Mesoporous magnesium oxide and its composites: Preparation, characterization, and removal of 2-chloroethyl ethyl sulfide

Chemical Engineering Journal

Volumn 269, Issue , 2015, Pages 82-93

  Vu, Anh Tuan ^a,b   Jiang, Shunbo ^a   Ho, Keon ^a   Lee, Joong Beom ^c   Lee, Chang Ha ^a  

^a Yonsei University   (South Korea)

^b HANOI UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Viet Nam)

^c Korea Electric Power Research Institute (KEPRI)   (South Korea)

Author keywords

2 CEES; Aerogel; Composite; Magnesium oxide; Sorption

Indexed keywords

AEROGELS; COMPOSITE MATERIALS; MAGNESIUM; SORPTION;

2-CEES; 2-CHLOROETHYL ETHYL SULFIDES; AMBIENT CONDITIONS; BREAKTHROUGH EXPERIMENT; MESOPOROUS; MGO; SORPTION CAPACITIES; SURFACE AREA;

MAGNESIA;

EID: 84922625410     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2015.01.089     Document Type: Article

References (38)

1. Khan N.A., Hasan Z., Jhung S.H. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J. Hazard. Mater. 2013, 244-245:444-456.
2. Barea E., Montoro C., Navarro J.A.R. Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours. Chem. Soc. Rev. 2014, 43:5419-5430.
3. Yang Y.C., Baker J.A., Ward J.R. Decontamination of chemical warfare agents. Chem. Rev. 1992, 92:1729-1743.
4. 3. Formation of aluminophosphonates. J. Am. Chem. Soc. 2001, 123:1636-1644.
5. Park Y., Kim S., Kim H., Jung K., Jeong K.-E., Jeong S.-Y., Jeon J.-K. Removal of sulfur dioxide from dibenzothiophene sulfone over Mg-based oxide catalysts prepared by spray pyrolysis. Korean J. Chem. Eng. 2010, 27:459-464.
6. Utamapanya S., Klabunde K.J., Schlup J.R. Nanoscale metal oxide particles/clusters as chemical reagents. Synthesis and properties of ultrahigh surface area magnesium hydroxide and magnesium oxide. Chem. Mater. 1991, 3:175-181.
7. Kim Y.-H., Tuan V.A., Park M.-K., Lee C.-H. Sulfur removal from municipal gas using magnesium oxides and a magnesium oxide/silicon dioxide composite. Microporous Mesoporous Mater. 2014, 197:299-307.
8. 3/MgO nanocomposite prepared via a simple precipitation method. Mater. Chem. Phys. 2010, 124:658-663.
9. Rakmak N., Wiyaratn W., Bunyakan C., Chungsiriporn J. Synthesis of Fe/MgO nano-crystal catalysts by sol-gel method for hydrogen sulfide removal. Chem. Eng. J. 2010, 162:84-90.
10. Lim S.-H., Woo E.-J., Lee H., Lee C.-H. Synthesis of magnetite-mesoporous silica composites as adsorbents for desulfurization from natural gas. Appl. Catal. B 2008, 85:71-76.
11. Bae Y.-S., Kim M.-B., Lee H.-J., Lee C.-H., Wook Ryu J. Adsorptive denitrogenation of light gas oil by silica-zirconia cogel. AlChE J. 2006, 52:510-521.
12. Kwon J.-M., Moon J.-H., Bae Y.-S., Lee D.-G., Sohn H.-C., Lee C.-H. Adsorptive desulfurization and denitrogenation of refinery fuels using mesoporous silica adsorbents. ChemSusChem 2008, 1:307-309.
13. Koriakin A., Kim Y.-H., Lee C.-H. Adsorptive desulfurization of natural gas using lithium-modified mesoporous silica. Ind. Eng. Chem. Res. 2012, 51:14489-14495.
14. Saxena A., Srivastava A.K., Singh B. Kinetics of adsorption of 2-CEES and HD on impregnated silica nanoparticles under static conditions. AlChE J. 2009, 55:1236-1245.
15. 4) aerogels. J. Non-Cryst. Solids 1998, 225:125-129.
16. 2 modified by MgO, NaOH and LiOH. Appl. Catal. A 2009, 368:65-70.
17. López T., Gómez R., Llanos M.E., Garcia-Figueroa E., Navarrete J., López-Salinas E. On the surface basic properties of sulfated magnesia-silica sol-gel mixed oxides. Mater. Lett. 1999, 39:51-57.
