메뉴 건너뛰기




Volumn 324, Issue , 2015, Pages 41-49

The Cu-ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures

Author keywords

CO2 valorization; Copper; Core shell structures; Cu ZnO synergy; Kirkendall effect; Mathematical model; Methanol synthesis; Sphere contact quantification; Structure activity relationships; Zinc oxide

Indexed keywords

CARBON DIOXIDE; COPPER; II-VI SEMICONDUCTORS; MATHEMATICAL MODELS; METHANOL; MIXTURES; OXYGEN VACANCIES; SHELLS (STRUCTURES); SPHERES; STRUCTURAL DESIGN; SYNTHESIS GAS MANUFACTURE; ZINC OXIDE;

EID: 84923298916     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2015.01.021     Document Type: Article
Times cited : (159)

References (39)
  • 2
    • 79959381321 scopus 로고    scopus 로고
    • Recent advances in catalytic hydrogenation of carbon dioxide
    • W. Wang, S. Wang, X. Ma, and J. Gong Recent advances in catalytic hydrogenation of carbon dioxide Chem. Soc. Rev. 40 2011 3703 3727
    • (2011) Chem. Soc. Rev. , vol.40 , pp. 3703-3727
    • Wang, W.1    Wang, S.2    Ma, X.3    Gong, J.4
  • 6
    • 0033149849 scopus 로고    scopus 로고
    • The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water-gas shift reaction
    • M.S. Spencer The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water-gas shift reaction Top. Catal. 8 1999 259 266
    • (1999) Top. Catal. , vol.8 , pp. 259-266
    • Spencer, M.S.1
  • 8
    • 0041038590 scopus 로고    scopus 로고
    • The role of ZnO in Cu/ZnO methanol synthesis catalysts
    • J. Nakamura, T. Uchijima, Y. Kanai, and T. Fujitani The role of ZnO in Cu/ZnO methanol synthesis catalysts Catal. Today 28 1996 223 230
    • (1996) Catal. Today , vol.28 , pp. 223-230
    • Nakamura, J.1    Uchijima, T.2    Kanai, Y.3    Fujitani, T.4
  • 14
    • 84901712741 scopus 로고    scopus 로고
    • Quantification of zinc atoms in a surface alloy on copper in an industrial-type methanol synthesis catalyst
    • S. Kuld, C. Conradsen, P.G. Moses, I. Chorkendorff, and J. Sehested Quantification of zinc atoms in a surface alloy on copper in an industrial-type methanol synthesis catalyst Angew. Chem., Int. Ed. 53 2014 5941 5945
    • (2014) Angew. Chem., Int. Ed. , vol.53 , pp. 5941-5945
    • Kuld, S.1    Conradsen, C.2    Moses, P.G.3    Chorkendorff, I.4    Sehested, J.5
  • 15
    • 0343344494 scopus 로고
    • Gas-phase transport of hydrogen atoms in methanol synthesis over copper/zinc oxide catalysts?
    • M.S. Spencer, R. Burch, and S.E. Golunski Gas-phase transport of hydrogen atoms in methanol synthesis over copper/zinc oxide catalysts? J. Chem. Soc., Faraday Trans. 86 1990 3151 3152
    • (1990) J. Chem. Soc., Faraday Trans. , vol.86 , pp. 3151-3152
    • Spencer, M.S.1    Burch, R.2    Golunski, S.E.3
  • 17
    • 33749540450 scopus 로고    scopus 로고
    • Preparation of Cu-Zn/ZnO core-shell nanocomposite by surface modification and precipitation process in aqueous solution and its photoluminescence properties
    • N. Yang, H. Yang, Y. Qu, Y. Fan, L. Chang, H. Zhu, M. Li, and G. Zou Preparation of Cu-Zn/ZnO core-shell nanocomposite by surface modification and precipitation process in aqueous solution and its photoluminescence properties Mater. Res. Bull. 41 2006 2154 2160
    • (2006) Mater. Res. Bull. , vol.41 , pp. 2154-2160
    • Yang, N.1    Yang, H.2    Qu, Y.3    Fan, Y.4    Chang, L.5    Zhu, H.6    Li, M.7    Zou, G.8
