Direct measurement of surface termination groups and their connectivity in the 2D MXene V2CTx using NMR spectroscopy

Journal of Physical Chemistry C

Volumn 119, Issue 24, 2015, Pages 13713-13720

  Harris, Kristopher J ^a   Bugnet, Matthieu ^b   Naguib, Michael ^c   Barsoum, Michel W ^c   Goward, Gillian R ^a  

^a MCMASTER UNIVERSITY   (Canada)

^b MCMASTER UNIVERSITY   (Canada)

^c Drexel University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBIDES; CHEMICAL SHIFT; ENERGY GAP; FLUORINE COMPOUNDS; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; HYDROGEN BONDS; MOLECULES; TRANSITION METALS;

13C SOLID STATE NMR; 1H NMR SPECTROSCOPY; DIRECT MEASUREMENT; EXPERIMENTAL VERIFICATION; HYDROGEN-BONDED WATER MOLECULES; STRONG INTERACTION; SURFACE HYDROXIDE; SURFACE TERMINATION;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 84934988380     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b03038     Document Type: Article

References (23)

1. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric Field Effect in Atomically Thin Carbon Films Science 2004, 306, 666-669
2. 2 Adv. Mater. 2011, 23, 4248-4253
3. n Phases: Materials Science and Thin-Film Processing Thin Solid Films 2010, 518, 1851-1878
4. Naguib, M.; Mochalin, V. N.; Barsoum, M. W.; Gogotsi, Y. 25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Adv. Mater. 2014, 26, 992-1005
5. Naguib, M.; Gogotsi, Y. Synthesis of Two-Dimensional Materials by Selective Extraction Acc. Chem. Res. 2015, 48, 128-135
6. 2 MXene as a High Capacity Electrode Material for Metal (Li, Na, K, Ca) Ion Batteries ACS Appl. Mater. Interfaces 2014, 6, 11173-11179
7. Xie, Y.; Dall'Agnese, Y.; Naguib, M.; Gogotsi, Y.; Barsoum, M. W.; Zhuang, H. L.; Kent, P. R. C. Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries ACS Nano 2014, 8, 9606-9615
8. Naguib, M.; Halim, J.; Lu, J.; Cook, K. M.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries J. Am. Chem. Soc. 2013, 135, 15966-15969
9. Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E.; Dall'Agnese, Y.; Rozier, P.; Taberna, P. L.; Naguib, M.; Simon, P.; Barsoum, M. W.; Gogotsi, Y. Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Science 2013, 341, 1502-1505
10. Ghidiu, M.; Lukatskaya, M. R.; Zhao, M.-Q.; Gogotsi, Y.; Barsoum, M. W. Conductive Two-Dimensional Titanium Carbide 'Clay' with High Volumetric Capacitance Nature 2014, 516, 78-U171
11. 2 Stacks: Electronic Structure versus Boundary Effects Phys. Rev. B 2014, 89, 235428
12. Halim, J.; Lukatskaya, M. R.; Cook, K. M.; Lu, J.; Smith, C. R.; Naslund, L.-A.; May, S. J.; Hultman, L.; Gogotsi, Y.; Eklund, P.; Barsoum, M. W. Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Chem. Mater. 2014, 26, 2374-2381
13. 2 and Temperature Dual-Responsive "Smart" MXene Phases Chem. Commun. 2015, 51, 314-317
14. 2 MXene Using Atomic Pair Distribution Function Phys. Rev. Lett. 2014, 112, 125501
15. 3 (MXene) Chem. Commun. 2014, 50, 9517-9520
16. Naguib, M.; Mashtalir, O.; Carle, J.; Presser, V.; Lu, J.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. Two-Dimensional Transition Metal Carbides ACS Nano 2012, 6, 1322-1331
17. 2 (X = F, OH) Monolayer J. Am. Chem. Soc. 2012, 134, 16909-16916
18. Bennett, A. E.; Ok, J. H.; Griffin, R. G.; Vega, S. Chemical-Shift Correlation Spectroscopy in Rotating Solids-Radio-Frequency Driven Dipolar Recoupling and Longitudinal Exchange J. Chem. Phys. 1992, 96, 8624-8627
19. Meiboom, S.; Gill, D. Modified Spin Echo Method for Measuring Nuclear Relaxation Times Rev. Sci. Instrum. 1958, 29, 688-691
20. Carr, H. Y.; Purcell, E. M. Effects of Diffusion on Free Precession in Nuclear Magnetic Resonance Experiments Phys. Rev. 1954, 94, 630
21. Vosegaard, T.; Larsen, F. H.; Jakobsen, H. J.; Ellis, P. D.; Nielsen, N. C. Sensitivity-Enhanced Multiple-Quantum MAS NMR of Half-Integer Quadrupolar Nuclei J. Am. Chem. Soc. 1997, 119, 9055-9056
22. Lefort, R.; Wiench, J. W.; Pruski, M.; Amoureux, J. P. Optimization of Data Acquisition and Processing in Carr-Purcell-Meiboom-Gill Multiple Quantum Magic Angle Spinning Nuclear Magnetic Resonance J. Chem. Phys. 2002, 116, 2493-2501
23. Feike, M.; Demco, D. E.; Graf, R.; Gottwald, J.; Hafner, S.; Spiess, H. W. Broadband Multiple-Quantum NMR Spectroscopy J. Magn. Reson., Ser. A 1996, 122, 214-221