Hydrothermal synthesis and characterization of a metal-organic framework by thermogravimetric analysis, powder X-ray diffraction, and infrared spectroscopy: An integrative inorganic chemistry experiment

Journal of Chemical Education

Volumn 92, Issue 2, 2015, Pages 373-377

  Crane, Johanna L ^a   Anderson, Kelly E ^a,b   Conway, Samantha G ^a  

^a UNIVERSITY OF PUGET SOUND   (United States)

^b ROANOKE COLLEGE   (United States)

Author keywords

Gravimetric Analysis; Hydrogen Bonding; Inorganic Chemistry; IR Spectroscopy; Laboratory Instruction; Materials Science; Thermal Analysis; Upper Division Undergraduate

Indexed keywords

EID: 84923666811     PISSN: 00219584     EISSN: 19381328     Source Type: Journal    
DOI: 10.1021/ed5000839     Document Type: Article

References (23)

1. Batten, S. R.; Champness, N. R.; Chen, X.; Garcia-Martinez, J.; Kitagawa, S.; Ohrstrom, L.; O'Keeffe, M.; Suh, M. P.; Reedijk, J. Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013) Pure Appl. Chem. 2013, 85 (8) 1715-1724
2. Batten, S. R.; Champness, N. R.; Chen, X.; Garcia-Martinez, J.; Kitagawa, S.; Ohrstrom, L.; O'Keeffe, M.; Suh, M. P.; Reedijk, J. Coordination polymers, metal-organic frameworks and the need for terminology guidelines CrystEngComm 2012, 14 (9) 3001-3004
3. Cook, T. R.; Zheng, Y.; Stang, P. J. Metal-organic Frameworks and Self-assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials Chem. Rev. 2013, 113 (1) 734-777
4. Thematic Issue: Metal Organic Frameworks. Chem. Rev. 2012, 112 (2), 673-1268.
5. Themed Collection: Metal Organic Frameworks. Chem. Soc. Rev. 2009, 38 (5), 1203-1504.
6. Themed Collection: Coordination Polymers: Structure and Function. New J. Chem. 2010, 34 (11), 2353-2681.
7. Sumida, K.; Arnold, J. Preparation, Characterization, and Postsynthetic Modification of Metal-Organic Frameworks: Synthetic Experiments for an Undergraduate Laboratory Course in Inorganic Chemistry J. Chem. Educ. 2011, 88 (1) 92-94
8. Rood, J. A.; Henderson, K. W. Synthesis and Small Molecule Exchange Studies of a Magnesium Bisformate Metal-Organic Framework: An Experiment in Host-Guest Chemistry for the Undergraduate Laboratory J. Chem. Educ. 2013, 90 (3) 379-382
9. Moskovitz, C.; Kellogg, D. Inquiry-Based Writing in the Laboratory Course Science 2011, 332 (6032) 919-920
10. Alaimo, P. J.; Bean, J. C.; Langenhan, J. M.; Nichols, L. Eliminating Lab Reports: A Rhetorical Approach for Teaching the Scientific Paper in Sophomore Organic Chemistry Writing Across Curric. J. 2009, 20, 17-32
11. Yaghi, O. M.; Li, H.; Groy, T. L. Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid J. Am. Chem. Soc. 1996, 118 (38) 9096-9101
12. Yaghi, O. M.; Li, H.; Davis, C.; Richardson, D.; Groy, T. L. Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids Acc. Chem. Res. 1998, 31 (8) 474-484
13. 3 Under Microwave: A Quantitative Analysis of Accelerated Synthesis Phys. Chem. Chem. Phys. 2010, 12 (11) 2625-2631
14. Diring, S.; Furukawa, S.; Takashima, Y.; Tsuruoka, T.; Kitagawa, S. Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes Chem. Mater. 2010, 22 (16) 4531-4538
15. Maniam, P.; Stock, N. Investigation of Porous Ni-Based Metal-Organic Frameworks Containing Paddle-Wheel Type Inorganic Building Units via High-Throughput Methods Inorg. Chem. 2011, 50 (11) 5085-5097
16. Zeltmann, A. H.; Matwiyoff, N. A.; Morgan, L. O. Nuclear Magnetic Resonance of Oxygen-17 and Chlorine-35 in Aqueous Hydrochloric Acid Solutions of Cobalt(II). I. Line Shifts and Relative Abundances of Solution Species J. Phys. Chem. 1968, 72 (1) 121-127
17. Shakhashiri, B. S. Chemical Demonstrations; The University of Wisconsin Press: Madison, WI, 1983; Vol. 1, pp 280-285.
18. O'Brien, J. J.; O'Brien, J. F. The Laporte Selection Rule in Electronic Absorption Spectroscopy J. Coll. Sci. Teach. 1999, 29 (2) 138-140
19. The Cambridge Crystallographic Data Centre (CCDC). http://www.ccdc.cam.ac.uk (accessed Mar 2013).
20. Plater, M. J.; Roberts, A. J.; Marr, J.; Lachowski, E. E.; Howie, R. A. Hydrothermal Synthesis and Characterisation of Alkaline-Earth Metal Salts of Benzene-1,3,5-Tricarboxylic Acid J. Chem. Soc., Dalton Trans. 1998, 5, 797-802
21. 2O)] Microporous Mesoporous Mater. 2010, 132 (1-2) 121-127
22. Yaghi, O. M.; Davis, C. E.; Li, G.; Li, H. Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)-Benzenetricarboxylate Network J. Am. Chem. Soc. 1997, 119 (12) 2861-2868
23. Srinivasan, B. R.; Shetgaonkar, S. Y.; Raghavaiah, P. Soft Synthesis of a Metal-organic Framework based on a Tribarium Building Block Indian J. Chem. 2012, 51A (8) 1064-1072