  • 20
    • 0000074194 scopus 로고
    • Turnover rates in heterogeneous catalysis
    • M. Boudart Turnover rates in heterogeneous catalysis Chem. Rev. (Washington, DC, US) 95 1995 661 666
    • (1995) Chem. Rev. (Washington, DC, US) , vol.95 , pp. 661-666
    • Boudart, M.1
  • 26
    • 0020341349 scopus 로고
    • Methanol synthesis
    • H.P.D.D. Eley, B.W. Paul, Academic Press
    • K. Klier Methanol synthesis H.P.D.D. Eley, B.W. Paul, Adv. Catal. 1982 Academic Press 243 313
    • (1982) Adv. Catal. , pp. 243-313
    • Klier, K.1
  • 30
    • 0042494074 scopus 로고    scopus 로고
    • The chemical modification seen in the Cu/ZnO methanol synthesis catalysts
    • T. Fujitani, and J. Nakamura The chemical modification seen in the Cu/ZnO methanol synthesis catalysts Appl. Catal. A: Gen. 191 2000 111 129
    • (2000) Appl. Catal. A: Gen. , vol.191 , pp. 111-129
    • Fujitani, T.1    Nakamura, J.2
  • 31
    • 0024055657 scopus 로고
    • Junction effect interactions in methanol synthesis catalysts
    • J.C. Frost Junction effect interactions in methanol synthesis catalysts Nature 334 1988 4
    • (1988) Nature , vol.334 , pp. 4
    • Frost, J.C.1
  • 33
    • 0002511064 scopus 로고
    • Infrared spectroscopy of chemisorbed carbon monoxide on copper
    • J. Pritchard, T. Catterick, and R.K. Gupta Infrared spectroscopy of chemisorbed carbon monoxide on copper Surf. Sci. 53 1975 1 20
    • (1975) Surf. Sci. , vol.53 , pp. 1-20
    • Pritchard, J.1    Catterick, T.2    Gupta, R.K.3
  • 35
    • 0021510155 scopus 로고
    • Characterization of copper-zinc catalysts by hydrogen thermodesorption. Correlation with activity in methanol synthesis
    • D. Duprez, J. Barbier, Z. Ferhat Hamida, and M. Bettahar Characterization of copper-zinc catalysts by hydrogen thermodesorption. correlation with activity in methanol synthesis Appl. Catal. 12 1984 219 225
    • (1984) Appl. Catal. , vol.12 , pp. 219-225
    • Duprez, D.1    Barbier, J.2    Hamida, Z.F.3    Bettahar, M.4
  • 36
    • 33845543008 scopus 로고
    • The role of copper and zinc oxide in methanol synthesis catalysts
    • R. Burch, S.E. Golunski, and M.S. Spencer The role of copper and zinc oxide in methanol synthesis catalysts J. Chem. Soc., Faraday Trans. 86 1990 2683 2691
    • (1990) J. Chem. Soc., Faraday Trans. , vol.86 , pp. 2683-2691
    • Burch, R.1    Golunski, S.E.2    Spencer, M.S.3
  • 37
    • 3943082588 scopus 로고
    • Rates of diffusion of copper and zinc in alpha brass
    • E. Kirkendall, L. Thomassen, and C. Upthegrove Rates of diffusion of copper and zinc in alpha brass Trans. AIME 133 1938 18
    • (1938) Trans. AIME , vol.133 , pp. 18
    • Kirkendall, E.1    Thomassen, L.2    Upthegrove, C.3
  • 38
    • 51349107792 scopus 로고    scopus 로고
    • Theory of grain boundary diffusion induced by the Kirkendall effect
    • H.-C. Yu, A. Van der Ven, and K. Thornton Theory of grain boundary diffusion induced by the Kirkendall effect Appl. Phys. Lett. 93 2008
    • (2008) Appl. Phys. Lett. , vol.93
    • Yu, H.-C.1    Van Der Ven, A.2    Thornton, K.3
  • 39
    • 1842309727 scopus 로고
    • Dense random packing of unequal spheres
    • 321
    • M.E. Wise Dense random packing of unequal spheres Philips Res. Reports 7 1952 321
    • (1952) Philips Res. Reports , vol.7
    • Wise, M.E.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.