Separators for li-ion and li-metal battery including ionic liquid based electrolytes based on the TFSI- and FSI- anions

International Journal of Molecular Sciences

Volumn 15, Issue 8, 2014, Pages 14868-14890

  Kirchhöfer, Marija ^a   Von Zamory, Jan ^a   Paillard, Elie ^a   Passerini, Stefano ^a,b,c  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b HELMHOLTZ INSTITUTE ULM HIU   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Ionic liquids; Li ion; Lithium metal; Separator

Indexed keywords

BIS(FLUOROSULFONYL)IMIDE; BIS(TRIFLUOROMETHANESULFONYL)IMIDE; CELLULOSE; GLASS FIBER; IMIDE; IONIC LIQUID; LITHIUM ION; UNCLASSIFIED DRUG; LITHIUM;

ARTICLE; CHEMICAL STRUCTURE; CONTACT ANGLE; CYCLING; DENSITOMETRY; ELECTRIC BATTERY; ELECTRIC CONDUCTIVITY; ELECTRIC POTENTIAL; ELECTRIC RESISTANCE; ELECTRICITY; ELECTROCHEMICAL ANALYSIS; ELECTROLYTE TRANSPORT; ELECTROSTIMULATION; IMPEDANCE; INTERPHASE; PLATING MEDIUM; SCANNING ELECTRON MICROSCOPY; SOLID ELECTROLYTE INTERPHASE; WETTABILITY; CHEMISTRY; ELECTRODE; POWER SUPPLY;

ELECTRIC POWER SUPPLIES; ELECTRODES; IONIC LIQUIDS; LITHIUM;

EID: 84929348230     PISSN: 16616596     EISSN: 14220067     Source Type: Journal    
DOI: 10.3390/ijms150814868     Document Type: Article

References (48)

