Particles

Journal of Physical Chemistry C

Volumn 119, Issue 31, 2015, Pages 17655-17661

  Schrader, Imke ^a   Warneke, Jonas ^a   Neumann, Sarah ^a   Grotheer, Sarah ^a   Swane, Andreas Abildgaard ^b   Kirkensgaard, Jacob J K ^c   Arenz, Matthias ^b   Kunz, Sebastian ^a  

^a UNIVERSITY OF BREMEN   (Germany)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBATES; ALKALINITY; ETHYLENE; ETHYLENE GLYCOL; NANOPARTICLES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARTICLE SIZE; PARTICLE SIZE ANALYSIS; SIZE DISTRIBUTION; SPACECRAFT INSTRUMENTS; SURFACE CHEMISTRY;

COLLOIDAL NANOPARTICLES; COLLOIDAL PARTICLE; FUNCTIONALIZED NANOPARTICLES; NAOH CONCENTRATION; PARTICLE DIAMETERS; PRECURSOR SOLUTIONS; SPECTROSCOPIC CHARACTERIZATION; SPECTROSCOPIC INVESTIGATIONS;

COLLOIDS;

EID: 84938723602     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b03863     Document Type: Article

References (32)

1. Xia, Y. N.; Xiong, Y. J.; Lim, B.; Skrabalak, S. E. Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Angew. Chem., Int. Ed. 2009, 48, 60-103 10.1002/anie.200802248
2. Park, J.; Joo, J.; Kwon, S. G.; Jang, Y.; Hyeon, T. Synthesis of Monodisperse Spherical Nanocrystals Angew. Chem., Int. Ed. 2007, 46, 4630-4660 10.1002/anie.200603148
3. Toshima, N.; Yonezawa, T. Bimetallic Nanoparticles-Novel Materials for Chemical and Physical Applications New J. Chem. 1998, 22, 1179-1201 10.1039/a805753b
4. Zhang, Y. W.; Grass, M. E.; Kuhn, J. N.; Tao, F.; Habas, S. E.; Huang, W. Y.; Yang, P. D.; Somorjai, G. A. Highly Selective Synthesis of Cataytically Active Monodisperse Rhodium Nanocubes J. Am. Chem. Soc. 2008, 130, 5868-5869 10.1021/ja801210s
5. Huang, W. X.; Hua, Q.; Cao, T. Influence and Removal of Capping Ligands on Catalytic Colloidal Nanoparticles Catal. Lett. 2014, 144, 1355-1369 10.1007/s10562-014-1306-5
6. Kunz, S.; Iglesia, E. Mechanistic Evidence for Sequential Displacement-Reduction Routes in the Synthesis of Pd-Au Clusters with Uniform Size and Clean Surfaces J. Phys. Chem. C 2014, 118, 7468-7479 10.1021/jp500537v
7. Fievet, F.; Lagier, J. P.; Blin, B.; Beaudoin, B.; Figlarz, M. Homogeneous and Heterogeneous Nucleations in the Polyol Process for the Preparation of Micron and Submicron Size Metal Particles Solid State Ionics 1989, 32-33, 198-205 10.1016/0167-2738(89)90222-1
8. Wang, Y.; Ren, J. W.; Deng, K.; Gui, L. L.; Tang, Y. Q. Preparation of Tractable Platinum, Rhodium, and Ruthenium Nanoclusters with Small Particle Size in Organic Media Chem. Mater. 2000, 12, 1622-1627 10.1021/cm0000853
9. Wang, X. D.; Stover, J.; Zielasek, V.; Altmann, L.; Thiel, K.; Al-Shamery, K.; Baumer, M.; Borchert, H.; Parisi, J.; Kolny-Olesiak, J. Colloidal Synthesis and Structural Control of Ptsn Bimetallic Nanoparticles Langmuir 2011, 27, 11052-11061 10.1021/la201829y
10. Fu, X. Y.; Wang, Y.; Wu, N. Z.; Gui, L. L.; Tang, Y. Q. Surface Modification of Small Platinum Nanoclusters with Alkylamine and Alkylthiol: An Xps Study on the Influence of Organic Ligands on the Pt 4f Binding Energies of Small Platinum Nanoclusters J. Colloid Interface Sci. 2001, 243, 326-330 10.1006/jcis.2001.7861
11. Wang, X.; Sonstrom, P.; Arndt, D.; Stover, J.; Zielasek, V.; Borchert, H.; Thiel, K.; Al-Shamery, K.; Baumer, M. Heterogeneous Catalysis with Supported Platinum Colloids: A Systematic Study of the Interplay between Support and Functional Ligands J. Catal. 2011, 278, 143-152 10.1016/j.jcat.2010.11.020
12. Speder, J.; Altmann, L.; Roefzaad, M.; Baeumer, M.; Kirkensgaard, J. J. K.; Mortensen, K.; Arenz, M. Pt Based Pemfc Catalysts Prepared from Colloidal Particle Suspensions-a Toolbox for Model Studies Phys. Chem. Chem. Phys. 2013, 15, 3602-3608 10.1039/c3cp50195g
13. Speder, J.; Altmann, L.; Bäumer, M.; Kirkensgaard, J. J.; Mortensen, K.; Arenz, M. The Particle Proximity Effect: From Model to High Surface Area Fuel Cell Catalysts RSC Adv. 2014, 4, 14971-14978 10.1039/c4ra00261j
