Helical jump motions of poly(l -Lactic Acid) chains in the α phase as revealed by solid-state NMR

Journal of Physical Chemistry B

Volumn 119, Issue 12, 2015, Pages 4552-4563

  Chen, Wei ^a   Reichert, Detlef ^b   Miyoshi, Toshikazu ^a  

^a University of Akron   (United States)

^b MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CHAINS; CHEMICAL SHIFT; CRYSTALLINE MATERIALS; GLASS TRANSITION; LACTIC ACID; LIGHT POLARIZATION; MOLECULAR DYNAMICS;

CHAIN DIFFUSION; CHEMICAL SHIFT ANISOTROPY; CRYSTALLINE REGIONS; HIGH RESOLUTION; INCREASING TEMPERATURES; POLY L LACTIC ACID; SOLID-STATE NMR SPECTROSCOPY; TWO-DIMENSIONAL EXCHANGE;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 84925946939     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/acs.jpcb.5b00694     Document Type: Article

References (62)

1. Hoffman, J. D.; Williams, G.; Passaglia, E. Analysis of the α, and Relaxations in Polychlorotrifluoroethylene and Polyethylene: Dielectric and Mechanical Properties J. Polym. Sci. Part C 1966, 235, 173-235
2. Kentgens, A. P. M.; de Boer, E.; Veeman, W. S. Ultraslow molecular motions in crystalline polyoxymethylene. A complete elucidation using two-dimensional solid state NMR J. Chem. Phys. 1987, 87, 6859-6866
3. 13C NMR Macromolecules 1999, 32, 1611-1619
4. Schaefer, D.; Spiess, H. W.; Suter, U. W.; F, W. W. Two-Dimensional Solid-state NMR Studies of Ultraslow Chain Motion: Glass Transition in Atactic Poly(propy1ene) versus Helical Jumps in Isotactic Poly(propy1ene) Macromolecules 1990, 23, 3431-3439
5. Kang, J.; Miyoshi, T. Two Chain-Packing Transformations and Their Effects on the Molecular Dynamics and Thermal Properties of α-Form Isotactic Poly(propylene) under Hot Drawing: A Solid-State NMR Study Macromolecules 2014, 47, 2993-3004
6. Li, Z.; Miyoshi, T.; Sen, M. K.; Koga, T.; Otsubo, A.; Kamimura, A. Solid-State NMR Characterization of the Chemical Defects and Physical Disorders in α Form of Isotactic Poly(propylene) Synthesized by Ziegler-Natta Catalysts Macromolecules 2013, 46, 6507-6519
7. Miyoshi, T.; Mamun, A.; Hu, W. Molecular Ordering and Molecular Dynamics in Isotactic-Polypropylene Characterized by Solid State NMR J. Phys. Chem. B 2010, 114, 92-100
8. 13C MAS Exchange NMR Macromolecules 2004, 37, 6460-6471
9. 13C NMR Spectroscopy Macromolecules 2002, 35, 2624-2632
10. Schmidt-Rohr, K.; Spiess, H. Multidimensional solid-state NMR and polymers; Academic Press: London, 1994.
11. Hu, W.-G.; Schmidt-Rohr, K. Polymer ultradrawability: the crucial role of α-relaxation chain mobility in the crystallites Acta Polym. 1999, 50, 271-285
12. 13C NMR Macromolecules 1991, 24, 5288-5293
13. Barenwald, R.; Goerlitz, S.; Godehardt, R.; Osichow, A.; Tong, Q.; Krumova, M.; Mecking, S.; Saalwachter, K. Local Flips and Chain Motion in Polyethylene Crystallites: A Comparison of Melt-Crystallized Samples, Reactor Powders, and Nanocrystals Macromolecules 2014, 47, 5163-5173
14. Barenwald, R.; Champouret, Y.; Saalwachter, K.; Schaler, K. Determination of Chain Flip Rates in Poly(ethylene) Crystallites by Solid-State Low-Field 1H NMR for Two Different Sample Morphologies J. Phys. Chem. B 2012, 116, 13089-13097
15. Yao, Y.-F.; Graf, R.; Spiess, H. W.; Rastogi, S. Restricted Segmental Mobility Can Facilitate Medium-Range Chain Diffusion: A NMR Study of Morphological Influence on Chain Dynamics of Polyethylene Macromolecules 2008, 41, 2514-2519
16. Yao, Y.; Graf, R.; Spiess, H.; Rastogi, S. Influence of Crystal Thickness and Topological Constraints on Chain Diffusion in Linear Polyethylene Macromol. Rapid Commun. 2009, 30, 1123-1127
17. Yao, Y.-F.; Graf, R.; Spiess, H.; Lippits, D.; Rastogi, S. Morphological differences in semicrystalline polymers: Implications for local dynamics and chain diffusion Phys. Rev. E 2007, 76, 060801
