Synergistic Stabilization of Emulsions and Emulsion Gels with Water-Soluble Polymers and Cellulose Nanocrystals

ACS Sustainable Chemistry and Engineering

Volumn 3, Issue 5, 2015, Pages 1023-1031

  Hu, Zhen ^a   Patten, Tyler ^a   Pelton, Robert ^a   Cranston, Emily D ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

Cellulose nanocrystals; Confocal microscopy; Emulsion gels; Hydroxyethyl cellulose; Interfacial tension; Methyl cellulose; Pickering emulsions

Indexed keywords

CELLULOSE; CONFOCAL MICROSCOPY; EMULSIFICATION; EMULSIONS; GELS; NANOCRYSTALS; OILS AND FATS; PHASE INTERFACES; PHASE SEPARATION; POLYMERS; QUARTZ; STABILIZATION; SURFACE TENSION;

CELLULOSE NANO-CRYSTALS; EMULSION GEL; HYDROXYETHYL CELLULOSE; METHYL CELLULOSE; PICKERING EMULSIONS;

CELLULOSE DERIVATIVES;

EMULSIONS; HYDROXYETHYL CELLULOSE; METHYL CELLULOSE; POLYMERS;

EID: 84929578505     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/acssuschemeng.5b00194     Document Type: Article

References (40)

