Determination of aminopolycarboxylic acids at ultra-trace levels by means of online coupling ion exchange chromatography and inductively coupled plasma-mass spectrometry with indirect detection via their Pd2+-complexes

Analytica Chimica Acta

Volumn 884, Issue , 2015, Pages 124-132

  Nette, David ^a   Seubert, Andreas ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

Aminopolycarboxylic acids; Inductively coupled plasma mass spectrometry; Ion exchange chromatography; On line coupling; Palladium; Water science

Indexed keywords

AMINO ACIDS; CHROMATOGRAPHIC ANALYSIS; DRUG PRODUCTS; GAS CHROMATOGRAPHY; INDUCTIVELY COUPLED PLASMA; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; ION CHROMATOGRAPHY; ION EXCHANGE; IONS; MASS SPECTROMETERS; PALLADIUM;

1 ,3-DIAMINOPROPANE; ION EXCHANGE CHROMATOGRAPHY; ION-PAIR CHROMATOGRAPHY; METHYLGLYCINEDIACETIC ACIDS; NITRILOTRIACETIC ACID; ON-LINE COUPLING; ORDERS OF MAGNITUDE; WATER SCIENCE;

PALLADIUM COMPOUNDS;

(2 CARBOXYETHYL)IMINODIACETIC ACID; (2 HYDROXYETHYL)ETHYLENEDIAMINE TRIACETIC ACID; 1,2 DIAMINOPROPANE TETRAACETIC ACID; 1,3 DIAMINOPROPANE TETRAACETIC ACID; CARBOXYLIC ACID; COBALT; COPPER ION; ETHYLENDIAMINE TETRAACETIC ACID; IRON; MANGANESE; METHYLGLYCINEDIACETIC ACID; NICKEL; NITRATE; NITRILOTRIACETIC ACID; PALLADIUM COMPLEX; PENTETIC ACID; UNCLASSIFIED DRUG; EDETIC ACID; N-(HYDROXYETHYL)ETHYLENEDIAMINETRIACETIC ACID; PALLADIUM;

ARTICLE; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; CORRELATION ANALYSIS; GAS CHROMATOGRAPHY; INTERMETHOD COMPARISON; ION EXCHANGE CHROMATOGRAPHY; LIMIT OF DETECTION; MASS SPECTROMETRY; MEASUREMENT REPEATABILITY; ONLINE COUPLING ION EXCHANGE CHROMATOGRAPHY; PH; PRIORITY JOURNAL; TEMPERATURE; ANALOGS AND DERIVATIVES; CHEMISTRY; ONLINE SYSTEM; PROCEDURES; REPRODUCIBILITY; STANDARDS; THERMODYNAMICS;

CARBOXYLIC ACIDS; CHROMATOGRAPHY, ION EXCHANGE; EDETIC ACID; HYDROGEN-ION CONCENTRATION; IRON; LIMIT OF DETECTION; MASS SPECTROMETRY; NITRILOTRIACETIC ACID; ONLINE SYSTEMS; PALLADIUM; REPRODUCIBILITY OF RESULTS; TEMPERATURE; THERMODYNAMICS;

EID: 84930823530     PISSN: 00032670     EISSN: 18734324     Source Type: Journal    
DOI: 10.1016/j.aca.2015.05.019     Document Type: Article

References (40)

