The role of lattice oxygen on the activity and selectivity of the OMS-2 catalyst for the total oxidation of toluene

Chemical Engineering Journal

Volumn 270, Issue , 2015, Pages 58-65

  Sun, Hong ^a   Liu, Zhigang ^a   Chen, Shuo ^b   Quan, Xie ^b  

^a DALIAN JIAOTONG UNIVERSITY   (China)

^b DALIAN UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Catalytic oxidation; DRIFTS; Lattice oxygen; OMS 2; Reaction mechanism

Indexed keywords

CATALYST ACTIVITY; CATALYST SELECTIVITY; CATALYSTS; OXIDATION; OXYGEN; TOLUENE;

CATALYTIC OXIDATION OF TOLUENE; DRIFTS; HYDROTHERMAL METHODS; LATTICE OXYGEN; OMS-2; REACTION MECHANISM; TOLUENE OXIDATION; TOTAL OXIDATION OF TOLUENE;

CATALYTIC OXIDATION;

EID: 84923127299     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2015.02.017     Document Type: Article

References (35)

1. Scirè S., Minicò S., Crisafulli C., Satriano C., Pistone A. Catalytic combustion of volatile organic compounds on gold/cerium oxide catalysts. Appl. Catal., B: Environ. 2003, 40:43-49.
2. Alvarez-Merino M.A., Ribeiro M.F., Silva J.M., Carrasco-Marín F., Maldonado-Hódar F.J. Activated carbon and tungsten oxide supported on activated carbon catalysts for toluene catalytic combustion. Environ. Sci. Technol. 2004, 38:4664-4670.
3. 2 as a VOC removal catalyst: comparison with a noble metal Catalyst. J. Catal. 1998, 178:214-225.
4. Luo J., Zhang Q., Huang A., Suib S.L. Total oxidation of volatile organic compounds with hydrophobic cryptomelane-type octahedral molecular sieves. Microporous Mesoporous Mater. 2000, 35-36:209-217.
5. Lamaita L., Peluso M.A., Sambeth J.E., Thomas H.J. Synthesis and characterization of manganese oxides employed in VOCs abatement. Appl. Catal., B: Environ. 2005, 61:114-119.
6. Chen X., Shen Y.F., Suib S.L., O'Young C.L. Catalytic decomposition of 2-propanol over different metal-cation-doped OMS-2 materials. J. Catal. 2001, 197:292-302.
7. Ghosh R., Son Y.C., Makwana V.D., Suib S.L. Liquid-phase epoxidation of olefins by manganese oxide octahedral molecular sieves. J. Catal. 2004, 224:288-296.
8. Luo J., Zhang Q.H., Garcia-Martinez J., Suib S.L. Adsorptive and acidic properties, reversible lattice oxygen evolution, and catalytic mechanism of cryptomelane-type manganese oxides as oxidation catalysts. J. Am. Chem. Soc. 2008, 130:3198-3227.
9. Gandhe A.R., Rebello J.S., Figueiredo J.L., Fernandes J.B. Manganese oxide OMS-2 as an effective catalyst for total oxidation of ethyl acetate. Appl. Catal., B: Environ. 2007, 72:129-135.
10. Kim S.C., Shim W.G. Catalytic combustion of VOCs over a series of manganese oxide catalysts. Appl. Catal., B: Environ. 2010, 98:180-185.
11. Li J.H., Wang R.H., Hao J.M. Role of lattice oxygen and Lewis acid on ethanol oxidation over OMS-2 catalyst. J. Phys. Chem. 2010, 114:10544-10550.
12. Sun H., Chen S., Wang P., Quan X. Catalytic oxidation of toluene over manganese oxide octahedral molecular sieves (OMS-2) synthesized by different Methods. Chem. Eng. J. 2011, 178:191-196.
13. Iyer A., Galindo H., Sithambaram S., King'ondu C., Chen C.H., Suib S.L. Nanoscale manganese oxide octahedral molecular sieves (OMS-2) as efficient photocatalysts in 2-propanol oxidation. Appl. Catal., A: Gen. 2010, 375:295-302.
