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Volumn 2, Issue 2, 2015, Pages 213-217

[M(CO)4(2,2′-bipyridine)] (M = Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode

Author keywords

2,2 bipyridine; Carbon dioxide; Electrocatalysis; Gold cathode; Molybdenum; N methyl 2 pyrrolidone

Indexed keywords

CARBON DIOXIDE; CATALYSIS; CATALYSTS; ELECTROCATALYSIS; ELECTROLYTIC REDUCTION; FREE RADICAL REACTIONS; GOLD; MOLYBDENUM; MOLYBDENUM COMPOUNDS; ORGANIC SOLVENTS;

EID: 84930201803     PISSN: None     EISSN: 21960216     Source Type: Journal    
DOI: 10.1002/celc.201402282     Document Type: Article
Times cited : (69)

References (45)
  • 8
    • 68349140297 scopus 로고    scopus 로고
    • No42 (Ed.: C. Vayenas), Springer, New York
    • 2 Reduction on Metal Electrodes" Y. Hori, in Modern Aspects of Electrochemistry, No42 (Ed.: C. Vayenas), Springer, New York, 2008, pp.89-189;
    • (2008) Modern Aspects of Electrochemistry , pp. 89-189
    • Hori, Y.1
  • 41
    • 0004190148 scopus 로고    scopus 로고
    • 5edth edGulf Publishing Company, USA
    • A. Kohl, R Nielsen, Gas Purification, 5edth edGulf Publishing Company, USA, 1997, pp.1210-1215.
    • (1997) Gas Purification , pp. 1210-1215
    • Kohl, A.1    Nielsen, R.2
  • 42
    • 84938626729 scopus 로고    scopus 로고
    • 4(R-bpy)] (M=Mo, W; R=H, tBu) in THF at Pt and GC working electrodes.
    • Our results obtained in this work at gold cathodes (in particular in NMP) show a strong catalytic activity already at the less negative hypothetical cathodic waveR2′, which corresponds to the reduction of partially stabilized tricarbonyl radical anions.
    • - reduction of the stable tetracarbonyl radical anions formed at the cathodic waveR2. Our results obtained in this work at gold cathodes (in particular in NMP) show a strong catalytic activity already at the less negative hypothetical cathodic waveR2′, which corresponds to the reduction of partially stabilized tricarbonyl radical anions.
    • - reduction of the stable tetracarbonyl radical anions formed at the cathodic waveR2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.