Hydrazine borane and hydrazinidoboranes as chemical hydrogen storage materials

Energies

Volumn 8, Issue 4, 2015, Pages 3118-3141

  Moury, Romain ^a   Demirci, Umit B ^b  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^b UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

Chemical hydrogen storage; Hydrazine borane; Hydrazinidoborane; Hydrolysis; Thermolysis

Indexed keywords

DEHYDROGENATION; HYDRAZINE; HYDROLYSIS; SOLUTIONS; THERMOLYSIS;

ALKALI HYDRIDES; CHEMICAL HYDROGEN STORAGE; EFFECTIVE POTENTIALS; HYDRAZINE BORANES; HYDRAZINIDOBORANE; HYDROLYTIC CONDITIONS; METAL-BASED CATALYSTS; SOLID RESIDUES;

HYDROGEN STORAGE;

EID: 84928654374     PISSN: None     EISSN: 19961073     Source Type: Journal    
DOI: 10.3390/en8043118     Document Type: Review

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74. Unpublished results. Typically, 10 mg of hydrazine borane were weighted and transferred in an agate mortar in an argon-filled glove box where the water and oxygen concentrations were kept below 0.1 ppm. Then, KH was added onto hydrazine borane with the help of a spatula. The addition was made carefully, almost grain by grain, and at each addition the reactivity was immediate, with an explosive formation of a brown gas and dispersion of products around the mortar.