14. Deng J.G., Zhang L., Dai H.X., He H., Au C.T. Strontium-doped lanthanum cobaltite and manganite: highly active catalysts for toluene complete oxidation. Ind. Eng. Chem. Res. 2008, 47:8175-8183.
15. Santos V.P., Pereira M.F.R., Órfão J.J.M., Figueiredo J.L. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds. Appl. Catal., B: Environ. 2010, 99:353-363.
16. Makwana V.D., Garces L.J., Liu J., Cai J., Son Y., Suib S.L. Selective oxidation of alcohols using octahedral molecular sieves: influence of synthesis method and property-activity relations. Catal. Today 2003, 85:225-233.
17. Nagao M., Suda Y. Adsorption of benzene, toluene, and chlorobenzene on titanium dioxide. Langmuir 1989, 5:42-47.
18. 2 substrate and mesoporous SBA-15. Colloids Surf. A: Physicochem. Eng. Aspects 2006, 272:220-226.
19. 4. J. Catal. 1995, 151:204-215.
20. 2 catalysts: a Raman and in situ DRIFTS study. J. Mol. Catal. A: Chem. 2000, 162:401-411.
21. Zhang Y., Martin A., Berndt H., Lücke B., Meisel M. FTIR investigation of surface intermediates formed during the ammoxidation of toluene over vanadyl pyrophosphate. J. Mol. Catal. A: Chem. 1997, 118:205-214.
22. Augustine S.M., Sachtler W.M.H. Catalytic probe for alloy formation in supported PtRe catalysts: isotope exchange and hydrogenolysis of cyclopentane. J. Catal. 1987, 106:417-427.
23. 3: an in situ ATR-IR study. J. Phys. Chem. B 2005, 109:958-967.
24. Augugliaro V., Kisch H., Loddo V., López-Muñoz M.J., Márquez-Álvarez C., Palmisano G., Palmisano L., Parrino F., Yurdakal S. Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home prepared titanium dioxide: 2. Intrinsic and surface features of catalysts. Appl. Catal., A: Gen. 2008, 349:189-197.
25. Keresszegi G., Ferri D., Mallat T., Baiker A. Unraveling the surface reactions during liquid-phase oxidation of benzyl alcohol on Pd/Al2O3: an in situ ATR-IR study. J. Phys. Chem. B 2005, 109:958-967.
26. 2. J. Catal. 1986, 10:323-330.
27. Bentrup U., Martin A., Lücke B. Infrared characterization of the surface intermediates in the oxidation of toluene on vanadyl pyrophosphate catalysts. Top. Catal. 2000, 11(12):139-145.
28. Finocchio E., Montanari T., Resini C., Busca G. Spectroscopic characterization of cobalt-containing solid catalysts. J. Mol. Catal. A: Chem. 2003, 204-205:535-544.
29. Su B.L., Norberg V., Martens J.A. An infrared study on the location of benzene molecules and cations in Cs+-exchanged EMT zeolite. Microporous Mesoporous Mater. 1998, 25:151-157.
30. Nozaki T., Hattori A., Okazaki K. Partial oxidation of methane using a microscale non-equilibrium plasma reactor. Catal. Today 2004, 98:607-616.
31. 2 over catalyst under pulse corona plasma. Catal. Today 2004, 89:97-102.
32. DeGuzman R.N., Shen Y.F., Neth E.J., Suib S.L., O'Young C.L., Levine S., Newsam M. Synthesis and characterization of octahedral molecular sieves (OMS-2) having the hollandite structure. Chem. Mater. 1994, 6:815-821.
33. 3; B = manganese, iron, cobalt, nickel) for toluene oxidation. Ind. Eng. Chem. Res. 1993, 32:2563-2572.
34. x catalysts synthesized via a novel "redox-precipitation" route. Chem. Mater. 2007, 19:2269-2276.
35. Moro-oka Y. Reactivities of active oxygen species and their roles in the catalytic oxidation of inactive hydrocarbon. Catal. Today 1998, 45:3-12.