Magnetic yolk-shell structured anatase-based microspheres loaded with Au nanoparticles for heterogeneous catalysis

Nano Research

Volumn 8, Issue 1, 2015, Pages 238-245

  Wang, Chun ^a   Chen, Junchen ^a   Zhou, Xinran ^a   Li, Wei ^a   Liu, Yong ^a   Yue, Qin ^a   Xue, Zhaoteng ^a   Li, Yuhui ^a   Elzatahry, Ahmed A ^b,c   Deng, Yonghui ^a   Zhao, Dongyuan ^a  

^a FUDAN UNIVERSITY   (China)

^b KING SAUD UNIVERSITY   (Saudi Arabia)

^c City for Scientific Research and Technology Applications ^*  (Egypt)

Author keywords

gold nanoparticles; heterogeneous catalysis; magnetic microspheres; titania; yolk shell structure

Indexed keywords

EID: 84925487159     PISSN: 19980124     EISSN: 19980000     Source Type: Journal    
DOI: 10.1007/s12274-014-0647-0     Document Type: Article

References (50)

1. Liu, J.; Qiao, S. Z.; Chen, J. S.; Lou, X. W.; Xing, X. R.; Lu, G. Q. Yolk/shell nanoparticles: New platforms for nanoreactors, drug delivery and lithium-ion batteries. Chem. Commun.2011, 47, 12578–12591.
2. Tang, F. Q.; Li, L. L.; Chen, D. Mesoporous silica nanoparticles: Synthesis, biocompatibility and drug delivery. Adv. Mater.2012, 24, 1504–1534.
3. Chaudhuri, R. G.; Paria, S. Core/shell nanoparticles: Classes, properties, synthesis mechanisms, characterization, and applications. Chem. Rev.2012, 112, 2373–2433.
4. Kamata, K.; Lu, Y.; Xia, Y. N. Synthesis and characterization of monodispersed core-shell spherical colloids with movable cores. J. Am. Chem. Soc.2003, 125, 2384–2385.
5. Zhou, W. D.; Yu, Y. C.; Chen, H.; DiSalvo, F. J.; Abruña, H. D. Yolk-shell structure of polyaniline-coated sulfur for lithium-sulfur batteries. J. Am. Chem. Soc.2013, 135, 16736–16743.
6. Zhang, W.-M.; Hu, J.-S.; Guo, Y.-G.; Zheng, S.-F.; Zhong, L.-S.; Song, W.-G.; Wan, L.-J. Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv. Mater.2008, 20, 1160–1165.
7. Chen, Z.; Cui, Z.-M.; Niu, F.; Jiang, L.; Song, W.-G. Pd nanoparticles in silica hollow spheres with mesoporous walls: A nanoreactor with extremely high activity. Chem. Commun.2010, 46, 6524–6526.
8. Arnal, P. M.; Comotti, M.; Schüth, F. High-temperature-stable catalysts by hollow sphere encapsulation. Angew. Chem. Int. Ed.2006, 45, 8224–8227.
9. Guan, B. Y.; Wang, T.; Zeng, S, J.; Wang, X.; An, D.; Wang, D. M.; Cao, Y.; Ma, D. X.; Liu, Y. L.; Huo, Q. S. A versatile cooperative template-directed coating method to synthesize hollow and yolk-shell mesoporous zirconium titanium oxide nanospheres as catalytic reactors. Nano Res.2014, 7, 246–262.
10. Liu, H. Y.; Chen, D.; Li, L. L.; Liu, T. L.; Tan, L. F.; Wu, X. L.; Tang, F. Q. Multifunctional gold nanoshells on silica nanorattles: A platform for the combination of photothermal therapy and chemotherapy with low systemic toxicity. Angew. Chem. Int. Ed.2011, 50, 891–895.
11. Liu, J.; Qiao, S. Z.; Hartono, S. B.; Lu, G. Q. Monodisperse yolk-shell nanoparticles with a hierarchical porous structure for delivery vehicles and nanoreactors. Angew. Chem. Int. Ed.2010, 49, 4981–4985.
12. Chen, Y.; Chen, H. R.; Guo, L. M.; He, Q. J.; Chen, F.; Zhou, J.; Feng, J. W.; Shi, J. L. Hollow/rattle-type mesoporous nanostructures by a structural difference-based selective etching strategy. ACS Nano2010, 4, 529–539.
13. Demirörs, A. F.; van Blaaderen, A.; Imhof, A. A general method to coat colloidal particles with titania. Langmuir2010, 26, 9297–9303.
14. 2 cage structures. Small2011, 7, 2037–2040.
