Hybrid cationic ring-opening polymerization of epoxy resin/glycidyloxypropyl-polyhedral oligomeric silsesquioxane nanocomposites and dynamic mechanical properties

Iranian Polymer Journal (English Edition)

Volumn 24, Issue 4, 2015, Pages 299-307

  Hou, Guixiang ^a,b   Li, Na ^a   Han, Hongzhe ^a   Huo, Li ^a   Gao, Jungang ^a  

^a HEBEI UNIVERSITY   (China)

^b HEBEI UNITED UNIVERSITY   (China)

Author keywords

Cationic ring opening polymerization; Epoxy resin; Hybrid composites; Silsesquioxanes; Thermomechanical properties

Indexed keywords

ACTIVATION ENERGY; BENZOYL PEROXIDE; CATIONIC POLYMERIZATION; CHEMICAL ACTIVATION; CURING; DYNAMICS; ELASTIC MODULI; EPOXY RESINS; HYDROLYSIS; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; MECHANICAL PROPERTIES; NANOCOMPOSITES; OLIGOMERS; POLYMERIZATION; POLYMERS; REACTION KINETICS;

BISPHENOL A EPOXY RESIN; CATIONIC RING OPENING POLYMERIZATION; DYNAMIC MECHANICAL PROPERTY; HYBRID COMPOSITES; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; SILSESQUIOXANES; THERMAL POLYMERIZATIONS; THERMOMECHANICAL PROPERTIES;

RING OPENING POLYMERIZATION;

EID: 84928168363     PISSN: 10261265     EISSN: 17355265     Source Type: Journal    
DOI: 10.1007/s13726-015-0321-8     Document Type: Article

References (31)