1. ISO 16588:2002 Water Quality - Determination of Six Complexing Agents - Gas-chromatographic Method 2015, International Standards Organisation, 2002.
2. Landesumweltamt Nordrhein-Westfalen, EDTA in Nordrhein-Westfalen-ein synthetischer Stoff in der aquatischen Umwelt, Gewässergüteberichte NRW ISSN 1437-7500, 2003.
3. Begum Z.A., Rahman I.M.M., Hasegawa H. Management of EDTA-containing aqueous effluent: environmental concerns and remedies. EDTA: Synthesis, Uses and Environmental Concerns 2013, 163-177. Nova Science Publishers. A. Molnar (Ed.).
4. Bucheli-Witschel M., Egli T. Environmental fate and microbial degradation of aminopolycarboxylic acids. FEMS Microbiol. Rev. 2001, 25:69-106.
5. Geschke R., Zehringer M. A new method for the determination of complexing agents in river water using HPLC. Fresenius J. Anal. Chem. 1997, 357:773-776.
6. Ammann A.A. Determination of strong binding chelators and their metal complexes by anion-exchange chromatography and inductively coupled plasma mass spectrometry. J. Chromatogr. A 2002, 947:205-216.
7. Ammann A.A. Speciation of heavy metals in environmental water by ion chromatography coupled to ICP-MS. Anal. Bioanal. Chem. 2002, 372:448-452.
8. Chen Z., Sun Q., Xi Y., Owens G. Speciation of metal-EDTA complexes by flow injection analysis with electrospray ionization mass spectrometry and ion chromatography with inductively coupled plasma mass spectrometry. J. Sep. Sci. 2008, 31:3796-3802.
9. Chen Z., Owens G., Kim K.-R., Naidu R. Confirmation of lead aminocarboxylic complex formation using electrospray ionization mass spectrometry and speciation by anion-exchange chromatography coupled with ICP-MS. Anal. Chim. Acta 2007, 599:163-169.
10. Bauer K.H., Bonin H., Fink A., Aimene A., Schön P., Weber L. Determination of synthetic chelons in waters of the Hessian Ried by indirect differential pulse anodic stripping voltammetry and gas chromatography. Vom Wasser 1997, 88:351-364.
11. Lee H.B., Peart T.E., Kaiser K.L.E. Determination of nitrolotriacetic, ethylenediaminetetraacetic and diethylenetriaminepentaacetic acids in sewage treatment plant and paper mill effluents. J. Chromatogr. A 1996, 738:91-99.
12. Nishikawa Y., Okumura T. Determination of nitrilotriacetic acid and ethylenediaminetetraacetic acid in environmental samples as their methyl ester derivatives by gas chromatography-mass spectrometry. J. Chromatogr. A 1995, 690:109-118.
13. 38413-8 D.I.N. Bestimmung der gelösten Komplexbildner NTA, EDTA und DTPA mit der Flüssigchromatographie 2000, Beuth Verlag, Berlin.
14. Kemmei T., Kodama S., Yamamoto A., Inoue Y., Hayakawa K. Determination of low-level ethylenediaminetetraacetic acid in water samples by ion chromatography with ultraviolet detection. Chromatographia 2007, 65:229.
15. Weiß J. Ionenchromatographie 2012, Wiley-VCH, Weinheim.
16. Laine P., Matilainen R. Simultaneous determination of DTPA, EDTA, and NTA by UV-visible spectrometry and HPLC. Anal. Bioanal. Chem. 2005, 382:1601-1609.
17. Randt C., Wittlinger R., Merz W. Analysis of nitrilotriacetic acid (NTA) ethylenediamine-tetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) in water, particularly waste water. Fresenius J. Anal. Chem. 1993, 346:728-731.
18. Meszaros A., Fekete J. Determination of ethylenediaminetetraacetic acid from swine organs, feces, urine, and plasma by liquid chromatography tandem mass spectrometry. Food Anal. Methods 2015, 8:678-684.
19. Chiumiento F., D'Aloise A., Marchegiani F., Melai V. Determination of EDTA in feed and premix formulations by HPLC-DAD. Food Chem. 2015, 175:452-456.
