Synthesis, characterisation, adsorption ability and activity of Cu,ZnO@UiO-66 in methanol synthesis

International Journal of Nanotechnology

Volumn 12, Issue 5-7, 2015, Pages 405-415

  Van, Nguyen Thi Thuy ^a   Loc, Luu Cam ^a   Tri, Nguyen ^a   Cuong, Hoang Tien ^a  

^a GRADUATE UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Viet Nam)

Author keywords

Adsorption; CH3OH synthesis; Nanotechnology; UiO 66

Indexed keywords

ADSORPTION; CATALYSTS; HYDROGENATION; II-VI SEMICONDUCTORS; METAL-ORGANIC FRAMEWORKS; METHANOL; NANOTECHNOLOGY; ORGANOMETALLICS; OXIDE MINERALS; PHYSISORPTION; THERMODYNAMIC STABILITY; ZINC OXIDE;

ADSORPTION ABILITY; HIGH SURFACE AREA; HYDROGENATION OF CO AND CO2; METHANOL SYNTHESIS; NITROGEN PHYSISORPTION MEASUREMENTS; SOLVOTHERMAL METHOD; SYNTHESIS CONDITIONS; UIO-66;

CARBON DIOXIDE;

EID: 84924491086     PISSN: 14757435     EISSN: None     Source Type: Journal    
DOI: 10.1504/IJNT.2015.067898     Document Type: Article

References (24)

