Development of Bipolar All-solid-state Lithium Battery Based on Quasi-solid-state Electrolyte Containing Tetraglyme-LiTFSA Equimolar Complex

Scientific Reports

Volumn 5, Issue , 2015, Pages

  Gambe, Yoshiyuki ^a   Sun, Yan ^a   Honma, Itaru ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84924352511     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep08869     Document Type: Article

References (27)

1. Tarascon, J.-M. & Armand, M. Issues and challenges facing rechargeable lithium batteries. Nature 414, 359-367 (2001).
2. Armand, M. & Tarascon, J.-M. Building better batteries. Nature 451, 652-657 (2008).
3. 2 polymer electrolytes. J. Power Sources 143, 236-242 (2005).
4. Baba, M. et al. Multi-layered Li-ion rechargeable batteries for a high-voltage and high-current solid-state power source. J. Power Sources 119-121, 914-917 (2003).
5. Sato, T. et al. Novel solid-state polymer electrolyte of colloidal crystal decorated with ionic-liquid polymer brush. Adv. Mater. 23, 4868-4872 (2011).
6. 12. Electrochemistry 80, 749-751 (2012).
7. Fergus, J. W. Ceramic and polymeric solid electrolytes for lithium-ion batteries. J. Power Sources 195, 4554-4569 (2010).
8. Kamaya, N. et al. A lithium superionic conductor. Nat. Mat. 10, 682-686 (2011).
9. Ohta, N. et al. Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacialmodification. Adv. Mater. 18, 2226-2229 (2006).
10. Sakaebe, H. & Matsumoto, H. N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13-TFSI)-novel electrolyte base for Li battery. Electrochem. Commun. 5, 594-598 (2003).
11. 2 cell using room temperature ionic liquids (TRILs) based on quaternary ammonium cation - Effect of the structure. J. Power Sources 146, 693-697 (2005).
12. -. J. Power Sources 160, 1308-1313 (2006).
13. Yoshida, K. et al. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes. J. Am. Chem. Soc. 133, 13121-13129 (2011).
14. Tamura, T. et al. Physicochemical properties of glyme-Li salt complexes as a new family of room-temperature ionic liquids. Chem. Lett. 39, 753-755 (2010).
15. Tachikawa, N. et al. Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme-Li salt molten complex electrolytes. Chem. Commun. 47, 8157-8159 (2011).
16. Yoshida, K., Tsuchiya, M., Tachikawa, N., Dokko, K. & Watanabe, M. Change from glyme solutions to quasi-ionic liquids for binary mixtures consisting of lithium bis(trifluoromethanesulfonyl)amide and glymes. J. Phys. Chem. C 115, 18384-18394 (2011).
17. Ueno, K. et al. Glyme-lithium salt equimolar molten mixtures: concentrated solutions or solvate ionic liquids? J. Phys. Chem. B 116, 11323-11331 (2012).
18. 2 complex for safe lithium-ion secondary battery electrolyte. J. Electrochem. Soc. 158, A769-A774 (2011).
19. Ueno, K., Hata, K., Katakabe, T., Kondoh, M. & Watanabe, M. Nanocomposite ion gels based on silica nanoparticles and an ionic liquid: ionic transport, viscoelastic properties and microstructure. J. Phys. Chem. B 112, 9013-9019 (2008).
20. Wang, P., Zakeeruddin, S.M., Comte, P., Exnar, I. & Grätzel, M. Gelation of ionic liquid-based electrolytes with silica nanoparticles for quasi-solid-state dyesensitized solar cells. J. Am. Chem. Soc. 125, 1166-1167 (2003).
21. Shimano, S., Zhou, H. & Honma, I. Preparation of nanohybrid solid-state electrolytes with liquidlike mobilities by solidifying ionic liquids with silica particles. Chem. Mater. 19, 5216-5221 (2007).
22. Ito, S., Unemoto, A., Ogawa, H., Tomai, T. & Honma, I. Application of quasi-solid-state silica nanoparticles-ionic liquid composite electrolytes to all-solid-state lithium secondary battery. J. Power Sources 208, 271-275 (2012).
23. Ogawa, H., Unemoto, A. & Honma, I. Quasi-solid-state lithium-sulfur battery using room temperature ionic liquid-Li-salt-fumed silica nanoparticle composites as electrolytes. Electrochemistry 80, 765-767 (2012).
24. Unemoto, A., Ogawa, H., Ito, S. & Honma, I. Electrical conductivity, self-diffusivity and electrolyte performance of a quasi-solid-state pseudo-ternary system, bis(trifluoromethanesulfonyl)amide-based room temperature ionic liquid-lithium bis(trifluoromethanesulfonl)amide-fumed silica nanoparticles. J. Electrochem. Soc. 160, A138-A147 (2013).
25. Unemoto, A., Matsuo, T., Ogawa, H., Gambe, Y. & Honma, I. Development of all-solid-state lithium battery using quasi-solidified tetraglyme-lithium bis(trifluoromethanesulfonyl)amide-fumed silica nano-composites as electrolytes. J. Power Sources 244, 354-362 (2013).
26. Unemoto, A., Gambe, Y., Komatsu, D. & Honma, I. Development of high capacity all-solid-state lithium battery using quasi-solid-state electrolyte containing tetraglyme-Li-TFSA equimolar complexes. Solid State Ionics 262, 765-768 (2014).
27. Matsuo, T., Gambe, Y., Sun, Y. & Honma, I. Bipolar stacked quasi-all-solid-state lithium secondary batteries with output cell potentials of over 6 V. Sci. Rep. 4, 6084 (2014).