1. Ramsden, W. Separation of solids in the surface-layers of solutions and "suspensions" (observations on surface-membranes, bubbles, emulsions, and mechanical coagulation). - Preliminary Account Proc. R. Soc. London 1903, 72, 156 - 164
2. Pickering, S. U. CXCVI.-Emulsions J. Chem. Soc., Trans. 1907, 91, 2001 - 2021
3. Binks, B. P.; Whitby, C. P. Nanoparticle silica-stabilised oil-in-water emulsions: Improving emulsion stability Colloids Surf., A 2005, 253, 105 - 115
4. Ashby, N. P.; Binks, B. P. Pickering emulsions stabilised by laponite clay particles Phys. Chem. Chem. Phys. 2000, 2, 5640 - 5646
5. Shen, M.; Resasco, D. E. Emulsions stabilized by carbon nanotube-silica nanohybrids Langmuir 2009, 25, 10843 - 10851
6. Zhou, J.; Qiao, X. Y.; Binks, B. P.; Sun, K.; Bai, M. W.; Li, Y. L.; Liu, Y. Magnetic Pickering emulsions stabilized by Fe3O4 nanoparticles Langmuir 2011, 27, 3308 - 3316
7. Larson-Smith, K.; Pozzo, D. C. Pickering emulsions stabilized by nanoparticle surfactants Langmuir 2012, 28, 11734 - 11741
8. Ngai, T.; Behrens, S. H.; Auweter, H. Novel emulsions stabilized by pH and temperature sensitive microgels Chem. Commun. 2005, 331 - 333
9. Kalashnikova, I.; Bizot, H.; Cathala, B.; Capron, I. New Pickering emulsions stabilized by bacterial cellulose nanocrystals Langmuir 2011, 27, 7471 - 7479
10. Habibi, Y.; Lucia, L. A.; Rojas, O. J. Cellulose nanocrystals: Chemistry, self-assembly, and applications Chem. Rev. 2010, 110, 3479 - 3500
11. The Global Market for Nanocellulose to 2020; Future Markets Inc.: Edinburgh, United Kingdom, 2012.
12. Kalashnikova, I.; Bizot, H.; Cathala, B.; Capron, I. Modulation of cellulose nanocrystals amphiphilic properties to stabilize oil/water interface Biomacromolecules 2011, 13, 267 - 275
13. Kalashnikova, I.; Bizot, H.; Bertoncini, P.; Cathala, B.; Capron, I. Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions Soft Matter 2013, 9, 952 - 959
14. Capron, I.; Cathala, B. Surfactant-free high internal phase emulsions stabilized by cellulose nanocrystals Biomacromolecules 2013, 14, 291 - 296
15. Hu, Z.; Ballinger, S.; Pelton, R.; Cranston, E. D. Surfactant-enhanced cellulose nanocrystal Pickering emulsions J. Colloid Interface Sci. 2015, 439, 139 - 148
16. Zoppe, J. O.; Venditti, R. A.; Rojas, O. J. Pickering emulsions stabilized by cellulose nanocrystals grafted with thermo-responsive polymer brushes J. Colloid Interface Sci. 2012, 369, 202 - 209
17. Tang, J.; Lee, M. F. X.; Zhang, W.; Zhao, B.; Berry, R. M.; Tam, K. C. Dual responsive Pickering emulsion stabilized by poly[2-(dimethylamino)ethyl methacrylate] grafted cellulose nanocrystals Biomacromolecules 2014, 15, 3052 - 3060
18. Saleh, N.; Phenrat, T.; Sirk, K.; Dufour, B.; Ok, J.; Sarbu, T.; Matyjaszewski, K.; Tilton, R. D.; Lowry, G. V. Adsorbed triblock copolymers deliver reactive iron nanoparticles to the oil/water interface Nano Lett. 2005, 5, 2489 - 2494
19. Feng, T.; Hoagland, D. A.; Russell, T. P. Assembly of acid-functionalized single-walled carbon nanotubes at oil/water interfaces Langmuir 2014, 30, 1072 - 1079
20. Okada, M.; Maeda, H.; Fujii, S.; Nakamura, Y.; Furuzono, T. Formation of Pickering emulsions stabilized via interaction between nanoparticles dispersed in aqueous phase and polymer end groups dissolved in oil phase Langmuir 2012, 28, 9405 - 9412
21. Edgar, K. J.; Buchanan, C. M.; Debenham, J. S.; Rundquist, P. A.; Seiler, B. D.; Shelton, M. C.; Tindall, D. Advances in cellulose ester performance and application Prog. Polym. Sci. 2001, 26, 1605 - 1688
22. Butchosa, N.; Zhou, Q. Water redispersible cellulose nanofibrils adsorbed with carboxymethyl cellulose Cellulose 2014, 21, 4349 - 4358
23. Laine, J.; Lindstrom, T.; Nordmark, G. G.; Risinger, G. Studies on topochemical modification of cellulosic fibres Part 1. Chemical conditions for the attachment of carboxymethyl cellulose onto fibres Nord. Pulp Pap. Res. J. 2000, 15, 520 - 526
24. Sundman, O. Adsorption of four non-ionic cellulose derivatives on cellulose model surfaces Cellulose 2014, 21, 115 - 124
25. Hu, Z.; Cranston, E. D.; Ng, R.; Pelton, R. Tuning cellulose nanocrystal gelation with polysaccharides and surfactants Langmuir 2014, 30, 2684 - 2692
26. Dickinson, E. Emulsion gels: The structuring of soft solids with protein-stabilized oil droplets Food Hydrocolloids 2012, 28, 224 - 241
27. Menner, A.; Ikem, V.; Salgueiro, M.; Shaffer, M. S. P.; Bismarck, A. High internal phase emulsion templates solely stabilised by functionalised titania nanoparticles Chem. Commun. 2007, 4274 - 4276
28. Tasset, S.; Cathala, B.; Bizot, H.; Capron, I. Versatile cellular foams derived from CNC-stabilized Pickering emulsions RSC Adv. 2014, 4, 893 - 898
29. Beck-Candanedo, S.; Roman, M.; Gray, D. G. Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions Biomacromolecules 2005, 6, 1048 - 1054
30. Abitbol, T.; Palermo, A.; Moran-Mirabal, J. M.; Cranston, E. D. Fluorescent labeling and characterization of cellulose nanocrystals with varying charge contents Biomacromolecules 2013, 14, 3278 - 3284
31. Lyons, W. J. Crystal density of native cellulose J. Chem. Phys. 1941, 9, 377 - 378
32. Beck-Candanedo, S.; Viet, D.; Gray, D. G. Induced phase separation in low-ionic strength cellulose nanocrystal suspensions containing high molecular weight blue dextrans Langmuir 2006, 22, 8690 - 8695
33. Zhang, J.; Pelton, R. Poly(N -isopropylacrylamide) microgels at the air-water interface Langmuir 1999, 15, 8032 - 8036
34. Kobayashi, K.; Huang, C.-i.; Lodge, T. P. Thermoreversible gelation of aqueous methylcellulose solutions Macromolecules 1999, 32, 7070 - 7077
35. Arvidson, S. A.; Lott, J. R.; McAllister, J. W.; Zhang, J.; Bates, F. S.; Lodge, T. P.; Sammler, R. L.; Li, Y.; Brackhagen, M. Interplay of phase separation and thermoreversible gelation in aqueous methylcellulose solutions Macromolecules 2012, 46, 300 - 309
36. Lott, J. R.; McAllister, J. W.; Arvidson, S. A.; Bates, F. S.; Lodge, T. P. Fibrillar structure of methylcellulose hydrogels Biomacromolecules 2013, 14, 2484 - 2488
37. Ghosh, S.; Rousseau, D. Fat crystals and water-in-oil emulsion stability Curr. Opin. Colloid Interface Sci. 2011, 16, 421 - 431
38. Vignati, E.; Piazza, R.; Lockhart, T. P. Pickering emulsions: Interfacial tension, colloidal layer morphology, and trapped-particle motion Langmuir 2003, 19, 6650 - 6656
39. van Vliet, T.; Lakemond, C. M. M.; Visschers, R. W. Rheology and structure of milk protein gels Curr. Opin. Colloid Interface Sci. 2004, 9, 298 - 304
40. Rodríguez-Abreu, C.; Lazzari, M. Emulsions with structured continuous phases Curr. Opin. Colloid Interface Sci. 2008, 13, 198 - 205