1. Jacobson, M.Z.; Delucchi, M.A. A Path to sustainable energy by 2030. Sci. Am. 2009, 301, 58-65.
2. Jacobson, M.Z.; Delucchi, M.A. Providing all global energy with wind, water, and solar power, Part I: Technologies, energy resources, quantities and areas of infrastructure, and materials. Energy Policy 2011, 39, 1154-1169.
3. Delucchi, M.A.; Jacobson, M.Z. Providing all global energy with wind, water, and solar power, Part II: Reliability, system and transmission costs, and policies. Energy Policy 2011, 39, 1170-1190.
4. Fong, R.; von Sacken, U.; Dahn, J.R. Studies of lithium intercalation into carbons using nonaqueous electrochemical cells. J. Electrochem. Soc. 1990, 137, 2009-2013.
5. Peled, E. The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems-The solid electrolyte interphase model. J. Electrochem. Soc. 1979, 126, 2047-2051.
6. Doughty, D.; Roth, P. A general discussion of Li ion battery safety. Electrochem. Soc. Interface 2012, 21, 37-44.
7. Arai, H.; Tsuda, M.; Saito, K.; Hayashi, M.; Sakurai, Y. Thermal reactions between delithiated lithium nickelate and electrolyte solutions. J. Electrochem. Soc. 2002, 149, 401-406.
8. Zinigrad, E.; Larush-Asraf, L.; Gnanaraj, J.S.; Sprecher, M.; Aurbach, D. On the thermal stability of LiPF6. Thermochim. Acta 2005, 438, 184-191.
9. Campion, C.L.; Li, W.; Lucht, B.L. Thermal decomposition of LiPF6-based electrolytes for lithium-ion batteries. J. Electrochem. Soc. 2005, 152, 2327-2334.
10. Barlowz, C.G. Reaction of water with hexafluorophosphates and with Li bis(perfluoroethylsulfonyl) imide salt. Electrochem. Solid State Lett. 1999, 2, 362-364.
11. Yang, H.; Zhuang, G.V.; Ross Jr., P.N. Thermal stability of LiPF6 salt and Li-ion battery electrolytes containing LiPF6. J. Power Sources 2006, 161, 573-579.
12. Vetter, J.; Novak, P.; Wagner, M.R.; Veit, C.; Möller, K.-C.; Besenhard, J.O.; Winter, M.; Wohlfahrt-Mehrens, M.; Vogler, C.; Hammouche, A. Ageing mechanisms in lithium-ion batteries. J. Power Sources 2005, 147, 269-281.
13. Armand, M. Materials for Advanced Batteries; Plenum Press: New York, NY, USA, 1980.
14. Lewandowski, A.; Swiderska-Mocek, A. Ionic liquids as electrolytes for Li-ion batteries-An overview of electrochemical studies. J. Power Sources 2009, 194, 601-609.
15. Armand, M.; Tarascon, J.-M. Building better batteries. Nature 2008, 451, 625-657.
16. Borgel, V.; Markevich, E.; Aurbach, D.; Semrau, G.; Schmidt, M. On the thermal behavior of model Li-LixCoO2 systems containing ionic liquids in standard electrolyte solutions, J. Power Sources 2009, 189, 331-336.
17. Armand, M.; Endres, F.; MacFarlane, D.R.; Ohno, H.; Scrosati, B. Ionic-liquid materials for the electrochemical challenges of the future. Nat. Mater. 2009, 8, 621-629.
18. Holzapfel, M.; Jost, C.; Novak, P. Stable cycling of graphite in an ionic liquid based electrolyte. Chem. Commun. 2004, 18, 2098-2099.
19. Sato, T.; Maruo, T.; Marukane, S.; Takagi, K. Ionic liquids containing carbonate solvent as electrolytes for lithium ion cells, J. Power Sources 2004, 138, 253-261.
20. Ishikawa, M.; Sugimoto, T.; Kikuta, M.; Ishiko, E.; Kono, M. Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries. J. Power Sources 2006, 162, 658-662.
21. Sugimoto, T.; Kikuta, M.; Ishiko, E.; Kono, M.; Ishikawa, M. Ionic liquid electrolytes compatible with graphitized carbon negative without additive and their effects on interfacial properties. J. Power Sources 2008, 183, 436-440.
22. Sugimoto, T.; Atsumi, Y.; Kikuta, M.; Ishiko, E.; Kono, M.; Ishikawa, M. Ionic liquid electrolyte systems based on bis(fluorosulfonyl)imide for lithium-ion batteries. J. Power Sources 2009, 189, 802-805.
23. Guerfi, A.; Duchesne, S.; Kobayashi, Y.; Vijh, A.; Zaghib, K. LiFePO4 and graphite electrodes with ionic liquids based on bis(fluorosulfonyl)imide (FSI)-For Li-ion batteries. J. Power Sources 2008, 175, 866-873.
24. Matsumoto, H.; Sakaebe, H.; Tatsumi, K.; Kikuta, M.; Ishiko, E.; Kono, M. Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide (FSI)-. J. Power Sources 2006, 160, 1308-1313.