20. Evans E.H., Giglio J.J. Interferences in inductively coupled plasma mass spectrometry. A review. J. Anal. At. Spectrom. 1993, 8:1-18.
21. Pantsar-Kallio M., Manninen P.K.G. Optimizing ion chromatography-inductively coupled plasma mass spectrometry for speciation analysis of arsenic, chromium and bromine in water samples. Int. J. Environ. Anal. Chem. 1999, 75:43-55.
22. Seubert A. On-line coupling of ion chromatography with ICP-AES and ICP-MS. Trends Anal. Chem. 2001, 20:274-287.
23. Kaiser E., Riviello J., Rey M., Statler J., Heberling S. Determination of trace level ions by high-volume direct-injection ion chromatography. J. Chromatogr. A 1996, 739:71-79.
24. Knöll J., Seubert A. Indirect ultra trace determination of aminopolycarboxylic acids in surface water using ion exchange chromatography coupled on-line to inductively coupled plasma mass spectrometry. J. Chromatogr. A 2012, 1270:219.
25. Yi L., Lucy C.A. Ion chromatographic determination of chelating ligands based on the postcolumn formation of ternary fluorescent complexes. J. Chromatogr. A 1996, 739:307-315.
26. Pátzay G., Ramadan Y., Tonkó C. New EDTA determination method based on ion chromatography with suppressed conductimetric detection. J. Radioanal. Nucl. Chem. 2014, 312:161-168.
27. Raskop M. Neue Stationäre Phasen zum Einsatz in der Ionenchromatographie, PhD-Thesis 2005, Philipps-Universität Marburg.
28. Knöll J. Ultraspurenbestimmung von Aminopolycarbonsäure-Komplexbildnern mittels inverser Online-Kopplung IC-ICP-MS, PhD-Thesis 2015, Philipps-Universität Marburg, 2012.
29. Kaplun M., Sandström M., Boström D., Shchukarev A., Persson P. Crystal structures and spectroscopic properties of palladium complexes isolated from Pd-edta solutions. Inorg. Chim. Acta 2005, 358:527-534.
30. Schmidt C.K., Brauch H.J. Aminopolycarbonsäuren in der Aquatischen Umwelt 2003, DVGW-Technologiezentrum Wasser Karlsruhe, Karlsruhe.
31. Yamaguchi A., Rajput A.R., Ohzeki K., Kambara T. Determination of ethylenediaminetetraacetic acid and nitrilotriacetic acid as their iron(II)-complexes by reversed phase high performance liquid chromatography. Bull. Chem. Soc. Jpn. 1983, 56:2621-2623.
32. Chaberek S., Martell A.E. Interaction of divalent metal ions with N-hydroxy-ethylenediaminetriacetic acid. J. Am. Chem. Soc. 1955, 77:1477-1480.
33. Wiberg N. Lehrbuch der Anorganischen Chemie 2007, Walter de Gruyter, Berlin.
34. Anderegg G., Malik S.C. Komplexone XLVII. The stability of palladium(II) complexes with aminopolycarboxylate anions. Helv. Chim. Acta 1976, 59:1498-1511.
35. Sokol L.S.W.L., Fink T.D., Rorabacher D.B. Kinetics of inner-sphere solvent exchange on the aquocopper(II) ion: indirect determination from kinetics of copper(II) reacting with ammonia in aqueous solution. Inorg. Chem. 1980, 19:1263-1266.
36. Helm L., Merbach A.E. Water exchange on metal ions: experiments and simulations. Coord. Chem. Rev. 1999, 187:151-181.
37. Berger J., Kotowski M., Van Eldik R., Frey U., Helm L., Merbach A.E. Kinetics and mechanism of solvent-exchange and anation reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution. Inorg. Chem. 1989, 28:3759-3765.
38. Tompkins E.R., Mayer S.W. Ion exchange as a separation method. III. Equilibrium studies of the reactions of rare earth complexes with synthetic ion exchange resins. J. Am. Chem. Soc. 1947, 69:2859-2866.
39. Barron L., Nesterenko P.N., Paull B. Use of temperature programming to improve resolution of inorganic anions, haloacetic acids and oxyhalides in drinking water by suppressed ion chromatography. J. Chromatogr. A 2005, 1072:207-215.
40. DIN 32645 Nachweis-, Erfassungs- und Bestimmungsgrenze 2008, Beuth Verlag, Berlin.