Photodegradation of 2-methyl-4-chlorophenol in a KrCl exciplex flow-through photoreactor: a kinetic study

Desalination and Water Treatment

Volumn 54, Issue 7, 2015, Pages 1862-1871

  Tchaikovskaya, O N ^a   Karetnikova, E ^b   Murcia, M D ^c   Gomez M ^c   Gomez J L ^c  

^a TOMSK STATE UNIVERSITY   (Russian Federation)

^b INSTITUTE OF BIOLOGY AND SOIL SCIENCE   (Russian Federation)

^c UNIVERSITY OF MURCIA   (Spain)

Author keywords

2 Methyl 4 chlorophenol; Excilamp; KrCl photoreactor; Photodegradation; UV

Indexed keywords

EID: 84927570781     PISSN: 19443994     EISSN: 19443986     Source Type: Journal    
DOI: 10.1080/19443994.2014.891079     Document Type: Article

References (21)

1. A. Zertal, T. Sehili, P. Boule, Photochemical behaviour of 4-chloro-2-methylphenoxyacetic acid:Influence of pH and irradiation wavelength, J. Photochem. Photobiol. A 146 (2001) 37–48.10.1016/S1010-6030(01)00534-2
2. S. Irmak, E. Kusvuran, O. Erbatur, Degradation of 4-chloro-2-methylphenol in aqueous solution by UV irradiation in the presence of titanium dioxide, Appl. Catal. B 54 (2004) 85–91.10.1016/j.apcatb.2004.06.003
3. E. Arias, Effects of the phenoxy herbicide MCPA on SCE frequency and cell kinetics in developing chick embryos, Ecotoxicol. Environ. Saf. 33 (1996) 25–29.10.1006/eesa.1996.0002
4. J.J. Aaron, M.A. Oturan, New photochemical and electrochemical methods for the degradation of pesticides in aqueous media. Environmental applications, Turkish J. Chem. 25 (2001) 509–520.
5. D. Vialaton, C. Richard, D. Baglio, A. Paya-Perez, Phototransformation of 4-chloro-2-methylphenol in water: Influence of humic substances on the reaction, J. Photochem. Photobiol. A 119 (1998) 39–45.10.1016/S1010-6030(98)00401-8
6. H.D. Burrows, M. Canle L, J.A. Santaballa, S. Steenken, Reaction pathways and mechanisms of photodegradation of pesticides, J. Photochem. Photobiol. 67 (2002) 71–108.10.1016/S1011-1344(02)00277-4
7. 2, J. Photochem. Photobiol. A 140 (2001) 249–253.10.1016/S1010-6030(01)00415-4
8. S. Irmak, H.I. Yavuz, O. Erbatur, Degradation of 4-chloro-2-methylphenol in aqueous solution by electro-Fenton and photoelectro-Fenton processes, Appl. Catal. B 63 (2006) 243–248.10.1016/j.apcatb.2005.10.008
9. V.B. Batoev, G.G. Matafonova, N.I. Filippova, Direct photolysis of chlorophenols in aqueous solutions by UV radiation from excilamps, Russ. J. Appl. Chem. 84 (2011) 407–411.10.1134/S1070427211030128
10. 2 barrier-discharge excilamps: A comparative study, Chem. Eng. J. 158 (2010) 120–128.10.1016/j.cej.2009.12.015
11. G. Matafonova, N. Christofi, V. Batoev, E. Sosnin, Degradation of chlorophenols in aqueous media using UV XeBr excilamp in a flow-through reactor, Chemosphere 70 (2008) 1124–1127.10.1016/j.chemosphere.2007.08.022
12. M. Gomez, M.D. Murcia, E. Gomez, J.L. Gomez, R. Dams, N. Christofi, Enhancement of 4-chlorophenol photodegradation with KrCl excimer UV lamp by adding hydrogen peroxide, Sep. Sci. Technol. 45 (2010) 1603–1609.10.1080/01496395.2010.487714
13. M.D. Murcia, M. Gómez, E. Gómez, J.L. Gómez, A.M. Hidalgo, N. Christofi, A new substrate and by-product kinetic model for the photodegradation of 4-chlorophenol with KrCl exciplex UV lamp and hydrogen peroxide, Chem. Eng. J. 187 (2012) 36–44.10.1016/j.cej.2012.01.069
14. E.A. Sosnin, T. Oppenländer, Victor F. Tarasenko, Applications of capacitive and barrier discharge excilamps in photoscience, J. Photochem. Photobiol. C 7 (2006) 145–163.10.1016/j.jphotochemrev.2006.12.002
15. I.V. Sokovola, O.N. Tchaikovskaya, V.A. Svetlichnyi, R.T. Kuznetsova, T.N. Kopylova, G.V. Maier, E.A. Sosnin, E.A. Kipatov, V.F. Tarasenko, Phototransformations of phenols in aqueous solutions under different excitation model, High Energ. Chem. 36 (2002) 272–275.
16. M. Gomez, M.D. Murcia, J.L. Gomez, G. Matafonova, V. Batoev, N. Christofi, Testing a KrCl excilamp as new enhanced UV source for 4-chlorophenol degradation: Experimental results and kinetic model, Chem. Eng. Process 49 (2010) 113–119.10.1016/j.cep.2009.11.016
17. O.N. Tchaikovskaya, E.A. Karetnikova, I.V. Sokolova, G.V. Mayer, D.A. Shvornev, The phototransformation of 4-chloro-2-methylphenoxyacetic acid under KrCl and XeBr excilamps irradiation in water, J. Photochem. Photobiol. A 228 (2012) 8–14.10.1016/j.jphotochem.2011.11.004
18. M. Gomez, M.D. Murcia, J.L. Gomez, E. Gomez, M.F. Maximo, A. Garcia, A KrCl exciplex flow-through photoreactor for degrading 4-chlorophenol: Experimental and modelling, Appl. Catal. B 117–118 (2012) 194–203.10.1016/j.apcatb.2012.01.017
19. J.A. Zazo, J.A. Casas, A.F. Mohedano, M.A. Gilarranz, J.J. Rodríguez, Chemical pathway and kinetics of phenol oxidation by fenton's reagent, Environ. Sci. Technol. 39 (2005) 9295–9302.10.1021/es050452h
20. K.H. Jones, P.W. Trudgill, D.J. Hopper, Metabolism of p-cresol by the fungus Aspergillus fumigatus, Appl. Environ. Microbiol. 59 (1993) 1125–1130.
21. R.D. Mair, A.J. Graupner, Determination of organic peroxides by iodine liberation procedures, Anal. Chem. 36 (1964) 1125–1130.