25. Zhou, Q.; Henderson, W.A.; Appetecchi, G.B.; Montanino, M.; Passerini, S. Physical and electrochemical properties of N-alkyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide ionic liquids: PY13FSI and PY14FSI. J. Phys. Chem. 2008, 112, 13577-13580.
26. Paillard, E.; Zhou, Q.; Henderson, W.A.; Appetecchi, G.B.; Montanino, M.; Passerini, S. Electrochemical and physicochemical properties of PY14FSI-based electrolytes with LiFSI. J. Electrochem. Soc. 2009, 156, A891-A895.
27. Howlett, P.C.; MacFarlane, D.R.; Hollenkamp, A.F. High lithium metal cycling efficiency in a room-temperature ionic liquid. Electrochem. Solid State Lett. 2004, 7, A97-A101.
28. Kim, G.-T.; Appetecchi, G.B.; Montanino, M.; Alessandrini, F.; Passerini, S. Long-term cyclability of lithium metal electrodes in ionic liquid-based electrolytes at room temperature. ECS Trans. 2010, 25, 127-138.
29. Zhang, J.; Liu, Z.; Kong, Q.; Zhang, C.; Pang, S.; Yue, L.; Wang, X.; Yao, J.; Cui, G. Mussel inspired modification of polypropylene separators by catechol/polyamine for Li-ion batteries. ACS Appl. Mater. Interfaces 2012, 5, 128-134.
30. Zhang, S.S. A review on the separators of liquid electrolyte Li-ion batteries, J. Power Sources 2007, 164, 351-364.
31. Venugopal, G.; Moore, J.; Howard, J.; Pendalwar, S. Characterization of microporous separators for lithium-ion batteries. J. Power Sources 1999, 77, 34-41.
32. Arora, P.; Zhang, Z.J. Battery separators. Chem. Rev. 2004, 104, 4419-4462.
33. Hennige, V.; Hying, C.; Hoerpel, G.; Novak, P.; Vetter, J. Separator provided with asymmetrical pore structures for an electrochemical cell. U.S. Patent 7,709,140, 4 May 2010.
34. Kuribayashi, I. Characterization of composite cellulosic separators for rechargeable lithium-ion batteries. J. Power Sources 1996, 63, 87-91.
35. Jabbour, L.; Destro, M.; Chaussy, D.; Gerbaldi, C.; Penazzi, N.; Bodoardo, S.; Beneventi, D. Flexible cellulose/LiFePO4 paper-cathodes: Toward eco-friendly all-paper Li-ion batteries. Cellulose 2013 20, 571-582.
36. Peled, E.; Golodnitsky, D.; Ardel, G.; Eshkenazy, V. The SEI model-application to lithium-polymer electrolyte batteries. Electrochim. Acta 1995, 40, 2197-2204.
37. Chazalviel, J.-N. Electrochemical aspects of the generation of ramified metallic electrodeposits. Phys. Rev. A 1990, 42, 7355-7367.
38. Brissot, C.; Rosso, M.; Chazalviel, J.-N.; Lascaud, S. Dendritic growth mechanisms in lithium/polymer cells. J. Power Sources 1999, 925, 81-82.
39. Rosso, M.; Gobron, T.; Brissot, C.; Chazalviel, J.-N.; Lascaud, S. Onset of dendritic growth in lithium/polymer cells. J. Power Sources 2001, 804, 97-98.
40. Reiter, J.; Paillard, E.; Grande, L.; Winter, M.; Passerini, S. Physicochemical properties of N-methoxyethyl-N-methylpyrrolidinum ionic liquids with perfluorinated anions. Electrochim. Acta 2013, 91, 101-107.
41. Maier, J. Defect chemistry and conductivity effects in heterogeneous solid electrolytes. J. Electrochem. Soc. 1987, 134, 1524-1535.
42. Bhattacharyya, A.J.; Maier, J. Second phase effects on the conductivity of non-aqueous salt solutions: "Soggy Sand Electrolytes". Adv. Mater. 2004, 16, 811-814.
43. Capiglia, C.; Mustarelli, P.; Quartarone, E.; Tomasi, C.; Magistris, A. Effects of nanoscale SiO2 on the thermal and transport properties of solvent-free, poly(ethylene oxide) (PEO)-based polymer electrolytes. Solid State Ionics 1999, 118, 73-79.
44. Grande, L.; Paillard, E.; Kim, G.-T.; Monaco, S.; Passerini, S. Ionic liquid electrolytes for Li-air batteries: Lithium metal cycling. Int. J. Mol. Sci. 2014, 15, 8122-8137.
45. Bard, A.J.; Faulkner, L.R. Electrochemical Methods Fundamentals and Applications; Wiley and Son: New York, NY, USA, 2001.
46. Appetecchi, G.B.; Scaccia, S.; Tizzani, C.; Alessandrini, F.; Passerini, S. Synthesis of hydrophobic ionic liquids for electrochemical applications J. Electrochem. Soc. 2006, 153, A1685-A1691.
47. Appetecchi, G.B.; Montanino, M.; Zane, D.; Carewska, M.; Alessandrini, F.; Passerini, S. Effect of the alkyl group on the synthesis and the electrochemical properties of N-alkyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquids. Electrochim. Acta 2009, 54, 1325-1332.
48. MacMullin, R.B.; Muccini, G.A. Characteristics of porous beds and structures. AIChE J. 1956, 2, 393-403.