Ethylene glycol-based microgels at solid surfaces: Swelling behavior and control of particle number density

Langmuir

Volumn 31, Issue 7, 2015, Pages 2202-2210

  Wellert, Stefan ^a   Kesal, Dikran ^a   Schön, Sebastian ^a   Von Klitzing, Regine ^a   Gawlitza, Kornelia ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ETHYLENE; ETHYLENE GLYCOL; GELS; PARTICLE SIZE; POLYOLS;

AMBIENT CONDITIONS; GEOMETRICAL CONFINEMENT; PARTICLE NUMBER DENSITY; PRECIPITATION POLYMERIZATIONS; PREPARATION PARAMETERS; SOLID/LIQUID INTERFACES; VOLUME PHASE TRANSITION; WATER-SWOLLEN STATE;

PRECIPITATION (CHEMICAL);

ETHYLENE GLYCOL; GEL; MACROGOL DERIVATIVE; METHACRYLIC ACID DERIVATIVE; POLYETHYLENE GLYCOL METHACRYLATE; SILICON;

ATOMIC FORCE MICROSCOPY; CHEMISTRY; GEL; PARTICLE SIZE;

ETHYLENE GLYCOL; GELS; METHACRYLATES; MICROSCOPY, ATOMIC FORCE; PARTICLE SIZE; POLYETHYLENE GLYCOLS; SILICON;

EID: 84923373097     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la504556m     Document Type: Article

References (35)