1. Wong-Foy, A.G., Matzger, A.J. and Yaghi, O.M. (2006) 'Exceptional H2 saturation uptake in microporous metal-organic frameworks', J. Am. Chem. Soc., Vol. 128, pp.3494-3495.
2. Düren, T., Sarkisov, L., Yaghi, O.M. and Snurr, R.Q. (2004) 'Design of new materials for methane storage', Langmuir, Vol. 20, pp.2683-2689.
3. Millward, A.R. and Yaghi, O.M. (2005) 'Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature', J. Am. Chem. Soc., Vol. 127, pp.17998?17999.
4. Choi, H.S. and Suh, M.P. (2009) 'Highly selective CO2 capture in flexible 3D coordination polymer networks', Angew. Chem., Int. Ed., Vol. 48, pp.6865-6869.
5. Saha, D., Bao, Z., Jia, F. and Deng, S. (2010) 'Adsorption of CO2, CH4, N2O, and N2 on MOF-5, MOF-177, and Zeolite 5A', Environ. Sci. Technol., Vol. 44, No. 5, pp.1820-1826.
6. Mu, B., Li, F. and Walton, K.S. (2009) 'A novel metal-organic coordination polymer for selective adsorption of CO2 over CH4', Chem. Commun., pp.2493-2495.
7. Esken, D., Zhang, X., Lebedev, O.I., Schroder, F. and Fischer, R.A. (2009) 'Pd@MOF-5: limitation of gas - phase infiltration and solution impregnation of [Zn4O(bdc)3] MOF-5 with metal -organic palladium precursors for loading with Pd nanoparticles', J. Mater. Chem., Vol. 19, pp.1314-1319.
8. Müller, M., Hermes, S., Kähler, K., Van den Berg, M.W.E., Muhler, M. and Fischer, R.A. (2008) 'Loading of MOF-5 with Cu and ZnO nanoparticles by gas-phase infiltration with organometallic precursors: Properties of Cu/ZnO@MOF-5 as catalyst for methanol synthesis', Chem. Mater., Vol. 14, pp.4576-4587.
9. Cavka, J.H., Jakobsen, S. and Olsbye, U. (2008) 'A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability', J. Am. Chem. Soc., Vol. 42, pp.13850-13867.
10. Van, N.T.T, Loc, L.C., Cuong, H. T., Tri, N., Huong, B. T, Duy, N.P.H. and Phuong, P.T.T. (2013) 'Synthesis of MOF-199 and apply to CO2 adsorption', Adv. Nat. Sci.: Nanosci. Nanotechnol., Vol. 4, 035016 (6pp) (online).
11. Wiersum, A.D., Soubeyrand-Lenoir, E.L., Yang, Q., Moulin, B., Guillerm, V., Yahia, M.B., Bourrelly, S., Vimont, A., Miller, S. and Vagner, C. (2011) 'An evaluation of UiO-66 for gas-based applications', Chemistry - An Asian Journal, Vol. 6, pp.3270-3280.
12. Valenzano, L., Civalleri, B., Chavan, S., Bordiga, S., Nilsen, M.H., Jakobsen, S., Lillerud, K.P. and Lamberti, C. (2011) 'Disclosing the complex structure of UiO-66 metal organic framework: A synergic combination of experiment and theory', Chem. Mater., Vol. 23, pp.1700-1718.
13. Cmarik, G.E., Kim, M., Cohen, S.M. and Walton, K.S. (2012) 'Tuning the adsorption properties of UiO-66 via ligand functionalization', Langmuir, Vol. 28, pp.15606-15613.
14. Morris, W., Doonan, C.J. and Yaghi, O.M. (2011) 'Postsynthetic modification of a metalorganic framework for stabilization of a hemiaminal and ammonia uptake', Inorg. Chem., Vol. 50, pp.6853-6855.
15. Düren, T., Millange, F., Férey, G., Walton, K.S. and Snurr, R.Q. (2007) 'Calculating geometric surface areas as a characterization tool for metal-organic frameworks', J. Phys.Chem., Vol. 111, pp.15350-15356.
16. Chavan, S., Vitillo, J.G., Gianolio, D., Zavorotynska, O., Civalleri, B., Jakobsen, S., Nilsen, M.H., Valenzano, L., Lamberti, C., Lillerud, K.P. and Bordiga, S. (2012) 'H2 storage in isostructural UiO-67 and UiO-66 MOFs', Phys. Chem. Chem. Phys., Vol. 14, pp.1614-1626.
17. Abib, H.R., Tian, H., Ang, H.M., Tade, M.O., Buckley, C.E. and Wang, S. (2012) 'Nanosize Zr-metal organic framework (UiO-66) for hydrogen and carbon dioxide storage', J. Chem. Eng., Vol. 187, pp.415-420.
18. Behrens, M. and Haber, F. (2009) 'Meso- and nanostructuring of industrial Cu/ZnO/Al2O3 catalysts', J. Catal., Vol. 267, pp.24-26.
19. Scholes, C.A., Kentish, S.E. and Stevens, G.W. (2008) 'Carbon dioxide separation through polymeric membrane systems for flue gas applications', Recent Patents on Chemical Engineering, Vol. 1, pp.52-66.
20. Nir, S., Adam, S. and Robert, R. (1973) 'Polarization calculations on water, hydrogen, oxygen and carbon dioxide', J. Chem. Phys., Vol. 59, pp.3341-3355.
21. Van den Berg, M.W.E., Polarz, S., Tkachenko, O.P., Klementiev, K.V., Bandyopadhyay, M., Khodeir, L., Gies, H., Muhler, M. and Grünert, W. (2006) 'Cu/ZnO aggregates in siliceous mesoporous matrices: Development of a new model methanol synthesis catalyst', J. Catal., Vol. 241, pp.446-455.
22. Becker, R., Parala, H., Hipler, H., Tkachenko, O.P., Klementiev, K.V., Grünert, W., Hinrichsen, O., Muhler, M., Birkner, A., Wöll, C. and Schäfer, S. (2004) 'MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: supported catalysts for methanol synthesis', J. Angew. Chem. Int. Ed., Vol. 43, pp.2839-2842.
23. Sloczynski, J., Grabowski, R., Kozlowska, A., Olszewski, P., Lachowska, M., Skrzypek, J. and Stoch, J. (2003) 'Effect of Mg and Mn oxide additions on structural and adsorptive properties of Cu/ZnO/ZrO2 catalysts for the methanol synthesis from CO2', Appl. Catal., A, Vol. 249, pp.129-138.
24. Spencer, M.S., Robert, B. and Stanislaw, E.G. (1999) 'The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water-gas shift reaction', Top. Catal., Vol. 8, Nos. 3-4, pp.259-266.