Production of Aromatic Hydrocarbons via Catalytic Pyrolysis of Biomass over Fe-Modified HZSM-5 Zeolites

ACS Sustainable Chemistry and Engineering

Volumn 3, Issue 7, 2015, Pages 1623-1631

  Mullen, Charles A ^a   Boateng, Akwasi A ^a  

^a EASTERN REGIONAL RESEARCH CENTER   (United States)

Author keywords

Aromatics; Biomass; Catalytic pyrolysis; Cellobiose; Cellulose; Hydrocarbons; HZSM 5; Iron; Lignin

Indexed keywords

AROMATIC COMPOUNDS; AROMATIZATION; BENZENE; BIOMASS; CARBON; CATALYST SELECTIVITY; CATALYSTS; CELLULOSE; CHROMATOGRAPHY; ETHYLBENZENE; GAS CHROMATOGRAPHY; HYDROCARBONS; ION EXCHANGE; IRON; LIGNIN; MASS SPECTROMETRY; NAPHTHALENE; PLANTS (BOTANY); XYLENE;

1 , 2 , 4-TRIMETHYLBENZENE; AROMATICS; CATALYTIC PYROLYSIS; CATALYTIC PYROLYSIS OF BIOMASS; CELLOBIOSE; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; H-ZSM-5; IRON CONTAINING CATALYSTS;

AROMATIC HYDROCARBONS;

EID: 84936804310     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/acssuschemeng.5b00335     Document Type: Article

References (34)

