Deep and shallow TiO2 gap states on cleaved anatase single crystal (101) surfaces, nanocrystalline anatase films, and ALD titania ante and post annealing

Journal of Physical Chemistry C

Volumn 119, Issue 18, 2015, Pages 9890-9898

  Reckers, Philip ^a   Dimamay, Mariel ^a   Klett, Joachim ^a   Trost, Sara ^b   Zilberberg, Kirill ^b   Riedl, Thomas ^b   Parkinson, Bruce A ^c   Brötz, Joachim ^a   Jaegermann, Wolfram ^a   Mayer, Thomas ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF WUPPERTAL   (Germany)

^c UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS FILMS; ANNEALING; ATOMIC FORCE MICROSCOPY; ATOMIC LAYER DEPOSITION; FERMI LEVEL; FILM PREPARATION; NANOCRYSTALLINE ALLOYS; NANOCRYSTALS; PHOTOELECTRON SPECTROSCOPY; SINGLE CRYSTAL SURFACES; SINGLE CRYSTALS; SINTERING; SYNCHROTRON RADIATION; SYNCHROTRONS; TITANIUM;

AMORPHOUS TITANIA; ANATASE CRYSTALS; ANATASE NANOCRYSTALS; ATOMIC LAYER DEPOSITED; NANOCRYSTALLINE ANATASE; NANOPOROUS ANATASE; OXYGEN DEFECT; POST ANNEALING;

TITANIUM DIOXIDE;

EID: 84929008755     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b01264     Document Type: Article

References (50)

1. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
2. 2 Anatase Surfaces Phys. Rev. B 2001, 63, 155409
3. 2 Films Nature 1991, 353, 737-740
4. Trost, S Zilberberg, K Behrendt, A Polywka, A Görrn, P Reckers, P Maibach, J Mayer, T Riedl, T. Overcoming the "Light-Soaking" Issue in Inverted Organic Solar Cells by the Use of Al:ZnO Electron Extraction Layers Adv. Energy Mater. 2013, 3, 1437-1444
5. 2 Blocking Layer for High Efficiency Solid-State Perovskite Absorber Solar Cells Adv. Mater. 2014, 26, 4309-4312
6. Chen, Y. W Prange, J. D Duhnen, S Park, Y Gunji, M Chidsey, C. E. D McIntyre, P. C. Atomic Layer-Deposited Tunnel Oxide Stabilizes Silicon Photoanodes for Water Oxidation Nat. Mater. 2011, 10, 539-544
7. 2 Coatings Stabilize Si, Gaas, and Gap Photoanodes for Efficient Water Oxidation Science 2014, 344, 1005-1009
8. 2/Ru-Dye/Electrolyte Interface by Means of Photoelectron Spectroscopy Chem. Phys. 2002, 285, 157-165
9. Peter, L. Sticky Electrons" Transport and Interfacial Transfer of Electrons in the Dye-Sensitized Solar Cell Acc. Chem. Res. 2009, 42, 1839-1847
10. 2 Photoelectrochemical Cells J. Phys. Chem. 1996, 100, 17021-17027
11. 2-Electrolyte System Studied with Time-Resolved Photocurrents J. Phys. Chem. B 1997, 101, 2514-2518
12. Dloczik, L Ileperuma, O Lauermann, I Peter, L. M Ponomarev, E. A Redmond, G Shaw, N. J Uhlendorf, I. Dynamic Response of Dye-Sensitized Nanocrystalline Solar Cells: Characterization by Intensity-Modulated Photocurrent Spectroscopy J. Phys. Chem. B 1997, 101, 10281-10289
13. Hagfeldt, A Graetzel, M. Light-Induced Redox Reactions in Nanocrystalline Systems Chem. Rev. 1995, 95, 49-68
14. Bisquert, J Fabregat-Santiago, F Mora-Sero, I Garcia-Belmonte, G Barea, E. M Palomares, E. A Review of Recent Results on Electrochemical Determination of the Density of Electronic States of Nanostructured Metal-Oxide Semiconductors and Organic Hole Conductors Inorg. Chim. Acta 2008, 361, 684-698
15. Fabregat-Santiago, F Bisquert, J Garcia-Belmonte, G Boschloo, G Hagfeldt, A. Influence of Electrolyte in Transport and Recombination in Dye-Sensitized Solar Cells Studied by Impedance Spectroscopy Sol. Energy Mater. Sol. Cells 2005, 87, 117-131
16. 2 Surf. Sci. 1997, 384, 192-200
17. 3+ Species J. Phys. Chem. C 2009, 113, 20543-20552
18. 2 Single-Crystal Surfaces Using Resonant Photoemission and X-Ray Absorption Spectroscopy Phys. Rev. B 2007, 75, 035105
19. 2 (110) Surfaces Determined by Resonant Photoemission Phys. Rev. B 1991, 43, 12004-12011
20. 2 (101) and (001) Single Crystals Phys. Rev. B 2003, 67, 035110
21. Wendt, S. The Role of Interstitial Sites in the Ti3d Defect State in the Band Gap of Titania Science 2008, 320, 1755-1759
22. 2 Nanocrystals: Effect of Saturation and Sintering Energy Environ. Sci. 2013, 6, 1221-1229
23. 2(110) Chem. Soc. Rev. 2008, 37, 2328-2353
24. 2(110) J. Phys. Chem. B 2003, 107, 534-545
25. 2 (110) Phys. Rev. Lett. 2013, 110, 5
26. 2 (110) Surface Probed by Resonant Photoelectron Diffraction Phys. Rev. Lett. 2008, 100, 4
27. 2 Phys. Status Solidi RRL 2013, 7, 199-203
28. 2(110) Surface Phys. Rev. Lett. 2010, 105, 4
29. 2 Rutile and Anatase Phys. Rev. Lett. 2014, 113, 5
30. 2 Anatase (101) Angew. Chem., Int. Ed. 2014, 53, 4714-4716
31. 2 Phys. Rev. Lett. 2013, 110, 5
32. 2/Electrolyte Interface: Band Gap States and Their Interaction with Dye and Solvent Molecules J. Phys. Chem. C 2006, 111, 849-854
33. Anta, J. A. Electron Transport in Nanostructured Metal-Oxide Semiconductors Curr. Opin. Colloid Interface Sci. 2012, 17, 124-131
34. Schwanitz, K Mankel, E Hunger, R Mayer, T Jaegermann, W. Photoelectron Spectroscopy at the Solid-Liquid Interface of Dye-Sensitized Solar Cells: Unique Experiments with the Solid-Liquid Interface Analysis System Solias at Bessy Chimia 2007, 61, 796-800
35. 2 Phys. Rev. Lett. 1976, 36, 1335-1339
36. 3 Philos. Mag. 1974, 30, 389-402
37. 2 Anatase (101) Surface Phys. Rev. B 2000, 62, R16334-R16336
38. 2 (001) Anatase Crystal Examined by XPS Surf. Sci. Spectra 2002, 9, 21-29
39. 2(101) Nat. Mater. 2006, 5, 665-670
40. 2 (110)-(1 × 1) Surface Via UHV Cleavage: An Scanning Tunneling Microscopy Study Rev. Sci. Instrum. 2007, 78, 113907-1-113907-3
41. 2 Anatase Single Crystals Solid State Commun. 1993, 87, 847-850
42. 2 J. Phys. Chem. Lett. 2013, 4182-4187
43. 2, and SrO and the Associated Valence Band Offsets with Si(001) J. Vac. Sci. Technol. B 2004, 22, 2205-2215
44. 2 Anatase (101): Pitfalls and How to Avoid Them Surf. Sci. 2014, 626, 61-67
45. 2 Anatase (101) Surface Phys. Rev. Lett. 2012, 109, 136103
46. 2(101) Phys. Rev. Lett. 2009, 102
47. 2 J. Phys. Chem. C 2010, 114, 5891-5897
48. Feibelman, P. J Knotek, M. L. Reinterpretation of Electron-Stimulated Desorption Data from Chemisorption Systems Phys. Rev. B 1978, 18, 6531-6539
49. Gregoratti, L Mentes, T. O Locatelli, A Kiskinova, M. Beam-Induced Effects in Soft X-Ray Photoelectron Emission Microscopy Experiments J. Electron Spectrosc. Relat. Phenom. 2009, 170, 13-18
50. Menteş, T. O Locatelli, A Aballe, L Pavlovska, A Bauer, E Pabisiak, T Kiejna, A. Surface Modification of Oxides by Electron-Stimulated Desorption for Growth-Mode Control of Metal Films: Experiment and Density-Functional Calculations Phys. Rev. B 2007, 76, 155413