Cobalt-based nanocatalysts for green oxidation and hydrogenation processes

Nature Protocols

Volumn 10, Issue 6, 2015, Pages 916-926

  Jagadeesh, Rajenahally V ^a   Stemmler, Tobias ^a   Surkus, Annette Enrica ^a   Bauer, Matthias ^b   Pohl, Marga Martina ^a   Radnik, Jörg ^a   Junge, Kathrin ^a   Junge, Henrik ^a   Brückner, Angelika ^a   Beller, Matthias ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b UNIVERSITY OF PADERBORN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; AMINE; AROMATIC NITRO COMPOUND; CARBON; COBALT ACETATE; COBALT COMPLEX; COBALT OXIDE; ESTER; GRAPHENE; HYDROGEN; NITRILE; NITROGEN; OXYGEN; PHENANTHROLINE; UNCLASSIFIED DRUG; WATER; COBALT; NANOMATERIAL; OXIDE;

ARTICLE; GREEN CHEMISTRY; HYDROGENATION; NANOCATALYST; OXIDATION; OXIDATION REDUCTION REACTION; PRIORITY JOURNAL; PYROLYSIS; CATALYSIS; CHEMISTRY;

CATALYSIS; COBALT; GREEN CHEMISTRY TECHNOLOGY; HYDROGENATION; NANOSTRUCTURES; OXIDATION-REDUCTION; OXIDES;

EID: 84930064856     PISSN: 17542189     EISSN: 17502799     Source Type: Journal    
DOI: 10.1038/nprot.2015.049     Document Type: Article

References (26)

1. Price of metals, http://www.metalprices.com/.
2. Holzwarth, M.S. & Plietker, B. Biorelevant metals in sustainable metal catalysis: a survey. ChemCatChem 5, 1650-1679 (2013).
3. Bullock, R.M. Abundant metals give precious hydrogenation performance. Science 342, 1054-1055 (2013).
4. Que, L. Jr. & Tolman, W.B. Biologically inspired oxidation catalysis. Nature 455, 333-340 (2008).
5. Kobayashi, M. & Shimizu, S. Cobalt proteins. Eur. J. Biochem. 261, 1-9 (1999).
6. Gridnev, A.A. & Ittel, S.D. Catalytic chain transfer in free-radical polymerizations. Chem. Rev. 101, 3611-3660 (2001).
7. Kesavan, L. et al. Solvent-free oxidation of primary carbon-hydrogen bonds in toluene using Au-Pd alloy nanoparticles. Science 331, 195-199 (2011).
8. 3-based catalysts for selective hydrogenation of nitroarenes to anilines. Science 342, 1073-1076 (2013).
9. Nishimura, S. Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis (John Wiley & Sons, 2001).
10. Centi, G., Cavani, F. & Trifirò, F. Selective Oxidation by Heterogeneous Catalysis (Springer, 2001).
11. Westerhaus, F.A. et al. Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes. Nat. Chem. 5, 537-543 (2013).
12. 4-N@C catalysts under mild conditions. J. Am. Chem. Soc. 135, 10776-10782 (2013).
13. Jagadeesh, R.V., Junge, H. & Beller, M. Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts. Nat. Commun. 5, 4123 (2014).
14. 4/NGr@C-catalyst. Green Chem. 16, 4535-4540 (2014).
15. Parmeggiani, C. & Cardona, F. Transition metal based catalysts in the aerobic oxidation of alcohols. Green Chem. 14, 547-564 (2012).
16. Whittall, J. & Sutton, P. Practical Methods for Biocatalysis and Biotransformations 2 (John Wiley & Sons, 2012).
17. Kleemann, A., Engel, V., Kutscher, B. & Reichert, D. Pharmaceutical Substances: Syntheses, Patents, Applications of the Most Relevant APIs 4th ed. (Georg Thieme, 2001).
18. Fleming, F.F. Nitrile-containing natural products. Nat. Prod. Rep. 16, 597-606 (1999).
19. Rappoport, Z. Chemistry of the Cyano Group (Wiley, 1970).
20. Larock, R.C. Comprehensive Organic Transformations: A Guide to Functional Group Preparations (VCH, 1989).
21. Fraser, F.F., Lihua, Y., Ravikumar, P.C., Funk, L. & Shook, B.C. Nitrile-containing pharmaceuticals: efficacious roles of the nitrile pharmacophore. J. Med. Chem. 53, 7902-7917 (2010).
22. Anbarasan, P., Schareina, T. & Beller, M. Recent developments and perspectives in palladium-catalyzed cyanation, of aryl halides: synthesis of benzonitriles. Chem. Soc. Rev. 40, 5049-5067 (2011).
23. Martin, A. & Kalevaru, V.N. Heterogeneously catalyzed ammoxidation: A valuable tool for one-step synthesis of nitriles. ChemCatChem. 2, 1504-1522 (2010).
24. Otera, J. Esterification: methods, reactions, and applications. (Wiley-VCH, 2003).
25. Downing, R.S., Kunkeler, P.J. & van Bekkum, H. Catalytic syntheses of aromatic amines. Catal. Today 37, 121-136 (1997).
26. Ono, N. The Nitro Group in Organic Synthesis (Wiley-VCH, 2001).