Cluster size controls branching between water and hydrogen peroxide production in electrochemical oxygen reduction at Ptn/ITO

Journal of Physical Chemistry C

Volumn 119, Issue 20, 2015, Pages 11160-11170

  Von Weber, Alexander ^a   Baxter, Eric T ^a   White, Henry S ^a   Anderson, Scott L ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING SITES; CHEMICAL PLANTS; CHLORINE COMPOUNDS; CLUSTER ANALYSIS; ELECTRODES; ELECTROLYTIC REDUCTION; ELECTRONIC PROPERTIES; HYDROGEN PEROXIDE; INDIUM COMPOUNDS; OXIDATION; OXIDE FILMS; OXYGEN; PEROXIDES; TIN OXIDES;

CATALYTIC SITES; ELECTROCHEMICAL OXYGEN REDUCTION; HYDROGEN PEROXIDE PRODUCTION; INDIUM TIN OXIDE FILMS; ONSET POTENTIAL; OXYGEN REDUCTION REACTION; POLYCRYSTALLINE; SELECTIVE CATALYSTS;

PLATINUM;

EID: 84930225491     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp5119234     Document Type: Article

References (48)

1. Markovic, N. M.; Adzic, R. R.; Vesovic, V. B. Structural Effects in Electrocatalysis. Oxygen Reduction on the Gold Single Crystal Electrodes with (110) and (111) Orientations J. Electroanal. Chem. Interfacial Electrochem. 1984, 165, 121-133
2. Adzic, R. R.; Strbac, S.; Anastasijevic, N. Electrocatalysis of Oxygen on Single Crystal Gold Electrodes Mater. Chem. Phys. 1989, 22, 349-375
3. El Kadiri, F.; Faure, R.; Durand, R. Electrochemical Reduction of Molecular Oxygen on Platinum Single Crystals J. Electroanal. Chem. Interfacial Electrochem. 1991, 301, 177-188
4. Strbac, S.; Adzic, R. Oxygen Reduction on Single Crystal Gold Electrodes in Acid Solutions J. Serb. Chem. Soc. 1992, 57, 835-848
5. Kita, H.; Lei, H.-W.; Gao, Y. Oxygen Reduction on Platinum Single-Crystal Electrodes in Acidic Solutions J. Electroanal. Chem. 1994, 379, 407-414
6. hkl Disk Studies J. Phys. Chem. 1995, 99, 3411-3415
7. Pt(hkl) Studies J. Phys. Chem. 1996, 100, 6715-6721
8. - Chemisorption on the Catalytic Properties of Gold Single Crystal Surfaces for Oxygen Reduction in Alkaline Solutions J. Electroanal. Chem. 1996, 403, 169-181
9. Perez, J.; Villullas, H. M.; Gonzalez, E. R. Structure Sensitivity of Oxygen Reduction on Platinum Single Crystal Electrodes in Acid Solutions J. Electroanal. Chem. 1997, 435, 179-187
10. Tanaka, A.; Adzic, R.; Nikolc, B. Oxygen Reduction on Single Crystal Platinum Electrodes in Phosphoric Acid Solutions J. Serb. Chem. Soc. 1999, 64, 695-705
11. hkl Surfaces J. Electroanal. Chem. 2000, 480, 219-224
12. Stamenkovic, V.; Markovic, N. M.; Ross, P. N. Structure-Relationships in Electrocatalysis: Oxygen Reduction and Hydrogen Oxidation Reactions on Pt(111) and Pt(100) in Solutions Containing Chloride Ions J. Electroanal. Chem. 2001, 500, 44-51
13. Ag(hkl) Studies J. Phys. Chem. B 2006, 110, 4735-4741
14. Greeley, J.; Rossmeisl, J.; Hellman, A.; Noerskov, J. K. Theoretical Trends in Particle Size Effects for the Oxygen Reduction Reaction Z. Phys. Chem. 2007, 221, 1209-1220
15. Kinoshita, K. Particle Size Effects for Oxygen Reduction on Highly Dispersed Platinum in Acid Electrolytes J. Electrochem. Soc. 1990, 137, 845-848
