Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route

Scientific Reports

Volumn 5, Issue , 2015, Pages

  Tong, Mingquan ^a,d   Zhang, Daliang ^a   Fan, Weibin ^b   Xu, Jun ^c   Zhu, Liangkui ^a   Guo, Wen ^a   Yan, Wenfu ^a   Yu, Jihong ^a   Qiu, Shilun ^a   Wang, Jianguo ^b   Deng, Feng ^c   Xu, Ruren ^a  

^a JILIN UNIVERSITY   (China)

^b INSTITUTE OF COAL CHEMISTRY   (China)

^c Wuhan National Laboratory for Optoelectronics   (China)

^d Yang Quan Coal Industry GROUP CO   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84935010323     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep11521     Document Type: Article

References (34)

1. Xu, R., Pang, W., Yu, J., Huo, Q. & Chen, J. Chemistry of zeolites and related porous materials: synthesis and structure. (John Wiley & Sons (Asia) Pte Ltd, 2007).
2. Cejka, J., Corma, A. & Zones, S. I. Zeolites and catalysis-synthesis, reactions and applications. (WILEY-VCH Verlag GmbH & Co. KGaA, 2010).
3. Zhang, J., Chen, S., Zingiryan, A. & Bu, X. Integrated molecular chirality, absolute helicity, and intrinsic chiral topology in threedimensional open-framework materials. J. Am. Chem. Soc. 130, 17246-17247 (2008).
4. Yu, J. & Xu, R. Chiral zeolitic materials: structural insights and synthetic challenges. J. Mater. Chem. 18, 4021-4030 (2008).
5. Baiker, A. Chiral catalysis on solids. Curr. Opin. Solid State Mater. Sci. 3, 86-93 (1998).
6. Lough, W. J. & Wainer, I. W. Chirality in Natural and Applied Science. (CRC Press, 2002).
7. Newsam, J. M., Treacy, M. M. J., Koetsier, W. T. & Degruyter, C. B. Structural characterization of zeolite-Beta. Proc. R. Soc. London, Ser. A 420, 375-405 (1988).
8. Higgins, J. B. et al. The framework topology of zeolite-Beta. Zeolites 8, 446-452 (1988).
9. Rajić, N., Logar, N. Z. & Kaučič, V. A novel open framework zincophosphate: synthesis and characterization. Zeolites 15, 672-678 (1995).
10. Rouse, R. C. & Peacor, D. R. Crystal structure of the zeolite mineral goosecreekite, CaAl2Si6O16.5H2O. Am. Mineral. 71, 1494-1501 (1986).
11. Sun, J. et al. The ITQ-37 mesoporous chiral zeolite. Nature 458, 1154-1157 (2009).
12. Song, X. et al. Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves. Angew. Chem. Int. Ed. 48, 314-317 (2009).
13. Broach, R. W. & Kirchner, R. M. Structures of the K+ and NH4+ forms of Linde J. Microporous Mesoporous Mater. 143, 398-400 (2011).
14. Cheetham, A. K. et al. 05-O-05-Very open microporous materials: from concept to reality. Stud. Surf. Sci. Catal. 135, 158 (2001).
15. Elomari, S., Burton, A., Medrud, R. C. & Grosse-Kunstleve, R. The synthesis, characterization, and structure solution of SSZ-56: An extreme example of isomer specificity in the structure direction of zeolites. Microporous Mesoporous Mater. 118, 325-333 (2009).
16. Tang, L. Q. et al. A zeolite family with chiral and achiral structures built from the same building layer. Nat. Mater. 7, 381-385 (2008).
17. Rojas, A. & Camblor, M. A. A Pure silica chiral polymorph with helical pores. Angew. Chem. Int. Ed. 51, 3854-3856 (2012).
18. Rojas, A., Arteaga, O., Kahr, B. & Camblor, M. A. Synthesis, structure, and optical activity of HPM-1, a pure silica chiral zeolite. J. Am. Chem. Soc. 135, 11975-11984 (2013).
19. Wadlinger, R. L., Kerr, G. T. & Rosinski, E. J. Catalytic composition of a crystalline zeolite. US patent 3,308,069 (1967).
20. Camblor, M. A. et al. High silica zeolites with three-dimensional systems of large pore channels. Microporous Mesoporous Mater. 48, 11-22 (2001).
21. Burton, A. W., Elomari, S., Chan, I., Pradhan, A. & Kibby, C. Structure and synthesis of SSZ-63: Toward an ordered form of zeolite beta. J. Phys. Chem. B 109, 20266-20275 (2005).
22. Cantin, A. et al. Synthesis and characterization of the all-silica pure polymorph C and an enriched polyrnorph B intergrowth of zeolite beta. Angew. Chem. Int. Ed. 45, 8013-8015 (2006).
23. Corma, A. et al. Synthesis and structure of polymorph B of zeolite beta. Chem. Mater. 20, 3218-3223 (2008).
24. Yu, Z. B. et al. Intergrown new zeolite beta polymorphs with Interconnected 12-Ring channels solved by combining electron crystallography and single-crystal X-ray diffraction. Chem. Mater. 24, 3701-3706 (2012).
25. Davis, M. E. & Lobo, R. F. Zeolite and molecular sieve synthesis. Chem. Mater. 4, 756-768 (1992).
26. Takagi, Y., Komatsu, T. & Kitabata, Y. Crystallization of zeolite beta in the presence of chiral amine or rhodium complex. Microporous Mesoporous Mater. 109, 567-576 (2008).
27. Taborda, F., Willhammar, T., Wang, Z., Montes, C. & Zou, X. 28 Synthesis and characterization of pure silica zeolite beta obtained by an aging-drying method. Microporous Mesoporous Mater. 143, 196-205 (2011).
28. Camblor, M. A., Corma, A. & Valencia, S. Spontaneous nucleation and growth of pure silica zeolite-beta free of connectivity defects. Chem. Commun. 2365-2366 (1996).
29. Larlus, O. & Valtchev, V. P. Control of the morphology of all-silica BEA-type zeolite synthesized in basic media. Chem. Mater. 17, 881-886 (2005).
30. Villaescusa, L. A. et al. Pure silica large pore zeolite ITQ-7: synthetic strategies, structure-directing effects, and control and nature of structural disorder. Chem. Mater. 19, 1601-1612 (2007).
31. Wright, P. A., Zhou, W. Z., Perez-Pariente, J. & Arranz, M. Direct observation of growth defects in zeolite beta. J. Am. Chem. Soc. 127, 494-495 (2005).
32. Sun, J. et al. Synthesis, surface and crystal structure investigation of the large zeolite beta crystal. Microporous Mesoporous Mater. 102, 242-248 (2007).
33. Szostak, R., Pan, M. & Lillerud, K. P. High-resolution TEM imaging of extreme faulting in natural zeolite tschernichite. J. Phys. Chem. 99, 2104-2109 (1995).
34. Hovmöller, S. CRISP: crystallographic image processing on a personal computer. Ultramicroscopy 41, 121-135 (1992).