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Irreversibility is likely based on electron density rearrangement chemical reactions In this context, it is reassuring that the transients seen at the end of the femtosecond experiments match those at the beginning of the nanosecond experiment. Moreover, maxima at 470 and 610 nm, minima at 532 and 570 nm, and an excited state lifetime of 36 μs in the absence of oxygen perfectly agree with what was found for the SubPc triplet excited state of 2c In the absence of oxygen, the SubPc triplet excited state lifetime is 20 ± 5 μs and, as such, agrees with what was found for 2d Singlet oxygen quantum yields of 1b were found to be as high as 0.49 (toluene), 0.24 (THF), and 0.65 (benzonitrile) and support the assignment that the triplet excited state evolves as the product of charge recombination. Please note that the singlet oxygen yields in 2d are 0.39 (toluene), 0.09 (THF), and 0.26 (benzonitrile)
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