Polybenzimidazole based polymeric ionic liquids (PILs): Effects of controlled degree of N-quaternization on physical and gas permeation properties

Journal of Membrane Science

Volumn 481, Issue , 2015, Pages 19-27

  Rewar, Anita S ^a   Bhavsar, Rupesh S ^a   Sreekumar, K ^a   Kharul, Ulhas K ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Degree of quaternization; Gas permeation; Polybenzimidazole; Polymeric ionic liquid

Indexed keywords

CARBON DIOXIDE; CHAINS; GAS PERMEABILITY; GASES; IONIC LIQUIDS; LIQUIDS; POLYMERS;

AMORPHOUS POLYMERS; DEGREE OF QUATERNIZATION; GAS PERMEATION; GAS PERMEATION PROPERTIES; IONIC INTERACTION; POLYBENZIMIDAZOLE; POLYMERIC IONIC LIQUIDS; STRUCTURAL VARIATIONS;

GAS PERMEABLE MEMBRANES;

BENZIMIDAZOLE; IONIC LIQUID; POLYBENZIMIDAZOLE; POLYMERIC IONIC LIQUID; UNCLASSIFIED DRUG;

ARTICLE; DENSITY; GAS PERMEABILITY; MECHANICS; N QUATERNIZATION; PHYSICAL PARAMETERS; PRIORITY JOURNAL; SOLUBILITY; THERMOSTABILITY;

EID: 84924942672     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2015.02.004     Document Type: Article

References (46)