18. Barenwald, R.; Goerlitz, S.; Godehardt, R.; Osichow, A.; Tong, Q.; Krumova, M.; Mecking, S.; Saalwachter, K. Correction to Local Flips and Chain Motion in Polyethylene Crystallites: A Comparison of Melt-Crystallized Samples, Reactor Powders, and Nanocrystals Macromolecules 2014, 47, 7677-7678
19. Spiess, H. W. Structure and Dynamics of Solid Polymers from 2D and 3D NMR Chem. Rev. 1991, 91, 1321-1338
20. Sin, L. T.; Rahmat, A. R.; Rahman, W. A. W. A. Polylactic Acid: PLA Biopolymer Technology and Applications; Elsevier: Oxford, U.K., 2012.
21. Nyambo, C.; Mohanty, A. K.; Misra, M. Polylactide-Based Renewable Green Composites from Agricultural Residues and Their Hybrids Biomacromolecules 2010, 11, 1654-1660
22. Yang, Q.; Hirata, M.; Lu, D.; Nakajima, H.; Kimura, Y. Highly Efficient Reinforcement of Poly- l -lactide Materials by Polymer Blending of a Thermotropic Liquid Crystalline Polymer Biomacromolecules 2010, 12, 354-358
23. Bai, H.; Huang, C.; Xiu, H.; Zhang, Q.; Deng, H.; Wang, K.; Chen, F.; Fu, Q. Significantly Improving Oxygen Barrier Properties of Polylactide via Constructing Parallel-Aligned Shish-Kebab-Like Crystals with Well-Interlocked Boundaries Biomacromolecules 2014, 15, 1507-1514
24. Tang, H.; Chen, J. B.; Wang, Y.; Xu, J. Z.; Hsiao, B. S.; Zhong, G. J.; Li, Z. M. Shear Flow and Carbon Nanotubes Synergistically Induced Nonisothermal Crystallization of Poly(lactic acid) and Its Application in Injection Molding Biomacromolecules 2012, 13, 3858-3867
25. De Santis, P.; Kovacs, J. Molecular conformation of poly(S-lactic acid) Biopolymers 1968, 6, 299-306
26. Zhang, J.; Duan, Y.; Sato, H.; Tsuji, H.; Noda, I.; Yan, S.; Ozaki, Y. Crystal Modifications and Thermal Behavior of Poly(l -lactic acid) Revealed by Infrared Spectroscopy Macromolecules 2005, 38, 8012-8021
27. Eling, B.; Gogolewski, S.; Pennings, A. J. Biodegradable materials of poly(l -lactic acid): 1. Melt-spun and solution-spun fibres Polymer 1982, 23, 1587-1593
28. Cartier, L.; Okihara, T.; Ikada, Y.; Tsuji, H.; Puiggali, J.; Lotz, B. The frustrated structure of poly(l -lactide) Polymer 2000, 41, 8909-8919
29. Ikada, Y.; Jamshidi, K.; Tsuji, H.; Hyon, S.-H. Stereocomplex Formation between Enantiomeric Poly(lactides) Macromolecules 1987, 904-906
30. Wasanasuk, K.; Tashiro, K.; Hanesaka, M.; Ohhara, T.; Kurihara, K.; Kuroki, R.; Tamada, T.; Ozeki, T.; Kanamoto, T. Crystal Structure Analysis of Poly(l -lactic Acid) α Form on the Basis of the 2-Dimensional Wide-Angle Synchrotron X-ray and Neutron Diffraction Measurements Macromolecules 2011, 44, 6441-6452
31. Bras, A. R.; Malik, P.; Dionsio, M.; Mano, J. Influence of Crystallinity in Molecular Motions of Poly(l -lactic acid) Investigated by Dielectric Relaxation Spectroscopy Macromolecules 2008, 41, 6419-6430
32. Kanchanasopa, M.; Runt, J. Broadband Dielectric Investigation of Amorphous and Semicrystalline l -Lactide/meso-Lactide Copolymers Macromolecules 2004, 37, 863-871
33. 13C NMR Investigations on Crystalline Structure and Molecular Dynamics of Polymorphic Poly(l -lactide) and Poly(l -lactide)/Poly(d -lactide) Stereocomplex Macromolecules 2011, 45, 189-197
34. 13C NMR analyses of the structures of crystallized and quenched poly(lactide)s: Effects of crystallinity, water absorption, hydrolytic degradation, and tacticity Polymer 2010, 51, 2215-2220
35. 13C CP-MAS NMR Studies of the Crystallinity and Morphology of Poly(l -lactide) Macromolecules 1996, 29, 8844-8851
36. 13C NMR Spectroscopy Macromolecules 1992, 25, 4114-4118
37. DeAzevedo, E. R.; Hu, W.-G.; Bonagamba, T. J.; Schmidt-Rohr, K. Centerband-Only Detection of Exchange: Efficient Analysis of Dynamics in Solids by NMR J. Am. Chem. Soc. 1999, 121, 8411-8412
38. Miyoshi, T.; Mamun, A. Critical roles of molecular dynamics in the superior mechanical properties of isotactic-poly(1-butene) elucidated by solid-state NMR Polym. J. 2011, 44, 65-71