15. Li, W.; Deng, Y. H.; Wu, Z. X.; Qian, X. F.; Yang, J. P.; Wang, Y.; Gu, D.; Zhang, F.; Tu, B.; Zhao, D. Y. Hydrothermal etching assisted crystallization: A facile route to functional yolk-shell titanate microspheres with ultrathin nanosheets-assembled double shells. J. Am. Chem. Soc.2011, 133, 15830–15833.
16. Cao, L.; Chen, D. H.; Caruso, R. A. Surface-metastable phase-initiated seeding and Ostwald ripening: A facile fluorine-free process towards spherical fluffy core/shell, yolk/shell, and hollow anatase nanostructures. Angew. Chem. Int. Ed.2013, 52, 10986–10991.
17. 2 shells for multifunctional core-shell structures. J. Am. Chem. Soc.2012, 134, 11864–11867.
18. Joo, J. B.; Zhang, Q.; Lee, I.; Dahl, M.; Zaera, F.; Yin, Y. D. Mesoporous anatase titania hollow nanostructures through silica-protected calcination. Adv. Funct. Mater.2012, 22, 166–174.
19. Zhang, Q.; Lima, D. Q.; Lee, I.; Zaera, F.; Chi, M. F.; Yin, Y. D. A highly active titanium dioxide based visible-light photocatalyst with nonmetal doping and plasmonic metal decoration. Angew. Chem. Int. Ed.2011, 50, 7088–7092.
20. 2 nanoparticles on graphene for high-performance lithium ion batteries. J. Am. Chem. Soc.2013, 135, 18300–18303.
21. 2 nanostructures with favorable architectures. J. Am. Chem. Soc.2011, 133, 19314–19317.
22. Sun, Z. K.; Yue, Q.; Liu, Y.; Wei, J.; Li, B.; Kaliaguine, S.; Deng, Y. H.; Wu, Z. X.; Zhao, D. Y. Rational synthesis of super-paramagnetic core-shell structured mesoporous microspheres with large pore sizes. J. Mater. Chem. A2014, 2, 18322–18328.
23. Deng, Y. H.; Cai, Y.; Sun, Z. K.; Zhao, D. Y. Magnetically responsive ordered mesoporous materials: A burgeoning family of functional composite nanomaterials. Chem. Phys. Lett.2011, 510, 1–13.
24. 2 microspheres with a tunable mesoporous anatase shell for highly selective and effective enrichment of phosphopeptides. ACS Nano2012, 6, 3179–3188.
25. Reddy, L. H.; Arias, J. L.; Nicolas, J.; Couvreur, P. Magnetic nanoparticles: Design and characterization, toxicity and biocompatibility, pharmaceutical and biomedical applications. Chem. Rev.2012, 112, 5818–5878.
26. 2 nanosheets as a magnetically separable photocatalyst. Chem. Commun.2011, 47, 2631–2633.
27. Shylesh, S.; Schünemann, V.; Thiel, W. R. Magnetically separable nanocatalysts: Bridges between homogeneous and heterogeneous catalysis. Angew. Chem. Int. Ed.2010, 49, 3428–3459.
28. Wang, M. H.; Sun Z. K.; Yue, Q.; Yang, J.; Wang, X. Q. Deng, Y. H.; Yu, C. Z.; Zhao, D. Y. An interface-directed co-assembly approach to synthesize uniform large-pore mesoporous silica spheres. J. Am. Chem. Soc.2014, 136, 1884–1892.
29. 2 hollow colloids and magnetic multifunctional particles. Adv. Mater.2008, 20, 1853–1858.
30. Sun, Z. K.; Yang, J. P.; Wang, J. X.; Li, W.; Kaliaguine, S.; Hou, X. F.; Deng, Y. H.; Zhao, D. Y. A versatile designed synthesis of magnetically separable nano-catalysts with well-defined core-shell nanostructures. J. Mater. Chem. A2014, 2, 6071–6074.
31. Liu, J.; Sun, Z. K.; Deng, Y. H.; Zou, Y.; Li, C. Y.; Guo, X. H.; Xiong, L. Q.; Gao, Y.; Li, F. Y.; Zhao, D. Y. Highly water-dispersible biocompatible magnetite particles with low cytotoxicity stabilized by citrate groups. Angew. Chem. Int. Ed.2009, 48, 5875–5879.
32. Deng, Y. H.; Cai, Y.; Sun, Z. K.; Liu, J.; Liu, C.; Wei, J.; Li, W.; Liu, C.; Wang, Y.; Zhao, D. Y. Multifunctional mesoporous composite microspheres with well-designed nanostructure: A highly integrated catalyst system. J. Am. Chem. Soc.2010, 132, 8466–8473.