1. Bauer, S.; Schmuki, P.; v. d. Mark, K.; Park, J. Engineering Biocompatible Implant Surfaces Part I: Materials and Surfaces Prog. Mater. Sci. 2013, 58, 261-326
2. Campoccia, D.; Montanaro, L.; Arciola, C. R. A Review of the Biomaterials Technologies for Infection-Resistant Surfaces Biomaterials 2013, 34, 8533-8554
3. Alcantar, N. A.; Aydil, E. S.; Israelachvili, J. N. Polyethylene Glycol-Coated Biocompatible Surfaces J. Biomed. Mater. Res. 2000, 51, 343-351
4. Mihai, R.; Florescu, I. P.; Coroiu, V.; Oancea, A.; Lungu, M. In Vitro Biocompatability Testing of Some Synthetic Polymers Used for the Achievement of Nervous Conduits J. Med. Life 2011, 4, 250-255
5. Mizrahi, B.; Khoo, X.; Chiang, H. H.; Sher, K. J.; Feldman, R. G.; Lee, J.-J.; Irusta, S.; Kohane, D. S. Long-Lasting Antifouling Coating from Multi-Armed Polymer Langmuir 2013, 29, 10087-10094
6. Pelton, R. H.; Chibante, P. Preparation of Aqueous Latices with N-Isopropylacrylamide Colloids Surf. 1986, 20, 247-256
7. Höfl, S.; Zitzler, L.; Hellweg, T.; Herminghaus, S.; Mugele, F. Volume Phase Transition of "Smart" Micro Gels in Bulk Solution and Adsorbed at an Interface: A Combined AFM, Dynamic Light, and Small Angle Neutron Scattering Study Polymer 2007, 48, 245-254
8. Schmidt, S.; Hellweg, T.; von Klitzing, R. Packing Density Control in P(NIPAM- co -AAc) Microgel Monolayers: Effect of Surface Charge, pH, and Preparation Technique Langmuir 2008, 24, 12595-12602
9. Schmidt, S.; Motschmann, H.; Hellweg, T.; von Klitzing, R. Thermoresponsive Surfaces by Spin-Coating of PNIPAM- co -PAA Microgels: A Combined AFM and Ellipsometry Study Polymer 2008, 49, 749-756
10. Saunders, B. R.; Vincent, B. Microgel Particles as Model Colloids: Theory, Properties and Applications Adv. Colloid Interface Sci. 1999, 80, 1-25
11. Crowther, H. M.; Saunders, B. R.; Mears, S. J.; Cosgrove, T.; Vincent, B.; King, S. M.; Yu, G.-E. Poly(NIPAM) Microgel Particle De-swelling: A Light Scattering and Small-Angle Neutron Scattering Study Colloids Surf., A 1999, 152, 327-333
12. Burmistrova, A.; von Klitzing, R. Control of Number Density and Swelling/Shrinking Behavior of P(NIPAM-AAc) Particles at Solid Surfaces J. Mater. Chem. 2010, 20, 3502-3507
13. Richter, M.; Hunnenmörder, M.; v. Klitzing, R. The Impact of the Co-non-solvency Effect on Poly(N -isopropylacrylamide) Based Microgels at Interfaces Colloids Polym. Sci. 2014, 292, 2439-2452
14. Burmistrova, A.; Richter, M.; Eisele, M.; Üzüm, C.; von Klitzing, R. The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles Polymers 2011, 3, 1575-1590
15. Burmistrova, A.; Richter, M.; Üzüm, C.; von Klitzing, R. The Effect of Cross-Linker Density of P(NIPAM-AAc) Microgels at Solid Surfaces on the Swelling/Shrinking Behaviour and the Youngs Modulus Colloid Polym. Sci. 2011, 289, 613-624
16. Nerapusri, V.; Keddie, J. L.; Vincent, B.; Bushnak, I. A. Swelling and Deswelling of Adsorbed Microgel Monolayers Triggered by Changes in Temperature, pH, and Electrolyte Concentration Langmuir 2006, 22, 5036-5041
17. Nayak, S.; Debord, S. B.; Lyon, L. A. Investigations into the Deswelling Dynamics and Thermodynamics of Thermoresponsive Microgel Composite Films Langmuir 2003, 19, 7374-7379
18. Gutowski, S. M.; Templeman, K. L.; South, A. B.; Gaulding, J. C.; Shoemaker, J. T.; LaPlaca, M. C.; Bellamkonda, R. V.; Lyon, L. A.; García, A. J. Host Response to Microgel Coatings on Neural Electrodes Implanted in the Brain J. Biomed. Mater. Res., Part A 2014, 102A, 1486-1499
19. Nolan, C. M.; Serpe, M. J.; Lyon, L. A. Pulsatile Release of Insulin from Layer-by-Layer Assembled Microgel Thin Films Macromol. Symp. 2005, 227, 285-294
20. Serpe, M.; Yarmey, K. A.; Noland, C. M.; Lyon, L. A. Doxorubicin Uptake and Release from Microgel Thin Films Biomacromolecules 2005, 6, 408-413
21. South, A. B.; Whitmire, R. E.; Garcia, A. J.; Lyon, L. A. Centrifugal Deposition of Microgels for the Rapid Assembly of Nonfouling Thin Films ACS Appl. Mater. Interfaces 2009, 1, 2747-2754
22. Islam, M. R.; Li, X.; Smyth, K.; Serpe, M. J. Polymer-Based Muscle Expansion and Contraction Angew. Chem., Int. Ed. 2013, 52, 10330-10333
23. Schmidt, S.; Zeiser, M.; Hellweg, T.; Duschl, C.; Fery, A.; Möhwald, H. Adhesion and Mechanical Properties of PNIPAM Microgel Films and Their Potential Use as Switchable Cell Culture Substrates Adv. Funct. Mater. 2010, 20, 3235-3243
24. Lynch, I.; Miller, I.; Gallagher, W. M.; Dawson, K. A. Novel Method to Prepare Morphologically Rich Polymeric Surfaces for Biomedical Applications via Phase Separation and Arrest of Microgel Particles J. Phys. Chem. B 2006, 110, 14581-14589
25. Tsai, H. Y.; Vats, K.; Yates, M. Z.; Benoit, D. S. W. Two-Dimensional Patterns of Poly(N -isopropyl acrylamide) Microgels to Spatially Control Fibroblast Adhesion and Temperature-Responsive Detachment Langmuir 2013, 29, 12183-12193
26. Bridges, A. W.; Singh, N.; Burns, K. L.; Babensee, J. E.; Lyon, L. A.; Garcá, A. J. Reduced Acute Inflammatory Responses to Microgel Conformal Coatings Biomaterials 2008, 29, 4605-4615
27. Harsh, D. C.; Gehrke, S. H. Controlling the Swelling Characteristics of Temperature-Sensitive Cellulose Ether Hydrogels J. Controlled Release 1991, 17, 175-186
28. Vihola, H.; Laukkanen, A.; Valtola, L.; Tenhu, H.; Hirvonen, J. Cytotoxicity of Thermosensitive Polymers Poly(N-isopropylacrylamide), Poly(N-vinylcaprolactam) and Amphiphilically Modfied Poly(N-vinylcaprolactam) Biomaterials 2005, 26, 3055-3064
29. Lutz, J.-F.; Akdemir, O.; Hoth, A. Point by Point Comparison of Two Thermosensitive Polymers Exhibiting a Similar LCST: Is the Age of Poly(NIPAM) Over? J. Am. Chem. Soc. 2006, 128, 13046-13047
30. Lutz, J.-F.; Andrieu, J.; Üzgün, S.; Rudolph, C.; Agarwal, S. Biocompatible, Thermoresponsive, and Biodegradable: Simple Preparation of "All-in-One" Biorelevant Polymers Macromolecules 2007, 40, 8540-8543
31. Lutz, J.-F. Polymerization of Oligo(ethylene glycol) (Meth)acrylates: Toward New Generations of Smart Biocompatible Materials J. Polym. Sci., Part A 2008, 46, 3459-3470
32. Cai, T.; Marquez, M.; Hu, Z. Monodisperse Thermoresponsive Microgels of Poly(ethylene glycol) Analogue-Based Biopolymers Langmuir 2007, 23, 8663-8666
33. Gawlitza, K.; Radulescu, A.; von Klitzing, R.; Wellert, S. On the Structure of Biocompatible, Thermoresponsive Poly(ethylene glycol) Microgels Polymer 2014, 55, 6717-6724
34. Provencher, S. W. A Constrained Regularization Method for Inverting Data Represented by Linear Algebraic or Integral Equations Comput. Phys. Commun. 1982, 27, 213-227
35. Geisel, K.; Richtering, W.; Isa, L. Highly Ordered 2D Microgel Arrays: Compression versus Self-Assembly Soft Matter 2014, 10, 7968-7976