16. Kunz, S.; Hartl, K.; Nesselberger, M.; Schweinberger, F. F.; Kwon, G.; Hanzlik, M.; Mayrhofer, K. J. J.; Heiz, U.; Arenz, M. Size-Selected Clusters as Heterogeneous Model Catalysts under Applied Reaction Conditions Phys. Chem. Chem. Phys. 2010, 12, 10288-10291
17. Nesselberger, M.; Roefzaad, M.; Hamou, R. F.; Biedermann, P. U.; Schweinberger, F. F.; Kunz, S.; Schloegl, K.; Wiberg, G. K. H.; Ashton, S.; Heiz, U. The Effect of Particle Proximity on the Oxygen Reduction Rate of Size-Selected Platinum Clusters Nat. Mater. 2013, 12, 919-924
18. Hartl, K.; Nesselberger, M.; Mayrhofer, K. J. J.; Kunz, S.; Schweinberger, F. F.; Kwon, G. H.; Hanzlik, M.; Heiz, U.; Arenz, M. Electrochemically Induced Nanocluster Migration Electrochim. Acta 2010, 56, 810-816
19. 17) Water Oxidation Electrocatalysis ACS Nano 2013, 7, 5808-5817
20. Lu, J.; Cheng, L.; Lau, K. C.; Tyo, E.; Luo, X.; Wen, J.; Miller, D.; Assary, R. S.; Wang, H.-H.; Redfern, P. Effect of the Size-Selective Silver Clusters on Lithium Peroxide Morphology in Lithium-Oxygen Batteries Nat. Commun. 2014, 5, 4895
21. Xia, C.; Falgairette, C.; Li, Y.; Foti, G.; Comninellis, C.; Harbich, W. Electrochemical Promotion of CO Combustion over Pt/YSZ under High Vacuum Conditions Appl. Catal., B 2012, 113-114, 250-254
22. Xia, C.; Hugentobler, M.; Li, Y.; Foti, G.; Comninellis, C.; Harbich, W. Electrochemical Promotion of CO Combustion over Non-percolated Pt Particles Supported on YSZ Using a Novel Bipolar Configuration Electrochem. Commun. 2011, 13, 99-101
23. n/Indium Tin Oxide (n = 1 to 14). J. Am. Chem. Soc. 2015, submitted for publication.
24. Perez-Alonso, F. J.; McCarthy, D. N.; Nierhoff, A.; Hernandez-Fernandez, P.; Strebel, C.; Stephens, I. E. L.; Nielsen, J. H.; Chorkendorff, I. The Effect of Size on the Oxygen Electroreduction Activity of Mass-Selected Platinum Nanoparticles Angew. Chem., Int. Ed. 2012, 51, S4641
25. Nesselberger, M.; Ashton, S.; Meier, J. C.; Katsounaros, I.; Mayrhofer, K. J. J.; Arenz, M. The Particle Size Effect on the Oxygen Reduction Reaction Activity of Pt Catalysts: Influence of Electrolyte and Relation to Single Crystal Models J. Am. Chem. Soc. 2011, 133, 17428-17433
26. Zhao, M.; Crooks, R. M. Dendrimer-Encapsulated Pt Nanoparticles. Synthesis, Characterization, and Applications to Catalysis Adv. Mater. 1999, 11, 217-220
27. Ye, H.; Crooks, J. A.; Crooks, R. M. Effect of Particle Size on the Kinetics of the Electrocatalytic Oxygen Reduction Reaction Catalyzed by Pt Dendrimer-Encapsulated Nanoparticles Langmuir 2007, 23, 11901-11906
28. Yamamoto, K.; Imaoka, T.; Chun, W.-J.; Enoki, O.; Katoh, H.; Takenaga, M.; Sonoi, A. Size-Specific Catalytic Activity of Platinum Clusters Enhances Oxygen Reduction Reactions Nat. Chem. 2009, 1, S397/1-S397/25
29. 2: Enhancing Activity and Selectivity by Electrocatalytic Site Engineering Nano Lett. 2014, 14, 1603-1608
30. Inaba, M.; Yamada, H.; Tokunaga, J.; Tasaka, A. Size Effects of Platinum Nanoparticles on Activity, Peroxide Formation, and Durability of Pt/C Catalysts. In 210th Meeting of the Electrochemical Society, Cancun, Mexico, October 29-November 3, 2006; abstract 560.
