Contacts between alcohols in water are random rather than hydrophobic

Journal of Physical Chemistry Letters

Volumn 6, Issue 4, 2015, Pages 688-692

  Rankin, Blake M ^a   Ben Amotz, Dor ^a   Van Der Post, Sietse T ^b   Bakker, Huib J ^b  

^a PURDUE UNIVERSITY   (United States)

^b FOM INSTITUTE AMOLF   (Netherlands)

Author keywords

femtosecond IR spectroscopy; hydrophobic interactions; Raman spectroscopy; random mixing

Indexed keywords

MIXING; MOLECULAR DYNAMICS; RAMAN SPECTROSCOPY; VAN DER WAALS FORCES;

FEMTOSECOND IR SPECTROSCOPY; HYDROPHOBIC CONTACT; HYDROPHOBIC INTERACTIONS; MOLECULAR DYNAMICS SIMULATIONS; RANDOM MIXING; SELF ASSEMBLY PROCESS; TERTIARY BUTYL ALCOHOLS; VAN DER WAALS INTERACTIONS;

HYDROPHOBICITY;

ALCOHOL DERIVATIVE; WATER;

CHEMICAL PHENOMENA; CHEMISTRY;

ALCOHOLS; HYDROPHOBIC AND HYDROPHILIC INTERACTIONS; WATER;

EID: 84923327174     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz5027129     Document Type: Article

References (39)