1. 2/light gas separation performance of cross-linked poly(vinylimidazolium) gel membranes as a function of ionic liquid loading and cross-linker content. J. Membr. Sci. 2012, 397-398:24-37.
2. 2/light gas separation performance of poly(vinylimidazolium) membranes and poly(vinylimidazolium)-ionic liquid composite films. Ind. Eng. Chem. Res. 2013, 52:1023-1032.
3. D' Alessandro D.M., Smit B., Long J.R. Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. Ed. 2010, 49:6058-6082.
4. 2. Polym. Adv. Technol. 2012, 23:835-840.
5. 2/He separation at temperatures up to 125°C. J. Membr. Sci. 2007, 298:41-47.
6. 2 capture with ionic liquids. Chin. J. Chem. Eng. 2012, 20:120-129.
7. 2 capture in ionic liquids: a review of solubilities and experimental methods. J. Chem. 2013, 2013:473584-473599.
8. 2: conventional versus ionic-liquid based technologies. Russ. Chem. Rev. 2012, 81:435-457.
9. 2 separation applying ionic liquid mixtures: the effect of mixing different anions on gas permeation through supported ionic liquid membranes. RSC Adv. 2013, 3:12220-12229.
10. Neves L.A., Crespo J.G., Coelhoso I.M. Gas permeation studies in supported ionic liquid membranes. J. Membr. Sci. 2010, 357:160-170.
11. 2 selectivity prediction in supported ionic liquid membranes (SILMs) by COSMO-RS. Ind. Eng. Chem. Res. 2011, 50:5739-5748.
12. 4 separation. Chem. Eng. J. 2011, 166:401-406.
13. FernDandez F.J.H., de los RDios A.P., Rubio M., Alonso F.T., GDomez D., VDillora G. A novel application of supported liquid membranes based on ionic liquids to the selective simultaneous separation of the substrates and products of a trans esterification reaction. J. Membr. Sci. 2007, 293:73-80.
14. 2 separations in imidazolium-based room-temperature ionic liquids. Ind. Eng. Chem. Res. 2009, 48:2739-2751.
15. Cserjesi P., Nemestothy N., Bako K.B. Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids. J. Membr. Sci. 2010, 349:6-11.
16. 2 through supported magnetic ionic liquid membranes (SMILMs). Sep. Purif. Technol. 2012, 97:26-33.
17. Yuan J., Mecerreyes D., Antonietti M. Poly(ionic liquid)s: an update. Progr. Polym. Sci. 2013, 38:1009-1036.
18. Mecerreyes D. Polymeric ionic liquids: broadening the properties and applications of polyelectrolytes. Progr. Polym. Sci. 2011, 36:1629-1648.
19. Green O., Grubjesic S., Lee S., Firestone M.A. The design of polymeric ionic liquids for the preparation of functional materials. J. Macromol. Sci. C: Polym. Rev. 2009, 49:339-360.
20. 2 absorption. Chem. Commun. 2005, 3325-3327.
21. 2 selectivity relative to methane and nitrogen. J. Membr. Sci. 2006, 281:130-138.
22. 2 selectivity in polymerized room-temperature ionic liquid gas separation membranes through incorporation of polar substituents. J. Membr. Sci. 2008, 321:3-7.
23. 2 separation. J. Membr. Sci. 2011, 370:141-148.
24. Li P., Zhao Q., Anderson J.L., Varanasi S., Coleman M.R. Synthesis of copolyimides based on room temperature ionic liquid diamines. J. Polym. Sci. Part A: Polym. Chem. 2010, 48:4036-4046.
25. 2 separation from flue gas using polyvinyl-(room temperature ionic liquid)-room temperature ionic liquid composite membranes. Ind. Eng. Chem. Res. 2011, 50:9344-9353.
26. 2 sorption. J. Membr. Sci. 2012, 389:305-315.
27. 2 separation. RSC Adv. 2014, 4:4500-4503.
28. Bhavsar R.S., Kumbharkar S.C., Rewar A.S., Kharul U.K. Polybenzimidazole based film forming polymeric ionic liquids: synthesis and effects of cation-anion variation on their physical properties. Polym. Chem. 2014, 5:4083-4096.
29. Bhavsar R.S., Kumbharkar S.C., Kharul U.K. Investigation of gas permeation properties of film forming polymeric ionic liquids (PILs) based on polybenzimidazoles. J. Membr. Sci. 2014, 470:494-503.
30. Madar J., Xiao L., Schmidt T., Benicewicz B.C. Polybenzimidazole/acid complexes as high-temperature membranes. Adv. Polym. Sci. 2008, 216:63-124.
31. Kumbharkar S.C., Karadkar P.B., Kharul U.K. Enhancement of gas permeation properties of polybenzimidazoles by systematic structure architecture. J. Membr. Sci. 2006, 286:161-169.
32. Kumbharkar S.C., Kharul U.K. Investigation of gas permeation properties of systematically modified polybenzimidazoles by N-substitution. J. Membr. Sci. 2010, 357:134-142.
33. Jeffery G.H., Bassett J., Mendham J., Denney C. Vogel[U+05F3]s Textbook of Quantitative Chemical Analysis 1989, 355-356. British Library Cataloguing in Publication Data. fifth ed.
34. Koros W.J., Paul D.R. Design considerations for measurement of gas sorption in polymers by pressure decay. J. Polym. Sci. Polym. Phys. 1976, 14:1903-1907.
35. Karadkar P.B., Kharul U.K., Bhole Y.S., Badhe Y.P., Tambe S.S., Kulkarni B.D. Gas sorption and transport in polyarylates: effect of substituent symmetry and polarity. J. Membr. Sci. 2007, 303:244-251.
36. Vieth W.R., Howell J.M., Hsieh J.H. Dual sorption theory. J. Membr. Sci. 1976, 1:177-220.
37. Kumbharkar S.C., Kharul U.K. N-substitution of polybenzimidazoles: synthesis and evaluation of physical properties. Polymer 2009, 45:3363-3371.
38. Musto P., Karaszt F.E., MacKnight W.J. Fourier transform infra-red spectroscopy on the thermo-oxidative degradation of polybenzimidazole and of a polybenzimidazole/polyetherimide blend. Polymer 1993, 34:2934-2946.
39. Pan X., Xiao S., Wanga C., Cai P., Lu X., Lu Q. Photoinduced anisotropy in an azo-containing ionic liquid-crystalline polymer. Opt. Commun. 2009, 282:763-768.
40. Chen C., Hess A.R., Jones A.R., Liu X., Barber G.D., Mallouk T.E., Allcock H.R. Synthesis of new polyelectrolytes via backbone quaternization of poly(aryloxy- and alkoxy phosphazenes) and their small molecule counterparts. Macromolecules 2012, 45:1182-1189.
41. Tin P.S., Chung T.S., Liu Y., Wang R., Liu S.L., Pramod K.P. Effects of cross-linking modification on gas separation performance of Matrimid membranes. J. Membr. Sci. 2003, 225:77-90.
42. McHattie J.S., Koros W.J., Paul D.R. Gas transport properties of polysulphones: 3. Comparison of tetra methyl-substituted bisphenols. Polymer 1992, 33:1701-1711.
43. Hellums M.W., Koros W.J., Husk G.R., Paul D.R. Fluorinated polycarbonates for gas separation applications. J. Membr. Sci. 1989, 46:93-112.
44. Xiao Y., Dai Y., Chung T.S., Guiver M.D. Effects of brominating Matrimid polyimide on the physical and gas transport properties of derived carbon membranes. Macromolecules 2005, 38:10042-10049.
45. Guiver M.D., Robertson G.P., Dai Y., Bilodeau F., Kang Y.S., Lee K.J., Jho J.Y., Won J. Structural characterization and gas-transport properties of brominated Matrimid polyimide. J. Polym. Sci. Part A: Polym. Chem. 2002, 40:4193-4204.
46. Kanehashi S., Nagai K. Analysis of dual-mode model parameters for gas sorption in glassy polymers. J. Membr. Sci. 2005, 253:117-138.