Radiolysis as a solution for accelerated ageing studies of electrolytes in Lithium-ion batteries

Nature Communications

Volumn 6, Issue , 2015, Pages

  Ortiz, Daniel ^a   Steinmetz, Vincent ^b   Durand, Delphine ^a   Legand, Solène ^a   Dauvois, Vincent ^a   Maître, Philippe ^b   Le Caër, Sophie ^a  

^a CEA SACLAY   (France)

^b UNIVERSITÉ PARIS SUD   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACETALDEHYDE; BUTANE; CARBON DIOXIDE; CARBON MONOXIDE; DEUTERIUM; ELECTROLYTE; ETHANE; ETHER; ETHYLENE; FORMIC ACID; LITHIUM ION; METHANE; PROPANE;

ACCELERATION; CARBONATE GROUP; ELECTROLYTE; ION; IRRADIATION; LITHIUM; REACTION KINETICS; REDOX CONDITIONS;

AGING; ARTICLE; COLLISIONALLY ACTIVATED DISSOCIATION; DEGRADATION; DENSITY FUNCTIONAL THEORY; ELECTRIC BATTERY; ELECTROSPRAY MASS SPECTROMETRY; IONIZING RADIATION; IRRADIATION; MASS FRAGMENTOGRAPHY; OXIDATION REDUCTION REACTION; RADIOLYSIS;

EID: 84928616715     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms7950     Document Type: Article

References (48)