39. Miyoshi, T.; Pascui, O.; Reichert, D. Large-Amplitude Motions of Form III of Isotactic Poly(4-methyl-1-pentene) Crystallites Prior to Crystal-Crystal Transformation Macromolecules 2004, 37, 6653-6656
40. Tang, C.; Inomata, A.; Sakai, Y.; Yokoyama, H.; Miyoshi, T.; Ito, K. Effects of Chemical Modification on the Molecular Dynamics of Complex Polyrotaxanes Investigated by Solid-State NMR Macromolecules 2013, 46, 6898-6907
41. Miyoshi, T.; Hu, W.; Li, Y. Dynamic Geometry and Kinetics of Polymer Confined in Self-Assembly via Cooperative Hydrogen Bonding: A Solid-State NMR Study under Paramagnetic Doping Macromolecules 2010, 43, 4435-4437
42. Fischer, E. W.; Sterzel, H. J.; Wegner, G. Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions Kolloid-Zeitschrift und Zeitschrift fur Polym. 1973, 251, 980-990
43. Loomis, G. L.; Murdoch, J. R.; Gardner, K. H. Polylactide stereocomplexes Polym. Prepr. 1990, 31, 55
44. 207Pb MAS Spectra of Solid Lead Nitrate. An Accurate, Sensitive Thermometer for Variable-Temperature MAS J. Magn. Reson. Ser. A 1995, 116, 215-220
45. Pawlak, T.; Jaworska, M.; Potrzebowski, M. J. NMR crystallography of α-poly(l -lactide) Phys. Chem. Chem. Phys. 2013, 15, 3137-3145
46. Kittel, C.; McEuen, P. Introduction to Solid State Physics; Wiley: New York, 1976.
47. Chen, W.; Sun, H.-J.; Miyoshi, T. Unique Molecular Dynamics of Structural Elements in an Asymmetric Janus Bisamide Supramolecule Characterized by Solid-State NMR J. Phys. Chem. B 2013, 117, 13698-13709
48. Pascui, O.; Beiner, M.; Reichert, D. Identification of Slow Dynamic Processes in Poly(n-hexyl Methacrylate) by Solid-State 1D-MAS Exchange NMR Macromolecules 2003, 3992-4003
49. Durrett, R. Probability: theory and examples, 4 th ed.; Cambridge University Press, 2010.
50. Perrin, C. L.; Dwyer, T. J. Application of Two-Dimensional NMR to Kinetics of Chemical Exchange Chem. Rev. 1990, 2, 935-967
51. 13C Solid-state NMR Macromolecules 1984, 17, 2182-2192
52. Schaler, K.; Achilles, A.; Barenwald, R.; Hackel, C.; Saalwachter, K. Dynamics in Crystallites of Poly(-caprolactone) As Investigated by Solid-State NMR Macromolecules 2013, 46, 7818-7825
53. Tsuji, H.; Ikada, Y. Stereocomplex formation between enantiomeric poly(lactic acid)s. XI. Mechanical properties and morphology of solution-cast film Polymer 1999, 40, 6699-6708
54. Fu, Y.; Yimin, R. B.; Affholter, K. A.; Wunderlich, B. Poly(ethylene terephthalate) Fibers. 1. Crystal Structure and Morphology Studies with Full-Pattern X-ray Diffraction Refinement Macromolecules 1993, 26, 2187-2193
55. Wang, Z.-G.; Hsiao, B. S.; Sauer, B. B.; Kampert, W. G. The nature of secondary crystallization in poly(ethylene terephthalate) Polymer 1999, 40, 4615-4627
56. Neppalli, R.; Marega, C.; Marigo, A.; Bajgai, M. P.; Kim, H. Y.; Causin, V. Improvement of tensile properties and tuning of the biodegradation behavior of polycaprolactone by addition of electrospun fiber Polymer 2011, 52, 4054-4060
57. Kawai, T.; Rahman, N.; Matsuba, G.; Nishida, K.; Kanaya, T.; Nakano, M.; Okamoto, H.; Kawada, J.; Usuki, A.; Honma, N. Crystallization and Melting Behavior of Poly(l -lactic Acid) Macromolecules 2007, 40, 9463-9469
58. Ashcraft, C. R.; Boyd, R. H. A Dielectric Study of Molecular Relaxation in Oxidized and Chlorinated Polyethylenes J. Polym. Sci. Polym. Phys. Ed. 1976, 14, 2153-2193
59. Spiess, H. W. Interplay of Structure and Dynamics in Macromolecular and Supramolecular Systems Macromolecules 2010, 43, 5479-5491
60. Hu, W.; Cai, T. Regime Transitions of Polymer Crystal Growth Rates: Molecular Simulations and Interpretation beyond Lauritzen-Hoffman Model Macromolecules 2008, 41, 2049-2061
61. Hong, Y.; Miyoshi, T. Elucidation of the Chain-Folding Structure of a Semicrystalline Polymer in Single Crystals by Solid-State NMR ACS Macro Lett. 2014, 3, 556-559
62. 13C Double Quantum NMR ACS Macro Lett. 2013, 2, 501-505