18. Kanyi C.W., Doetschman D.C., Schulte J.T. Nucleophilic chemistry of X-type Faujasite zeolites with 2-chloroethyl ethyl sulfide (CEES), a simulant of common mustard gas. Microporous Mesoporous Mater. 2009, 124:232-235.
19. 3 nanoparticles. J. Chem. Eng. Data 2012, 57:1456-1462.
20. Roy A., Srivastava A.K., Singh B., Mahato T.H., Shah D., Halve A.K. Degradation of sulfur mustard and 2-chloroethyl ethyl sulfide on Cu-BTC metal organic framework. Microporous Mesoporous Mater. 2012, 162:207-212.
21. Kleinhammes A., Wagner G.W., Kulkarni H., Jia Y., Zhang Q., Qin L.-C., Wu Y. Decontamination of 2-chloroethyl ethylsulfide using titanate nanoscrolls. Chem. Phys. Lett. 2005, 411:81-85.
22. 2 powders. J. Phys. Chem. B 2003, 107:10560-10564.
23. Wagner G.W., Koper O.B., Lucas E., Decker S., Klabunde K.J. Reactions of VX, GD, and HD with nanosize CaO: autocatalytic dehydrohalogenation of HD. J. Phys. Chem. B 2000, 104:5118-5123.
24. 3 surfaces. Langmuir 1999, 15:4789-4795.
25. Narske R.M., Klabunde K.J., Fultz S. Solvent effects on the heterogeneous adsorption and reactions of (2-chloroethyl)ethyl sulfide on nanocrystalline magnesium oxide. Langmuir 2002, 18:4819-4825.
26. Mahato T.H., Singh B., Srivastava A.K., Prasad G.K., Srivastava A.R., Ganesan K., Vijayaraghavan R. Effect of calcinations temperature of CuO nanoparticle on the kinetics of decontamination and decontamination products of sulphur mustard. J. Hazard. Mater. 2011, 192:1890-1895.
27. 2 capture at intermediate temperatures. Chem. Eng. J. 2014, 258:254-264.
28. 2 nanorods synthesized by a facile hydrothermal method in the presence of CTAB. Nano-Micro Lett. 2011, 3:153-159.
29. 2O and MgO complex nanostructures: controllable biomimetic fabrication and physical chemical properties. Phys. Chem. Chem. Phys. 2011, 13:5047-5052.
30. Hacquart R., Krafft J.-M., Costentin G., Jupille J. Evidence for emission and transfer of energy from excited edge sites of MgO smokes by photoluminescence experiments. Surf. Sci. 2005, 595:172-182.
31. Klabunde K.J., Stark J., Koper O., Mohs C., Park D.G., Decker S., Jiang Y., Lagadic I., Zhang D. Nanocrystals as stoichiometric reagents with unique surface chemistry. J. Phys. Chem. B 1996, 100:12142-12153.
32. Arcibar-Orozco J.A., Bandosz T.J. Visible light enhanced removal of a sulfur mustard gas surrogate from a vapor phase on novel hydrous ferric oxide/graphite oxide composites. J. Mater. Chem. A 2015, 3:220-231.
33. Stout S.C., Larsen S.C., Grassian V.H. Adsorption, desorption and thermal oxidation of 2-CEES on nanocrystalline zeolites. Microporous Mesoporous Mater. 2007, 100:77-86.
34. 3 magnetic nanorods and application to the detection of uric acid. RSC Adv. 2014, 4:17146-17155.
35. 3/MgO system doped with aluminium and zinc oxides. Thermochim. Acta 2003, 408:75-84.
36. Ay A.N., Konuk D., Zümreoğlu-Karan B. Magnetic nanocomposites with drug-intercalated layered double hydroxide shell supported on commercial magnetite and laboratory-made magnesium ferrite core materials. Mater. Sci. Eng., C 2011, 31:851-857.
37. Zhao S., Yi H., Tang X., Gao F., Zhang B., Wang Z., Zuo Y. Methyl mercaptan removal from gas streams using metal-modified activated carbon. J. Cleaner Prod. 2015, 87:856-861.
38. Subhan F., Liu B.S., Zhang Y., Li X.G. High desulfurization characteristic of lanthanum loaded mesoporous MCM-41 sorbents for diesel fuel. Fuel Process. Technol. 2012, 97:71-78.