1. Wang, Q. et al. Molecular wiring of insulators: charging and discharging electrode materials for high-energy Lithium-ion batteries by molecular charge transport layers. J. Am. Chem. Soc. 129, 3163-3167 (2007
2. Armstrong, A. R. et al. Synthesis of tetrahedral LiFeO2 and its behavior as a cathode in rechargeable lithium batteries. J. Am. Chem. Soc. 130, 3554-3559 (2008
3. Tarascon, J. M. & Armand, M. Issues and challenges facing rechargeable Lithium batteries. Nature 414, 359-367 (2001
4. Hu, Y.-Y. et al. Origin of additional capacities in metal oxide Lithium-ion battery electrodes. Nat. Mater. 12, 1130-1136 (2013
5. Bhattacharyya, R. et al. In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries. Nat. Mater. 9, 504-510 (2010
6. Broussely, M. et al. Main aging mechanisms in Li ion batteries. J. Power Sources 146, 90-96 (2005
7. Vetter, J. et al. Ageing mechanisms in Lithium-ion batteries. J. Power Sources 147, 269-281 (2005
8. Fong, R., Vonsacken, U. & Dahn, J. R. Studies of lithium intercalation into carbons using nonaqueous electrochemical-cells. J. Electrochem. Soc. 137, 2009-2013 (1990
9. Jia-Yan, L., Wang-Jun, C., Ping, H. & Yong-Yao, X. Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte. Nat. Chem. 2, 760-765 (2010
10. Zonghai, C. et al. New class of nonaqueous electrolytes for long-life and safe lithium-ion batteries. Nat. Commun. 4, 1513 (2013
11. Bridel, J.-S. et al. Decomposition of ethylene carbonate on electrodeposited metal thin film anode. J. Power Sources 195, 2036-2043 (2010
12. Gachot, G. et al. Deciphering the multi-step degradation mechnanisms of carbonate-based electrolyte in Li batteries. J. Power Sources 178, 409-421 (2008
13. Gireaud, L. et al. Identification of Li battery electrolyte degradation products through direct synthesis and characterization of alkyl carbonate salts. J. Electrochem. Soc. 152, A850-A857 (2005
14. Gireaud, L. et al. Mass spectrometry investigations on electrolyte degradation products for the development of nanocomposite electrodes in lithium ion batteries. Anal. Chem. 78, 3688-3698 (2006
15. Kumai, K. et al. Gas generation mechanism due to electrolyte decomposition in commercial Lithium-ion cell. J. Power Sources 81, 715-719 (1999
16. Laruelle, S. et al. Identification of Li-based electrolyte degradation products through DEI and ESI High-Resolution Mass Spectrometry. J. Electrochem. Soc. 151, A1202-A1209 (2004
17. Yoshida, H. et al. Degradation mechanism of alkyl carbonate solvents used in lithium-ion cells during initial charging. J. Power Sources 68, 311-315 (1997
18. Spotheim-Maurizot, M., Mostafavi, M., Douki, T. & Belloni, J. Radiation Chemistry from Basics to Applications in Material and Life Sciences Ch.7 (EDP Sciences, 2012
19. Xu, K. Nonaqueous liquid electrolytes for Lithium-based rechargeable batteries. Chem. Rev. 104, 4303-4417 (2004
20. Isenberg, S. L., Armistead, P. M. & Glish, G. L. Optimization of peptide separations by differential ion mobility spectrometry. J. Am. Soc. Mass Spectrom 25, 1592-1599 (2014
21. Kanu, A. B. et al. Ion mobility-mass spectrometry. J. Mass Spectrom. 43, 1-22 (2008
22. Guevremont, R. High-field asymmetric waveform ion mobility spectrometry: a new tool for mass spectrometry. J. Chromat. A 1058, 3-19 (2004
23. Mac Aleese, L. et al. Mid-IR spectroscopy of protonated leucine methyl ester performed with an FTICR or a Paul type ion-trap. Int. J. Mass Spectrom. 249, 14-20 (2006
24. MacAleese, L. & Maitre, P. Infrared spectroscopy of organometallic ions in the gas phase: from model to real world complexes. Mass Spectrom. Rev. 26, 583-605 (2007
25. Simon, A. et al. Fingerprint vibrational spectra of protonated methyl esters of amino acids in the gas phase. J. Am. Chem. Soc. 129, 2829-2840 (2007
26. Lemaire, J. et al. Gas phase infrared spectroscopy of selectively prepared ions. Phys. Rev. Lett. 89 (2002
27. Torche, F. et al. Picosecond pulse radiolysis of the liquid diethyl carbonate. J. Phys. Chem. A 117, 10801-10810 (2013
28. Ganghi, N. S., Rao, D. N. R. & Symons, M. C. R. Radical cations of organic carbonates, trimethyl borate and methyl nitrate-A Radiation Electron-Spin-Resonance Study. J. Chem. Soc. Faraday Trans. I 82, 2367-2376 (1986
29. Shkrob, I. A., Zhu, Y., Marin, T. W. & Abraham, D. Reduction of carbonate electrolytes and the formation of solid-electrolyte interface (SEI) in Lithium-ion batteries. 1. spectroscopic observations of radical intermediates generated in oneelectron reduction of carbonates. J. Phys. Chem. C 117, 19255-19269 (2013
30. Shkrob, I. A., Zhu, Y., Marin, T. W. & Abraham, D. Reduction of carbonate electrolytes and the formation of solid-electrolyte interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically induced polymerization of ethylene carbonate. J. Phys. Chem. C 117, 19270-19279 (2013
31. Kondoh, T. et al. Femtosecond pulse radiolysis study on geminate ion recombination in n-dodecane. Rad. Phys. Chem. 80, 286-290 (2011
32. Matsui, M. & Imamura, M. Radiation chemical studies with cyclotron beams. 3. Heavy-ion radiolysis of liquid aliphatic-ketones. Bull. Chem. Soc. Jpn 47, 1113-1116 (1974
33. Ausloos, P. & Trumbore, C. N. Radiolysis of CH3COOCH3 and CH3COOCD3 by cobalt-60 gamma-rays. J. Am. Chem. Soc. 81, 3866-3871 (1959
34. Hall, K. L., Bolt, R. O. & Carroll, J. K. Radiation Effects on Organic Materials Vol. 104 (Academic, 1963
35. Matsuta, S. et al. Electron-spin-resonance study of the reaction of electrolytic solutions on the positive electrode for lithium-ion secondary batteries. J. Electrochem. Soc. 148, A7-A10 (2001
36. Sasaki, T. et al. Formation mechanism of alkyl dicarbonates in Li-ion cells. J. Power Sources 150, 208-215 (2005
37. Dedryvere, R. et al. Characterization of lithium alkyl carbonates by X-Ray photoelectron spectroscopy: experimental and theoretical Study. J. Phys. Chem. B 109, 15868-15875 (2005
38. Dedryvere, R. et al. XPS identification of the organic and inorganic components of the electrode/electrolyte interface formed on a metallic cathode. J. Electrochem. Soc. 152, A689-A696 (2005
39. Fricke, H. & Hart, E. J. in Radiation Dosimetry (eds Attix, F. H. & Roesch, W. C.) Vol. 2, 167-232 (Academic, 1966
40. Mialocq, J. C., Hickel, B., Baldacchino, G. & Juillard, M. The radiolysis project of CEA. J. Chim. Phys 96, 35-43 (1999
41. Fourdrin, C. et al. Water radiolysis in exchanged-montmorillonites: the H2 production mechanisms. Environ. Sci. Technol. 47, 9530-9537 (2001
42. Le Caer, S. et al. Modifications under irradiation of a self-assembled monolayer grafted on a nanoporous silica glass: a solid-state NMR characterization. J. Phys. Chem. C 116, 4748-4759 (2012
43. Prazeres, R. et al. Two-colour operation of a free-electron laser and applications in the mid-infrared. Eur. Phys. J. D 3, 87-93 (1998
44. Gaussian 03 (Gaussian, Inc., Wallingford, CT, 2004
45. Becke, A. D. Density-functional thermochemistry 3. The role of exact exchange. J. Chem. Phys. 98, 5648-5652 (1993
46. Lee, C. T., Yang, W. T. & Parr, R. G. Development of the Colle-Salvetti correlation energy formula into a functional of the electron density. Phys. Rev. B 37, 785-789 (1988
47. Halls, M. D. & Schlegel, H. B. Comparison of the performance of local, gradient-corrected, and hybrid density functional models in predicting infrared intensities. J. Chem. Phys. 109, 10587-10593 (1998
48. Halls, M. D., Velkovski, J. & Schlegel, H. B. Harmonic frequency scaling factors for Hartree-Fock, S-VWN, B-LYP, B3-LYP, B3-PW91 and MP2 with the Sadlej pVTZ electric property basis set. Theo. Chem. Accounts 105, 413-421 (2001).