1. Mohan P (2013) A critical review: the modification, properties, and applications of epoxy resins. Polym Plast Technol Eng 52:107–125
2. Clayton AM (1988) Epoxy resins chemistry and technology, 2nd edn. Marcel Dekker, New York
3. Jin H, Mangun CL, Griffin AS, Moore JS, Sottos NR, White SR (2014) Thermally stable autonomic healing in epoxy using a dual-microcapsule system. Adv Mater 26:282–287
4. Rakshit PB, Jain RC, Shah SR, Shrinet V (2011) Synthesis and characterization of cycloaromatic polyamines to cure epoxy resin for industrial applications. Polym Plast Technol Eng 50:647–680
5. Crivello JV, Lam JHW (1977) Diaryliodonium salts. A new class of photoinitiators for cationic polymerization. Macromolecules 10:1307–1315
6. Wang T, Wang ZH (2005) Cationic photopolymerization of epoxy systems initiated by cyclopentadien-iron-biphenyl hexafluorophosphate ([Cp-Fe-biphenyl]+PF6 −). Polym Bull 53:323–331
7. Abu-Abdoun II, Ledwith A (2007) Photoinitiated cationic polymerization of epoxide and vinyl monomers by p-trimethoxytrityl salts. J Polym Res 14:99–105
8. Oxman JD, Jacobs DW, Trom MC, Sipani V, Ficek B, Scranton AB (2005) Evaluation of initiator systems for controlled and sequentially curable free-radical/cationic hybrid photopolymerizations. J Polym Sci, Part A: Polym Chem 43:1747–1756
9. Sangermano M, Malucelli G, Priola A, Mannea M (2006) Synthesis and characterization of acrylate-oxetane interpenetrating polymer networks through a thermal-UV dual cure process. Prog Org Coat 55:225–230
10. Pappas SP (1985) Photoinitiation of cationic and concurrent radical-cationic polymerization. Part V. Prog Org Coat 13:35–64
11. Chen M, Chen QD, Xiao SQ, Hong XY (2001) The mechanism and application of hybrid UV curing system. Photogr Sci Photochem 19:208–216
12. Park YJ, Lim DH, Kim HJ, Park DS, Sung IK (2009) UV- and thermal-curing behaviors of dual-curable adhesives based on epoxy acrylate oligomers. Int J Adhes Adhes 29:710–717
13. Qi YS, Meng X, Yang JW, Zeng ZH, Chen YL (2005) Synthesis and properties of ultraviolet/moisture dual-curable polysiloxane acrylates. J Appl Polym Sci 96:846–853
14. Hofmeier H, El-Ghayoury A, Schubert US (2004) Free radical and thermal curing of terpyridine-modified terpolymers. J Polym Sci, Part A: Polym Chem 42:4028–4035
15. Crivello JV, Lam JHW (1981) Redox cationic polymerization: the diaryliodonium salt/ascorbate redox couple. J Polym Sci, Part A: Polym Chem 19:539–548
16. Hou GX, Gao JG, Tian C (2013) Hybrid free radical-cationic thermal polymerization of methylacryloylpropyl-POSS/epoxy resins nanocomposites. J Polym Res 20:221–231
17. Shokrieh MM, Esmkhani M, Vahedi F, Shahverdi HR (2013) Improvement of mechanical and electrical properties of epoxy resin with carbon nanofibers. Iran Polym J 22:721–727
18. Wang J, Feng L, Feng Y, Yan A, Ma X (2012) Preparation and properties of organic rectorite/epoxy resin nano-composites. Polym Plast Technol Eng 51:1583–1588
19. Frank KL, Exley SE, Thornell TL, Morgan SE, Wiggins JS (2012) Investigation of pre-reaction and cure temperature on multiscale dispersion in POSS-epoxy nanocomposites. Polymer 53:4643–4651
20. Chen SH, Gao JG, Han HZ, Wang C (2014) Mechanical and thermal properties of epoxy-POSS reinforced-(biphenyl diol formaldehyde/epoxy hybrid resin) composites. Iran Polym J 23:609–617
21. Pistor V, Ornaghi FG, Ornaghi HL Jr, Zattera AJ (2012) Degradation kinetic of epoxy nanocomposites containing different percentage of epoxycyclohexyl-POSS. Polym Compos 33:1224–1232
22. Choi J, Yee AF, Laine RM (2003) Organic/inorganic hybrid composites from cubic silsesquioxanes. Epoxy resins of octa(dimethylsiloxyethylcyclohexylepoxide) silsesquioxane. Macromolecules 36:5666–5682
23. Gao JG, Kong DJ, Zhao HC, Li SR (2011) Curing kinetics, thermal, mechanical, and dielectric properties based on o-cresol formaldehyde epoxy resin with polyhedral oligomeric (N-aminoethyl-g-aminopropyl) silsesquioxane. Polym Adv Technol 22:1395–1402
24. Crivello JV (1979) Photoinitiators. US patent 4136102 A
25. Saito H, Isosaki M, Ando H (2002) Manufacturing methods of cage-type silsesquioxane resins with functional groups. Jpn Kokai patent 285387
26. Rosu D, Mititelu A, Cascaval CN (2004) Cure kinetics of a liquid-crystalline epoxy resin studied by non-isothermal data. Polym Test 23:209–215
27. Kissinger HE (1957) Reaction kinetics in differential thermal analysis. Anal Chem 29:1702–1706
28. Vyazovkin S, Sbirrazzuoli N (2003) Isoconversional analysis of calorimetric data on nonisothermal crystallization of a polymer melt. J Phy Chem B 107:882–888
29. Vyazovkin S, Mititelu A, Sbirrazzuoli N (2003) Kinetics of epoxy–amine curing accompanied by the formation of liquid crystalline structure. Macromol Rapid Commun 24:1060–1065
30. Gillham JK (1977) The TBA torsion pendulum: a technique for characterizing the cure and properties of thermosetting systems. Polym Int 44:262–276
31. Achorn PJ, Ferrillo RG (1994) Comparison of thermal techniques for glass transition measurements of polystyrene and cross-linked acrylic polyurethane films. J Appl Polym Sci 54:2033–2043