14. Speder, J.; Zana, A.; Spanos, I.; Kirkensgaard, J. J. K.; Mortensen, K.; Hanzlik, M.; Arenz, M. Comparative Degradation Study of Carbon Supported Proton Exchange Membrane Fuel Cell Electrocatalysts-the Influence of the Platinum to Carbon Ratio on the Degradation Rate J. Power Sources 2014, 261, 14-22 10.1016/j.jpowsour.2014.03.039
15. Kunz, S.; Schreiber, P.; Ludwig, M.; Maturi, M. M.; Ackermann, O.; Tschurl, M.; Heiz, U. Rational Design, Characterization and Catalytic Application of Metal Clusters Functionalized with Hydrophilic, Chiral Ligands: A Proof of Principle Study Phys. Chem. Chem. Phys. 2013, 15, 19253-19261 10.1039/c3cp53626b
16. Morsbach, E.; Spéder, J.; Arenz, M.; Brauns, E.; Lang, W.; Kunz, S.; Bäumer, M. Stabilizing Catalytically Active Nanoparticles by Ligand Linking: Toward Three-Dimensional Networks with High Catalytic Surface Area Langmuir 2014, 30, 5564-5573 10.1021/la4049055
17. Ertl, G.; Küppers, J. Low Energy Electrons and Surface Chemistry; Verlag Chemie: 1983.
18. Yang, J.; Deivaraj, T. C.; Too, H. P.; Lee, J. Y. Acetate Stabilization of Metal Nanoparticles and Its Role in the Preparation of Metal Nanoparticles in Ethylene Glycol Langmuir 2004, 20, 4241-4245 10.1021/la0361159
19. Bock, C.; Paquet, C.; Couillard, M.; Botton, G. A.; MacDougall, B. R. Size-Selected Synthesis of Ptru Nano-Catalysts: Reaction and Size Control Mechanism J. Am. Chem. Soc. 2004, 126, 8028-8037 10.1021/ja0495819
20. Schrader, I.; Warneke, J.; Backenköhler, J.; Kunz, S. Functionalization of Platinum Nanoparticles with L-Proline: Simultaneous Enhancements of Catalytic Activity and Selectivity J. Am. Chem. Soc. 2015, 137, 905-912 10.1021/ja511349p
21. Hens, Z.; Martins, J. C. A Solution Nmr Toolbox for Characterizing the Surface Chemistry of Colloidal Nanocrystals Chem. Mater. 2013, 25, 1211-1221 10.1021/cm303361s
22. Wu, Z.; Gayathri, C.; Gil, R. R.; Jin, R. Probing the Structure and Charge State of Glutathione-Capped Au-25(Sg)(18) Clusters by Nmr and Mass Spectrometry J. Am. Chem. Soc. 2009, 131, 6535-6542 10.1021/ja900386s
23. Tong; Rice, C.; Godbout, N.; Wieckowski, A.; Oldfield, E. Correlation between the Knight Shift of Chemisorbed Co and the Fermi Level Local Density of States at Clean Platinum Catalyst Surfaces J. Am. Chem. Soc. 1999, 121, 2996-3003 10.1021/ja9830492
24. van der Klink, J. J.; Brom, H. B. Nmr in Metals, Metal Particles and Metal Cluster Compounds Prog. Nucl. Magn. Reson. Spectrosc. 2000, 36, 89-201 10.1016/S0079-6565(99)00020-5
25. Sexton, B. A.; Rendulic, K. D.; Huges, A. E. Decomposition Pathways of C1-C4 Alcohols Adsorbed on Platinum (111) Surf. Sci. 1982, 121, 181-198 10.1016/0039-6028(82)90245-X
26. Lee, A. F.; Gawthrope, D. E.; Hart, N. J.; Wilson, K. A Fast Xps Study of the Surface Chemistry of Ethanol over Pt {111} Surf. Sci. 2004, 548, 200-208 10.1016/j.susc.2003.11.004
27. Altmann, L.; Kunz, S.; Bäumer, M. Influence of Organic Amino and Thiol Ligands on the Geometric and Electronic Surface Properties of Colloidally Prepared Platinum Nanoparticles J. Phys. Chem. C 2014, 118, 8925-8932 10.1021/jp4116707
28. Günzler, H.; Gremlich, H. U. IR Spectroscopy: An Introduction; Wiley: New York, 2002.
29. Hoffmann, F. M. Infrared Reflection-Absorption Spectroscopy of Adsorbed Molecules Surf. Sci. Rep. 1983, 3, 107-192 10.1016/0167-5729(83)90001-8
30. Marzun, G.; Streich, C.; Jendrzej, S.; Barcikowski, S.; Wagener, P. Adsorption of Colloidal Platinum Nanoparticles to Supports: Charge Transfer and Effects of Electrostatic and Steric Interactions Langmuir 2014, 30, 11928-11936 10.1021/la502588g
31. Song, H.; Rioux, R. M.; Hoefelmeyer, J. D.; Komor, R.; Niesz, K.; Grass, M.; Yang, P. D.; Somorjai, G. A. Hydrothermal Growth of Mesoporous Sba-15 Silica in the Presence of Pvp-Stabilized Pt Nanoparticles: Synthesis, Characterization, and Catalytic Properties J. Am. Chem. Soc. 2006, 128, 3027-3037 10.1021/ja057383r
32. Park, J. Y.; Aliaga, C.; Renzas, J. R.; Lee, H.; Somorjai, G. A. The Role of Organic Capping Layers of Platinum Nanoparticles in Catalytic Activity of Co Oxidation Catal. Lett. 2009, 129, 1-6 10.1007/s10562-009-9871-8