Co-non-solvency: Mean-field polymer theory does not describe polymer collapse transition in a mixture of two competing good solvents

Journal of Chemical Physics

Volumn 142, Issue 11, 2015, Pages

  Mukherji, Debashish ^a   Marques, Carlos M ^a,b   Stuehn, Torsten ^a   Kremer, Kurt ^a  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^b UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

MIXTURES; SOLVENTS;

CHEMICAL DETAILS; CONCENTRATION FLUCTUATION; CONFORMATIONAL TRANSITIONS; POLYMER COLLAPSE; POLYMER COLLAPSE TRANSITION; PUZZLING PHENOMENA; SOLVENCY EFFECTS; THERMODYNAMIC TREATMENT;

POLYMERS;

EID: 84925047386     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.4914870     Document Type: Article

References (37)

1. D. Mukherji, C. M. Marques, and K. Kremer, Nat. Commun. 5, 4882 (2014). 10.1038/ncomms5882
2. M. A. Cohen-Stuart, W. T. S. Huck, J. Genzer, M. Müller, C. Ober, M. Stamm, G. B. Sukhorukov, I. Szleifer, V. V. Tsukruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, and S. Minko, Nat. Mater. 9, 101 (2010). 10.1038/nmat2614
3. M. A. Ward and T. K. Georgiou, Polymers 3, 1215 (2011). 10.3390/polym3031215
4. S. de Beer, E. Kutnyanszky, P. M. Schön, G. J. Vancso, and M. H. Müser, Nat. Commun. 5, 3781 (2014). 10.1038/ncomms4781
5. S. de Beer and M. H. Müser, Macromolecules 47, 7666 (2014). 10.1021/ma501718b
6. H. G. Schild, M. Muthukumar, and D. A. Tirrell, Macromolecules 24, 948 (1991). 10.1021/ma00004a022
7. G. Zhang and C. Wu, Phys. Rev. Lett. 86, 822 (2001). 10.1103/PhysRevLett.86.822
8. J. Walter, J. Sehrt, J. Vrabec, and H. Hasse, J. Phys. Chem. B 116, 5251 (2012). 10.1021/jp212357n
9. H. Kojima, F. Tanaka, C. Scherzinger, and W. Richtering, J. Polym. Sci., Part B: Polym. Phys. 51, 1100 (2012). 10.1002/polb.23194
10. F. Tanaka, T. Koga, and F. M. Winnik, Phys. Rev. Lett. 101, 028302 (2008). 10.1103/PhysRevLett.101.028302
11. J. Walter, V. Ermatchkov, J. Vrabec, and H. Hasse, Fluid Phase Equilib. 296, 164 (2010). 10.1016/j.fluid.2010.03.025
12. A. K. Tucker and M. J. Stevens, Macromolecules 45, 6697 (2012). 10.1021/ma300729z
13. J. Heyda, A. Muzdalo, and J. Dzubiella, Macromolecules 46, 1231 (2013). 10.1021/ma302320y
14. D. Mukherji and K. Kremer, Macromolecules 46, 9158 (2013). 10.1021/ma401877c
15. F. Rodriguez-Ropero and N. F. A. van der Vegt, J. Phys. Chem. B 118, 7327 (2014). 10.1021/jp504065e
16. A. Hiroki, Y. Maekawa, M. Yoshida, K. Kubota, and R. Katakai, Polymer 42, 1863 (2001). 10.1016/S0032-3861(00)00416-X
17. R. Lund, L. Willner, J. Stellbrink, A. Radulescu, and D. Richter, Macromolecules 37, 9984 (2004). 10.1021/ma035633n
18. A. R. Shultz and P. J. Flory, J. Polym. Sci. 15, 231 (1955). 10.1002/pol.1955.120157919
19. B. E. Read, Trans. Faraday Soc. 56, 382 (1960). 10.1039/tf9605600382
20. B. A. Wolf and M. M. Willms, Makromol. Chem. 179, 2265 (1978). 10.1002/macp.1978.021790914
21. F. M. Winnik, H. Ringsdorf, and J. Venzmer, Macromolecules 23, 2415 (1990). 10.1021/ma00210a048
22. M. Ohkura, T. Kanaya, and K. Kaji, Polymer 33, 3686 (1992). 10.1016/0032-3861(92)90656-H
23. Y. Kiritoshi and K. Ishihara, J. Biomater. Sci., Polym. Ed. 13, 213 (2002). 10.1163/156856202317414384
24. Y. Kiritoshi and K. Ishihara, Sci. Technol. Adv. Mater. 4, 93 (2003). 10.1016/S1468-6996(03)00010-X
25. H. N. Lee and T. P. Lodge, J. Phys. Chem. Lett. 1, 1962 (2010). 10.1021/jz100617t
26. G. Hernandez-Sosa, N. Bornemann, I. Ringle, M. Agari, E. Dörsam, N. Mechau, and U. Lemmer, Adv. Funct. Mater. 23, 3164 (2013). 10.1002/adfm.201202862
27. K. Kremer and G. S. Grest, J. Chem. Phys. 92, 5057 (1990). 10.1063/1.458541
28. C. Jeppesen and K. Kremer, Eur. Phys. Lett. 34, 563 (1996). 10.1209/epl/i1996-00495-1
29. J. S. Higgins and H. C. Benoit, Polymers and Neutron Scattering, Oxford Series on Neutron Scattering in Condensed Matter (Clarendon Press, 1997).
30. D. Mukherji, C. M. Marques, T. Stühn, and K. Kremer, " Co-non-solvency as a design principle for smart heteropolymer architectures " (unpublished).
31. P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, London, 1979).
32. J. Des Cloizeaux and G. Jannink, Polymers in Solution: Their Modelling and Structure (Clarendon Press, Oxford, 1990).
33. J. G. Kirkwood and F. P. Buff, J. Chem. Phys. 19, 774 (1951). 10.1063/1.1748352
34. J. Rösgen, B. M. Pettitt, and D. W. Bolen, Biophys. J. 89, 2988 (2005). 10.1529/biophysj.105.067330
35. T. L. Hill, An Introduction to Statistical Thermodynamics (Courier Dover Publications, 1960).
36. J. D. Halverson, T. Brandes, O. Lenz, A. Arnold, S. Bevc, V. Starchenko, K. Kremer, T. Stuehn, and D. Reith, Comput. Phys. Commun. 184, 1129 (2013). 10.1016/j.cpc.2012.12.004
37. W. Humphrey, A. Dalke, and K. Schulten, J. Mol. Graphics 14, 33 (1996). 10.1016/0263-7855(96)00018-5