Operando UV-visible spectroscopy evidence of the reactions of iodide as redox mediator in Li-O2 batteries

Electrochemistry Communications

Volumn 59, Issue , 2015, Pages 24-27

  Landa Medrano, I ^a   Olivares Marin M ^b   Pinedo, R ^a,d   Ruiz De Larramendi, I ^a   Rojo, T ^a,c   Tonti, D ^b  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c CIC ENERGIGUNE   (Spain)

^d JUSTUS LIEBIG UNIVERSITY   (Germany)

Author keywords

In situ monitoring; Iodide; Lithium air batteries; Redox mediator; Side reactions; UV visible spectroscopy

Indexed keywords

ELECTROLYTES; INDIUM COMPOUNDS; INFRARED SPECTROPHOTOMETERS; LITHIUM COMPOUNDS; OPEN CIRCUIT VOLTAGE; OXYGEN; REDOX REACTIONS; ULTRAVIOLET VISIBLE SPECTROSCOPY;

IN- SITU MONITORING; IODIDE; REDOX MEDIATORS; SIDE REACTIONS; UV VISIBLE SPECTROSCOPY;

LITHIUM-AIR BATTERIES;

EID: 84936943258     PISSN: 13882481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elecom.2015.06.019     Document Type: Article

References (27)

1. D. Kwabi, N. Ortiz-Vitoriano, S.A. Freunberger, Y. Chen, N. Imanishi, P.G. Bruce, and Y. Shao-Horn Materials challenges in rechargeable lithium-air batteries MRS Bull. 39 2014 443 452
2. G. Girishkumar, B. McCloskey, A.C. Luntz, S. Swanson, and W. Wilcke Lithium-air battery: promise and challenges J. Phys. Chem. Lett. 1 2010 2193 2203
3. J. Christiansen, P. Albertus, R.S. Sanchez-Carrera, T. Lohmann, B. Kozinsky, R. Liedtke, J. Ahmed, and A. Kojic A critical review of Li/air batteries J. Electrochem. Soc. 159 2012 R1 R30
4. 2 batteries Chem. Rev. 114 2014 5611 5640
5. 2 cells J. Am. Chem. Soc. 135 2012 494 500
6. Y.-C. Lu, Z. Xu, H.A. Gasteiger, S. Chen, K. Hamad-Schifferli, and Y. Shao-Horn Platinum-gold nanoparticles: a highly active bifunctional electrocatalyst for rechargeable lithium-air batteries J. Am. Chem. Soc. 132 2010 12170 12171
7. 4 spinel nanoparticles grown on graphene as bifunctional catalyst for lithium-air batteries J. Electrochem. Soc. 158 2011 A1379 A1382
8. S.S. Zhang, X. Ren, and J. Read Heat-treated metal phthalocyanine complex as an oxygen reduction catalyst for non-aqueous electrolyte Li/air batteries J. Electrochem. Acta 56 2011 4544 4548
9. 2 to Li-air batteries: carbon nanotubes/ionic liquid gels with a tricontinuous passage of electrons, ions and oxygen Angew. Chem. Int. Ed. 51 2012 11062 11067
10. 2 batteries Nat. Chem. 4 2012 1004 1010
11. 2 battery using a redox mediator Nat. Chem. 5 2013 489 494
12. D. Sun, Y. Shen, W. Zhang, L. Yu, Z. Yi, W. Yin, D. Wang, Y. Huang, J. Wang, D. Wang, and J.B. Goodenough A solution-phase bifunctional catalyst for lithium-oxygen batteries J. Am. Chem. Soc. 136 2014 8941 8946
13. 2 batteries J. Am. Chem. Soc. 136 2014 15054 15064
14. H.-D. Lim, H. Song, J. Kim, H. Gwon, Y. Bae, K.-Y. Park, J. Hong, H. Kim, T. Kim, Y.-H. Kim, X. Lepró, R. Ovalle-Robles, R.H. Baughman, and K. Kang Superior rechargeability and efficiency of lithium-oxygen batteries: hierarchical air electrode architecture combined with a soluble catalyst Angew. Chem. Int. Ed. 53 2014 1 7
15. D.S. Kim, and Y.J. Park Effect of multi-catalysts on rechargeable Li-air batteries J. Alloys Compd. 591 2014 164 169
16. M. Yu, X. Ren, L. Ma, and Y. Wu Integrating a redox-coupled dye-sensitized photoelectrode into a lithium-oxygen battery for photoassisted charging Nat. Commun. 5 2014 1 6
17. W.-J. Kwak, D. Hirshberg, D. Sharon, H.-J. Shin, M. Afri, J.-B. Park, A. Garsuch, F.F. Chesneau, A.A. Frimer, D. Aurbach, and Y.-K. Sun Understanding the behavior of Li-oxygen cells containing LiI J. Mater. Chem. A 3 2015 8855 8864
18. 2 battery Nano Lett. 13 2013 4702 4707
19. 2 + I J. Am. Chem. Soc. 73 4 1951 1842 1843
20. H.A. Liebhafsky, and A. Mohammad The kinetics of the reduction.in acid solution, of hydrogen peroxide by iodide ion J. Am. Chem. Soc. 55 10 1933 3977 3986
21. W.-W. Yin, Z. Shadike, Y. Yang, F. Ding, L. Sang, H. Li, and Z.-W. Fu A long-life Na-air battery based on a soluble NaI catalyst Chem. Commun. 51 2015 2324 2327
22. G. Boschloo, and A. Hagfeldt Characteristics of the iodide/triiodide redox mediator in dye-sensitized solar cells Acc. Chem. Res. 42 2009 1819 1826
23. K.J. Hanson, and C.W. Tobias Electrochemistry of iodide in propylene carbonate J. Electrochem. Soc. 134 9 1987 2204 2210
24. B.F. Minaev The singlet-triplet absorption and photodissociation of the HOCl, HOBr, and HOI molecules calculated by the MCSCF quadratic response method J. Phys. Chem. A 103 1999 7294 7309
25. T.M. Allen, and F.M. Feefer The formation of hypoiodous acid and hydrated iodine cation by the hydrolysis of iodine J. Am. Chem. Soc. 77 11 1955 2957 2960
26. Z. Marczenko, and M. Balcerzak Separation, Preconcentration and Spectrophotometry in Inorganic Analysis 2000 Elsevier Science Poland
27. S.A. Freunberger, Y. Chen, N.E. Drewett, L.J. Hardwick, F. Bardé, and P.G. Bruce The lithium-oxygen battery with ether-based electrolytes Angew. Chem. Int. Ed. 50 2011 8609 8613