33. Stöber, W.; Fink, A.; Bohn, E. Controlled growth of monodisperse silica spheres in the micron size range. J. Colloid Interface Sci.1968, 26, 62–69.
34. 2 shell for removal of microcystins J. Am. Chem. Soc.2008, 130, 28–29.
35. 2@C yolk-shell nanospheres as a high-performance anode material for lithium ion batteries. Nanoscale2014, 6, 3217–3222.
36. Chen, J. C.; Xue, Z. T.; Feng, S. S.; Tu, B.; Zhao, D. Y. Synthesis of mesoporous silica hollow nanospheres with multiple gold cores and catalytic activity. J. Colloid Interface Sci.2014, 429, 62–67.
37. Fang, X. L.; Liu, S. J.; Zang, J.; Xu, C. F.; Zheng, M.-S.; Dong, Q.-F.; Sun, D. H.; Zheng, N. F. Precisely controlled resorcinol-formaldehyde resin coating for fabricating core-shell, hollow, and yolk-shell carbon nanostructures. Nanoscale2013, 5, 6908–6916.
38. 4@C nanospheres. J. Mater. Chem. A2013, 1, 7488–7493.
39. Li, N.; Zhang, Q.; Liu, J.; Joo, J.; Lee, A.; Gan, Y.; Yin, Y. D. Sol-gel coating of inorganic nanostructures with resorcinol-formaldehyde resin. Chem. Commun.2013, 49, 5135–5137.
40. Fuertes, A. B.; Valle-Vigón, P.; Sevilla, M. One-step synthesis of silica@resorcinol-formaldehyde spheres and their application for the fabrication of polymer and carbon capsules. Chem. Commun.2012, 48, 6124–6126.
41. Zhang, J. Y.; Deng, Y. H.; Gu, D.; Wang, S. T.; She, L.; Che, R. C.; Wang, Z.-S.; Tu, B.; Xie, S. H.; Zhao, D. Y. Ligand-assisted assembly approach to synthesize large-pore ordered mesoporous titania with thermally stable and crystalline framework. Adv. Energy Mater.2011, 1, 241–248.
42. Lee, J.; Orilall, M. C.; Warren, S. C.; Kamperman, M.; Disalvo, F. J.; Wiesner, U. Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores. Nat. Mater.2008, 7, 222–228.
43. Zhu, H. G.; Liang, C. D.; Yan, W. F.; Overbury, S. H.; Dai, S. Preparation of highly active silica-supported Au catalysts for CO oxidation by a solution-based technique. J. Phys. Chem. B2006, 110, 10842–10848.
44. Chen, J. C.; Zhang, R. Y.; Han, L.; Tu, B.; Zhao, D. Y. One-pot synthesis of thermally stable gold@mesoporous silica core-shell nanospheres with catalytic activity. Nano Res.2013, 6, 871–879.
45. Li, Y. H.; Wei, J.; Luo, W.; Wang, C.; Li, W.; Feng, S. S.; Yue, Q.; Wang, M. H.; Elzatahry, A. A.; Deng, Y. H.; Zhao, D. Y. Tricomponent coassembly approach to synthesize ordered mesoporous carbon/silica nanocomposites and their derivative mesoporous silicas with dual porosities. Chem. Mater.2014, 26, 2438–2444.
46. Wang, M. H.; Wang, X. Q.; Yue, Q.; Zhang, Y.; Wang, C.; Chen, J.; Cai, H. Q.; Lu, H. L.; Elzatahry, A. A.; Zhao, D. Y.; Deng, Y. H. Templated fabrication of core-shell magnetic mesoporous carbon microspheres in 3-dimensional ordered macroporous silicas. Chem. Mater.2014, 26, 3316–3321.
47. Wang, C.; Wei, J.; Yue, Q.; Luo, W.; Li, Y. H.; Wang, M. H.; Deng, Y. H.; Zhao, D. Y. A shear stress regulated assembly route to silica nanotubes and their closely packed hollow mesostructures. Angew. Chem. Int. Ed.2013, 52, 11603–11606.
48. Wei, J.; Yue, Q.; Sun, Z. K.; Deng, Y. H.; Zhao, D. Y. Synthesis of dual-mesoporous silica using non-ionic diblock copolymer and cationic surfactant as co-templates. Angew. Chem. Int. Ed.2012, 51, 6149–6153.
49. Xu, R.; Wang, D. S.; Zhang, J. T.; Li, Y. D. Shape-dependent catalytic activity of silver nanoparticles for the oxidation of styrene. Chem. Asian J.2006, 1, 888–893.
50. 2 as oxidizing agent. J. Catal.1995, 156, 163–166.