1. U.S. Department of Energy. 2011 U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry; Perlack, R. D.; Stokes, B. J. (Leads); ORNL/TM-2011/224; Oak Ridge National Laboratory: Oak Ridge, TN, 2011.
2. Bridgewater, A. V. Review of fast pyrolysis of biomass and product upgrading Biomass Bioenergy 2012, 38, 68-94
3. Talmadge, M. S.; Baldwin, R. M.; Biddy, M. J.; McCormick, R. L.; Beckham, G. T.; Ferguson, G. A.; Czernik, S.; Magrini-Bair, K. A.; Foust, T. D.; Metelski, P. D.; Hetrick, C.; Nimlos, M. R. A perspective on oxygenated species in the refinery integration of pyrolysis oil Green Chem. 2014, 16, 407-453
4. Carlson, T. R.; Vispute, T. P.; Huber, G. W. Green gasoline by catalytic fast pyrolysis of solid biomass derived compounds ChemSusChem 2008, 1, 397-400
5. Vispute, T. P.; Zhang, H.; Sanna, A.; Xiao, R.; Huber, G. W. Renewable chemical commodity feedstocks from integrated catalytic processing of pyrolysis oils Science 2010, 330, 1222-1227
6. Jae, J.; Coolman, R.; Mountziaris, T. J.; Huber, G. W. Catalytic fast pyrolysis of lignocellulosic biomass in a process development unit with continual catalyst addition and removal Chem. Eng. Sci. 2014, 108, 33-46
7. Zhang, H.; Xiao, R.; Jin, B.; Shen, D.; Chen, R.; Xiao, G. Catalytic fast pyrolysis of straw biomass in an internally interconnected fludized bed to produce aromatics and olefins: effect of different catalysts Bioresour. Technol. 2013, 137, 82-87
8. Williams, P. T.; Nugranad, N. Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks Energy 2000, 25, 493-513
9. Zhang, H.; Xiao, R.; Huang, H.; Xiao, G. Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor Bioresour. Technol. 2009, 100, 1428-1434
10. Mihalcik, D. L.; Mullen, C. A.; Boateng, A. A. Screening acidic zeolites for catalytic fast pyrolysis of biomass and its components J. Anal. Appl. Pyrolysis 2011, 92, 224-232
11. Mullen, C. A.; Boateng, A. A.; Mihalcik, D. L.; Goldberg, N. M. Catalytic fast pyrolysis of white oak wood in a bubbling fluidized bed Energy Fuels 2011, 25, 5444-5451
12. Mullen, C. A.; Boateng, A. A. Accumulation of inorganic impurities on HZSM-5 zeolites during catalytic fast pyrolysis of switchgrass Ind. Chem. Eng. Res. 2013, 52, 17516-17161
13. Williams, C. L.; Chang, C.; Do, P.; Nikbin, N.; Caratzoulas, S.; Vlachos, D. G.; Lobo, R. F.; Fan, W.; Dauenhauer, P. J. Cycloaddition of biomass-derived furans for catalytic production of renewable p-xylene ACS Catal. 2012, 2, 935-939
14. Cheng, Y.; Wang, Z.; Gilbert, G. J.; Fan, W.; Huber, G. W. Production of p-xylene from biomass by catalytic fast pyrolysis using ZSM-5 catalysts with reduced pore openings Angew. Chem., Int. Ed. 2012, 51, 11097-11100
15. Cheng, Y.; Jae, J.; Fan, W.; Huber, G. W. Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/HZSM-5 catalysts Angew. Chem., Int. Ed. 2012, 51, 1387-1390
16. Vichaphund, S.; Aht-ong, D.; Sricharoenchaikul, V.; Atong, D. Renewable Energy 2014, 65, 70-77
17. Iliopoulou, E. F.; Stefanidis, S. D.; Kalogiannis, K. G.; Delimitis, A.; Lappas, A. A.; Triantafyllidis, K. S. Catalytic upgrading of biomass pyrolysis vapors using transition metal modified ZSM-5 zeolite Applied Catal., B 2012, 127, 281-290
18. Veses, A.; Puértolas, B.; Callén, M. S.; García, T. Catalytic upgrading of biomass derived pyrolysis vapor over metal-loaded ZSM-5 zeolites: Effect of different metal cations on the bio-oil final properties Microporous Mesoporous Mater. 2015, 209, 189-196
19. Huber, G. W.; Cheng, T.; Carlson, T.; Vispute, T.; Jae, J.; Tompsett, G. Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds. U.S. Patent US 8,277,643 B2, October 2, 2012.
20. Cihanoglu, A.; Gündüz, G.; Dükkanci, M. Degradation of acetic acid by heterogeneous Fenton-like oxidation of iron containing ZSM-5 zeolites Appl. Catal., B 2015, 165, 687-699
21. Ivanov, D. P.; Piruko, L. V.; Panov, L. V. G. I. Oxidation of phenol to dihydroxybenzenes by nitrous oxide Appl. Catal., A 2012, 415-416, 10-16
22. Krishna, K.; Makkee, M. Preparation of Fe-ZSM-5 with enhanced activity and stability for SCR of NOx Catal. Today 2006, 114, 23-30
23. Brandenberger, S.; Kröcher, O.; Casapu, M.; Tissler, A.; Althoff, R. Hydrothermal deactivation of Fe-ZSM-5 catalysts for the selective catalytic reduction of NO with NH3 Appl. Catal., B 2011, 101, 649-659
24. Yathavan, B. K.; Agblevor, F. A. Catalytic pyrolysis of pinyon-juniper using red mud and HZSM-5 Energy Fuels 2013, 27, 6858-6865
25. Veses, A.; Aznar, M.; López, J. M.; Callén, M. S.; Murillo, R.; García, T. Production of upgraded bio-oils by biomass catalytic pyrolysis in an auger reactor using low cost materials Fuel 2015, 141, 17-27
26. Zhang, H.; Zheng, J.; Xia, D. Catalytic pyrolysis of willow wood with Me/ZSm-5 (Me = Mg, K, Fe, Ga, Ni) to produce aromatics and olefins BioResources 2013, 8, 5612-5621
27. Mullen, C. A.; Boateng, A. A.; Dadson, R. B.; Hashem, F. W. Biological mineral range effects on biomass conversion to aromatic hydrocarbons via catalytic fast pyrolysis over HZSM-5 Energy Fuels 2014, 28, 7014-7024
28. Jae, J. H.; Tompsett, G. A.; Lin, Y. C.; Carlson, T. R.; Shen, J. C.; Zhang, T. Y.; Yang, B.; Wyman, C. E.; Conner, W. C.; Huber, G. W. Depolymerization of lignocellulosic biomass to fuel precursors: maximizing carbon efficiency by combining hydrolysis with pyrolysis Energy Environ. Sci. 2010, 3, 358-365
29. Mullen, C. A.; Boateng, A. A. Catalytic pyrolysis-GC/MS of lignin from several sources Fuel Process. Technol. 2010, 91, 1446-1458
30. Adler, P. R.; Sanderson, M. A.; Boateng, A. A.; Weimer, P. J.; Jung, H. G. Biomass yield and biofuel quality of switchgrass harvested in fall or spring Agron. J. 2006, 98, 1518-1525
31. Mukarakate, C.; Zhang, x.; Stanton, A. R.; Robichaud, D. J.; Ciesielski, P. N.; Malhotra, K.; Donohoe, B. S.; Gjersing, E.; Evans, R. J.; Heroux, D. S.; Richards, R.; Iisa, K.; Nimols, M. R. Real-time monitoring of the deactivation of HZSM-5 during upgrading of pine pyrolysis vapors Green Chem. 2014, 16, 1444-1461
32. Graça, I.; Comparot, J.; Laforge, S.; Magnoux, P.; Lopes, J. M.; Ribeiro, M. F.; Ribeiro, R. Influence of phenol addition on the HZSM-5 zeolite catalytic properties during methylcyclohexane transformation Energy Fuels 2009, 23, 4224-4230
33. Fahmi, R.; Bridgwater, A. V.; Donnison, I.; Yates, N.; Jones, J. M. The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability Fuel 2008, 87, 1230-1240
34. Patwardhan, P. R.; Satrio, J. A.; Brown, R. C.; Shanks, B. H. Influence of inorganic salts on the primary pyrolysis products of cellulose Bioresour. Technol. 2010, 101, 4646-4655