31. Inaba, M.; Yamada, H.; Tokunaga, J.; Tasaka, A. Effect of Agglomeration of Pt/C Catalyst on Hydrogen Peroxide Formation Electrochem. Solid-State Lett. 2004, 7, A474-A476
32. Grgur, B. N.; Marković, N. M.; Ross, P. N. Temperature-Dependent Oxygen Electrochemistry on Platinum Low-Index Single Crystal Surfaces in Acid Solutions Can. J. Chem. 1997, 75, 1465-1471
33. Inaba, M.; Yamada, H.; Tokunaga, J.; Matsuzawa, K.; Hatanaka, A.; Tasaka, A. Hydrogen Peroxide Formation as a Degradation Factor of Polymer Electrolyte Fuel Cells ECS Trans. 2006, 1, 315-322
34. 2(110) Model Catalysts: Size Dependence of Binding Sites and Energies, and Support-Mediated Adsorption J. Chem. Phys. 2012, 136, 204705/1-204705/12
35. Qiu, H.; Yan, J.; Sun, X.; Liu, J.; Cao, W.; Yang, X.; Wang, E. Microchip Capillary Electrophoresis with an Integrated Indium Tin Oxide Electrode-Based Electrochemiluminescence Detector Anal. Chem. 2003, 75, 5435-5440
36. Klett, J.; Krähling, S.; Elger, B.; Schäfer, R.; Kaiser, B.; Jaegermann, W. The Electronic Interaction of Pt-Clusters with Ito and Hopg Surfaces Upon Water Adsorption Z. Phys. Chem. 2014, 228, 503-520
37. Roberts, F. S.; Kane, M. D.; Baxter, E. T.; Anderson, S. L. Oxygen Activation and CO Oxidation over Size-Selected Ptn/Alumina/Re(0001) Model Catalysts: Correlations with Valence Electronic Structure, Physical Structure, and Binding Sites Phys. Chem. Chem. Phys. 2014, 16, 26443-26457
38. Schweizer, A. E.; Kerr, G. T. Thermal Decomposition of Hexachloroplatinic Acid Inorg. Chem. 1978, 17, 2326-2327
39. Vigier, F.; Coutanceau, C.; Perrard, A.; Belgsir, E. M.; Lamy, C. Development of Anode Catalysts for a Direct Ethanol Fuel Cell J. Appl. Electrochem. 2004, 34, 439-446
40. Thomas, J. M. Student Construction of a Gel-Filled Ag/AgCl Reference Electrode for Use in a Potentiometric Titration J. Chem. Educ. 1999, 76, 97-98
41. Ion Channels; Rudy, B.; Iverson, L. E., Eds.; Academic Press: San Diego, CA, 1997.
42. Frumkin, A. N. Hydrogen Overvoltage and Adsorption Phenomena. II. In Advances in Electrochemistry and Eletrochemical Engineering; Delahay, P.; Tobias, C. W., Eds.; Wiley-Interscience: New York, 1963; Vol. 3, pp 287-391.
43. Trasatti, S.; Petrii, O. A. Real Surface Area Measurements in Electrochemstry Pure Appl. Chem. 1991, 63, 711-734
44. Katsounaros, I.; Schneider, W. B.; Meier, J. C.; Benedikt, U.; Biedermann, P. U.; Auer, A. A.; Mayrhofer, K. J. J. Hydrogen Peroxide Electrochemistry on Platinum: Towards Understanding the Oxygen Reduction Reaction Mechanism Phys. Chem. Chem. Phys. 2012, 14, 7384-7391
45. Savinova, D. V.; Molodkina, E. B.; Danilov, A. I.; Polukarov, Y. M. Surface and Subsurface Oxygen on Platinum in a Perchloric Acid Solution Rus. J. Electrochem. 2004, 40, 683-687
46. Chang, G.; Oyama, M.; Hirao, K. In Situ Chemical Reductive Growth of Platinum Nanoparticles on Indium Tin Oxide Surfaces and Their Electrochemical Applications J. Phys. Chem. B 2006, 110, 1860-1865
47. 2 Surfaces Science 2009, 326, 826-829
48. 2 with Platinum-Implications for the Oxygen Reduction Reaction Pathways Phys. Chem. Chem. Phys. 2013, 15, 8058-8068