n-butane carbonylation to n-pentanal using a cascade reaction of dehydrogenation and SILP-catalyzed hydroformylation

AIChE Journal

Volumn 61, Issue 3, 2015, Pages 893-897

  Walter, Simon ^a   Haumann, Marco ^a   Wasserscheid, Peter ^a   Hahn, Hanna ^b   Franke, Robert ^b,c  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b EVONIK INDUSTRIES AG   (Germany)

^c RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Cascade reaction; Catalysis; Dehydrogenation; Hydroformylation; Supported ionic liquids

Indexed keywords

BUTANE; CARBONYLATION; CATALYSIS; GASES; HYDROFORMYLATION; IONIC LIQUIDS; LIGANDS; RHODIUM COMPOUNDS;

ALKANE DEHYDROGENATIONS; CASCADE REACTIONS; DIPHOSPHITE LIGANDS; GAS PHASE HYDROFORMYLATION; GAS PHASE PROCESS; RHODIUM COMPLEXES; SUPPORTED IONIC LIQUID-PHASE; SUPPORTED IONIC LIQUIDS;

DEHYDROGENATION;

EID: 84922644267     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.14676     Document Type: Article

References (23)

1. Cornils B, Herrmann WA. Applied homogeneous catalysis with organometallic compounds: a comprehensive handbook in three volumes. 2nd, completely rev. and enlarged ed. Weinheim: Wiley-VCH, 2002.
2. Franke R, Selent D, Börner A. Applied hydroformylation. Chem Rev. 2012;112(11):5675-5732.
3. Armor JN. Emerging importance of shale gas to both the energy & chemicals landscape. J Energy Chem. 2013;22(1):21-26.
4. Majhi S, Mohanty P, Wang H, Pant KK. Direct conversion of natural gas to higher hydrocarbons: a review. J Energy Chem. 2013;22(4):543-554.
5. Ertl G, Knözinger H, Weitkamp J. Handbook of Heterogeneous Catalysis. Weinheim: VCH, 1997.
6. Bohnen H-W, Cornils B. Hydroformylation of alkenes: an industrial view of the status and importance. Adv Catal 2002;47:1-64.
7. Mehnert CP, Cook RA, Dispenziere NC, Afeworki M. Supported ionic liquid catalysis-a new concept for homogeneous hydroformylation catalysis. J Am Chem Soc. 2002;124(44):12932-12933.
8. Riisager A, Wasserscheid P, van Hal R, Fehrmann R. Continuous fixed-bed gas-phase hydroformylation using supported ionic liquid-phase (SILP) Rh catalysts. J Catal. 2003;219(2):452-455.
9. Haumann M, Dentler K, Joni J, Riisager A, Wasserscheid P. Continuous gas-phase hydroformylation of 1-butene using supported ionic liquid phase (SILP) catalysts. Adv Synth Catal. 2007;349(3):425-431.
10. Riisager A, Fehrmann R, Haumann M, Wasserscheid P. Catalytic SILP Materials. In: Leitner W, Hölscher M, editors. Regulated Systems for Multiphase Catalysis, vol. 23. Berlin: Springer, 2008:149-161.
11. Haumann M, Riisager A. Hydroformylation in Room temperature ionic liquids (RTILs): catalyst and process developments. Chem Rev. 2008;108(4):1474-1497.
12. Werner S, Szesni N, Kaiser M, Haumann M, Wasserscheid P. A scalable preparation method for SILP and SCILL ionic liquid thin-film materials. Chem Eng Technol. 2012;35(11):1962-1967.
13. Schneider MJ, Lijewski M, Woelfel R, Haumann M, Wasserscheid P. Continuous gas-phase hydroaminomethylation using supported ionic liquid phase catalysts. Angew Chem Int Ed. 2013;52(27):6996-6999.
14. Öchsner E, Schneider MJ, Meyer C, Haumann M, Wasserscheid P. Challenging the scope of continuous, gas-phase reactions with supported ionic liquid phase (SILP) catalysts-asymmetric hydrogenation of methyl acetoacetate. Appl Catal A. 2011;399(1-2):35-41.
15. Scholz J, Demin A, Loekman S, Szesni N, Hieringer W, Görling A, Haumann M, Wasserscheid P. Ethene-induced temporary inhibition of grubbs metathesis catalysts. Adv Synth Catal. 2011;353(14-15):2701-2707.
16. 4 feedstocks. Angew Chem Int Ed. 2011;50(19):4492-4495.
17. 4 Feed using supported ionic liquid phase catalysts. ChemCatChem. 2011;3(11):1822-1827.
18. Weckhuysen BM, Wachs IE, Schoonheydt RA. Surface chemistry and spectroscopy of chromium in inorganic oxides. Chem Rev. 1996;96(8):3327-3350.
19. Voge HH, May NC. Isomerization equilibria among the n-butenes. J Am Chem Soc. 1946;68(4):550-553.
20. Evans D, Osborn JA, Wilkinson G. Hydroformylation of alkenes by use of rhodium complex catalysts. J Chem Soc A. 1968(0):3133-3142.
21. Brown CK, Wilkinson G. Homogeneous hydroformylation of alkenes with hydridocarbonyltris-(triphenylphosphine)rhodium(I) as catalyst. J Chem Soc A. 1970(0):2753-2764.
22. Schönweiz A, Debuschewitz J, Walter S, et al. Ligand-modified rhodium catalysts on porous silica in the continuous gas-phase hydroformylation of short-chain alkenes-catalytic reaction in liquid-supported aldol products. ChemCatChem. 2013;5(10):2955-2963.
23. Selent D, Franke R, Kubis C, et al. A new diphosphite promoting highly regioselective rhodium-catalyzed hydroformylation. Organometallics. 2011;30(17):4509-4514.