Illustrating catalysis with interlocking building blocks: A BINAP-ruthenium complex catalyzed asymmetric hydrogenation

Journal of Chemical Education

Volumn 92, Issue 2, 2015, Pages 332-335

  Horikoshi, Ryo ^a  

^a OSAKA SANGYO UNIVERSITY   (Japan)

Author keywords

Catalysis; First Year Undergraduate General; Hands On Learning Manipulatives; High School Introductory Chemistry; Inorganic Chemistry

Indexed keywords

EID: 84923701182     PISSN: 00219584     EISSN: 19381328     Source Type: Journal    
DOI: 10.1021/ed500484u     Document Type: Article

References (11)

1. Ault, A. The Nobel Prize in Chemistry for 2001 J. Chem. Educ. 2002, 79 (5) 572-577
2. Peeters, C. M.; Deliever, R.; De Vos, D. Microscale Synthesis of Chiral Alcohols via Asymmetric Transfer Hydrogenation J. Chem. Educ. 2009, 86 (1) 87-90
3. Noyori, R.; Kitamura, M.; Ohkuma, T. Toward Efficient Asymmetric Hydrogenation: Architectural and Functional Engineering of Chiral Molecular Catalysts Proc. Natl. Acad. Sci. U.S.A. 2004, 101 (15) 5336-5362
4. Noyori, R.; Sandoval, C. A.; Muñiz, K.; Ohkuma, T. Metal-Ligand Bifunctional Catalysis for Asymmetric Hydrogenation Philos. Trans. R. Soc., A 2005, 363 (1829) 901-912
5. Noyori, R.; Takaya, H. BINAP: An Efficient Chiral Element for Asymmetric Catalysis Acc. Chem. Res. 1990, 23 (10) 345-350
6. Campbell, D. J.; Miller, J. D.; Bannon, S. J.; Obermaier, L. M. An Exploration of the Nanoworld with LEGO Bricks J. Chem. Educ. 2011, 88 (5) 602-608
7. Exploring the Nanoworld with LEGO Bricks. http://www.nisenet.org/catalog/programs/exploring-nanoworld-lego%C2%AE-bricks (accessed Nov 2013).
8. Campbell, D. J.; Freidinger, E. R.; Querns, M. K. Spontaneous Assembly of Magnetic LEGO Bricks Chem. Educator 2001, 6 (6) 321-323
9. Cloonan, C. A.; Nichol, C. A.; Hutchinson, J. S. Understanding Chemical Reaction Kinetics and Equilibrium with Interlocking Building Blocks J. Chem. Educ. 2011, 88 (10) 1400-1403
10. Horikoshi, R.; Kobayashi, Y.; Kageyama, H. Illustrating Catalysis with Interlocking Building Blocks: Correlation between Structure of a Metallocene Catalyst and the Stereoregularity of Polypropylene J. Chem. Educ. 2013, 90 (5) 620-622
11. Horikoshi, R.; Kobayashi, Y.; Kageyama, H. Illustrating Catalysis with Interlocking Building Blocks: A Ruthenium-Carbene Complex for Olefin Metathesis Reactions J. Chem. Educ. 2014, 91 (2) 255-258