1. Patel, A. J.; Varilly, P.; Jamadagni, S. N.; Hagan, M. F.; Chandler, D.; Garde, S. Sitting at the Edge: How Biomolecules Use Hydrophobicity to Tune Their Interactions and Function J. Phys. Chem. B 2012, 116, 2498-2503
2. Hummer, G. Molecular Binding under Water?s Influence Nat. Chem. 2010, 2, 906-907
3. Rasaiah, J. C.; Garde, S.; Hummer, G. Water in Nonpolar Confinement: From Nanotubes to Proteins and Beyond Annu. Rev. Phys. Chem. 2008, 59, 713-740
4. Granick, S.; Bae, S. C. A Curious Antipathy for Water Science 2008, 322, 1477-1478
5. Chandler, D. Interfaces and the Driving Force of Hydrophobic Assembly Nature 2005, 437, 640-647
6. Baldwin, R. L. Dynamic Hydration Shell Restores Kauzmann?s 1959 Explanation of How the Hydrophobic Factor Drives Protein Folding Proc. Natl. Acad. Sci. U.S.A. 2014, 111, 13052-13056
7. Ben-Naim, A. Hydrophobic Interactions; Plenum Press: New York, 1980.
8. Pratt, L. R.; Chandler, D. Hydrophobic Interactions and Osmotic 2nd Virial-Coefficients for Methanol in Water J. Solution Chem. 1980, 9, 1-17
9. Koga, K. Osmotic Second Virial Coefficient of Methane in Water J. Phys. Chem. B 2013, 117, 12619-12624
10. Morrone, J. A.; Li, J.; Berne, B. J. Interplay between Hydrodynamics and the Free Energy Surface in the Assembly of Nanoscale Hydrophobes J. Phys. Chem. B 2012, 116, 378-389
11. Makowski, M.; Czaplewski, C.; Liwo, A.; Scheraga, H. A. Potential of Mean Force of Association of Large Hydrophobic Particles: Toward the Nanoscale Limit J. Phys. Chem. B 2010, 114, 993-1003
12. Gupta, R.; Patey, G. N. Aggregation in Dilute Aqueous Tert-Butyl Alcohol Solutions: Insights from Large-Scale Simulations J. Chem. Phys. 2012, 137, 034509
13. Ghosh, M. K.; Uddin, N.; Choi, C. H. Hydrophobic and Hydrophilic Associations of a Methanol Pair in Aqueous Solution J. Phys. Chem. B 2012, 116, 14254-14260
14. Li, J. L.; Car, R.; Tang, C.; Wingreen, N. S. Hydrophobic Interaction and Hydrogen-Bond Network for a Methane Pair in Liquid Water Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 2626-2630
15. Bowron, D. T.; Finney, J. L. Anion Bridges Drive Salting out of a Simple Amphiphile from Aqueous Solution Phys. Rev. Lett. 2002, 89, 215508
16. Nishikawa, K.; Hayashi, H.; Iijima, T. Temperature-Dependence of the Concentration Fluctuation, the Kirkwood-Buff Parameters, and the Correlation Length of Tert-Butyl Alcohol and Water Mixtures Studied by Small-Angle X-Ray-Scattering J. Phys. Chem. 1989, 93, 6559-6565
17. Sedlak, M.; Rak, D. Large-Scale Inhomogeneities in Solutions of Low Molar Mass Compounds and Mixtures of Liquids: Supramolecular Structures or Nanobubbles? J. Phys. Chem. B 2013, 117, 2495-2504
18. Petersen, C.; Bakulin, A. A.; Pavelyev, V. G.; Pshenichnikov, M. S.; Bakker, H. J. Femtosecond Midinfrared Study of Aggregation Behavior in Aqueous Solutions of Amphiphilic Molecules J. Chem. Phys. 2010, 133, 164514
19. Di Michele, A.; Freda, M.; Onori, G.; Paolantoni, M.; Santucci, A.; Sassi, P. Modulation of Hydrophobic Effect by Cosolutes J. Phys. Chem. B 2006, 110, 21077-21085
20. Wilcox, D. S.; Rankin, B. M.; Ben-Amotz, D. Distinguishing Aggregation from Random Mixing in Aqueous T-Butyl Alcohol Solutions Faraday Disc. 2013, 167, 177-190
21. Comez, L.; Lupi, L.; Paolantoni, M.; Picchio, F.; Fioretto, D. Hydration Properties of Small Hydrophobic Molecules by Brillouin Light Scattering. J. Chem. Phys. 2012, 137.
22. Sinibaldi, R.; Casieri, C.; Melchionna, S.; Onori, G.; Segre, A. L.; Viel, S.; Mannina, L.; De Luca, F. The Role of Water Coordination in Binary Mixtures. A Study of Two Model Amphiphilic Molecules in Aqueous Solutions by Molecular Dynamics and Nmr J. Phys. Chem. B 2006, 110, 8885-8892
23. Fukasawa, T.; Tominaga, Y.; Wakisaka, A. Molecular Association in Binary Mixtures of Tert-Butyl Alcohol-Water and Tetrahydrofuran-Heavy Water Studied by Mass Spectrometry of Clusters from Liquid Droplets J. Phys. Chem. A 2004, 108, 59-63
24. Koga, Y.; Wong, T. Y. H.; Siu, W. W. Y. Vapor-Pressure of Aqueous Tert-Butanol in the Water-Rich Region-Transition in the Mixing Scheme Thermochim. Acta 1990, 169, 27-38
25. Shulgin, I. L.; Ruckenstein, E. Excess around a Central Molecule with Application to Binary Mixtures Phys. Chem. Chem. Phys. 2008, 10, 1097-1105
26. Koga, Y. Excess Partial Molar Enthalpies of Tert-Butanol in Water Tert-Butanol Mixtures Can. J. Chem. 1988, 66, 1187-1193
27. Clark, A. H.; Franks, F.; Pedley, M. D.; Reid, D. S. Solute Interactions in Dilute-Solutions 0.2. Statistical Mechanical Study of Hydrophobic Interaction J. Chem. Soc., Faraday Trans. 1 1977, 73, 290-305
28. Omelyan, I.; Kovalenko, A.; Hirata, F. Compressibility of Tert-Butyl Alcohol-Water Mixtures: The Rism Theory J. Theor. Comput. Chem. 2003, 2, 193-203
29. Wilcox, D. S.; Rankin, B. M.; Ben-Amotz, D. Distinguishing Aggregation from Random Mixing in Aqueous T-Butyl Alcohol Solutions Faraday Discuss. 2013, 167, 177-190
30. Bakulin, A. A.; Pshenichnikov, M. S.; Bakker, H. J.; Petersen, C. Hydrophobic Molecules Slow Down the Hydrogen-Bond Dynamics of Water J. Phys. Chem. A 2011, 115, 1821-1829
31. Lawton, W. H.; Sylvestre, E. A. Self Modeling Curve Resolution Technometrics 1971, 13, 617-633
32. Davis, J. G.; Gierszal, K. P.; Wang, P.; Ben-Amotz, D. Water Structural Transformation at Molecular Hydrophobic Interfaces Nature 2012, 491, 582-585
33. Davis, J. G.; Rankin, B. M.; Gierszal, K. P.; Ben-Amotz, D. On the Cooperative Formation of Non-Hydrogen Bonded Water at Molecular Hydrophobic Interfaces Nat. Chem. 2013, 5, 796-802
34. Fega, K. R.; Wilcox, D. S.; Ben-Amotz, D. Application of Raman Multivariate Curve Resolution to Solvation-Shell Spectroscopy Appl. Spectrosc. 2012, 66, 282-8
35. Ben-Amotz, D.; Herschbach, D. R. Estimation of Effective Diameters for Molecular Fluids J. Phys. Chem. 1990, 94, 1038-47
36. Tanaka, S. H.; Yoshihara, H. I.; Ho, A. W. C.; Lau, F. W.; Westh, P.; Koga, Y. Excess Partial Molar Enthalpies of Alkane-Mono-Ols in Aqueous Solutions Can. J. Chem. 1996, 74, 713-721
37. Raschke, T. M.; Tsai, J.; Levitt, M. Quantification of the Hydrophobic Interaction by Simulations of the Aggregation of Small Hydrophobic Solutes in Water Proc. Natl. Acad. Sci. U.S.A. 2001, 98, 5965-5969
38. Matsumoto, M. Four-Body Cooperativity in Hydrophonic Association of Methane J. Phys. Chem. Lett. 2010, 1, 1552-1556
39. Jacobson, L. C.; Hujo, W.; Molinero, V. Amorphous Precursors in the Nucleation of Clathrate Hydrates J. Am. Chem. Soc. 2010, 132, 11806-11811