Sulfur isotopic composition of individual organic compounds from Cariaco Basin sediments

Organic Geochemistry

Volumn 80, Issue , 2015, Pages 53-59

  Raven, Morgan Reed ^a   Adkins, Jess F ^a   Werne, Josef P ^b   Lyons, Timothy W ^c   Sessions, Alex L ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF PITTSBURGH   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cariaco Basin; Kerogen; Organosulfur compounds; Sediment diagenesis; Sulfur isotopes

Indexed keywords

GAS CHROMATOGRAPHY; ISOTOPES; KEROGEN; MASS SPECTROMETRY; OIL SHALE; ORGANIC COMPOUNDS; SEDIMENTOLOGY; SEDIMENTS; SULFUR;

CARIACO BASINS; INDIVIDUAL ORGANIC COMPOUNDS; IRREVERSIBLE REACTIONS; KINETIC ISOTOPE EFFECTS; ORGANOSULFUR COMPOUNDS; PRESERVATION OF ORGANIC MATTERS; SULFUR ISOTOPE; SULFURIZATION REACTIONS;

SULFUR COMPOUNDS;

DIAGENESIS; ISOTOPIC COMPOSITION; MOLECULAR ANALYSIS; ORGANIC COMPOUND; SEDIMENT CHEMISTRY; SULFIDE; SULFUR COMPOUND; SULFUR ISOTOPE; TIMESCALE; VOLATILE ORGANIC COMPOUND;

ATLANTIC OCEAN; CARIACO BASIN; CARIBBEAN SEA;

EID: 84922442500     PISSN: 01466380     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.orggeochem.2015.01.002     Document Type: Article

References (45)

1. Aizenshtat, Z., Krein, E., Vairavamurthy, M.A., Goldstein, T., 1995. Role of sulfur in the transformations of sedimentary organic matter: a mechanistic overview. In: Geochemical Transformations of Sedimentary Sulfur. ACS Symposium Series 612. Washington, DC, pp. 16-37.
2. 34S imprint. Organic Geochemistry 2004, 35:1319-1336.
3. Amrani A., Aizenshtat Z. Reaction of polysulfide anions with α, β unsaturated isoprenoid aldehydes in aquatic media: simulation of oceanic conditions. Organic Geochemistry 2004, 35:909-921.
4. Amrani A., Deev A., Sessions A., Tang Y., Adkins J., Hill R., Moldowan M., Wei Z. The sulfur-isotopic compositions of benzothiophenes and dibenzothiophenes as a proxy for thermochemical sulfate reduction. Geochimica et Cosmochimica Acta 2012, 84:152-164.
5. 2S aqueous solution. Inorganic Chemistry 2006, 45:1427-1429.
6. 34S analysis of volatile organics by coupled GC/multicollector-ICPMS. Analytical Chemistry 2009, 81:9027-9034.
7. Anderson, T.F., Pratt, L.M., 1995. Isotopic evidence for the origin of organic sulfur and elemental sulfur in marine sediments. In: Geochemical Transformations of Sedimentary Sulfur. ACS Symposium Series 612, Washington, DC, pp. 378-396.
8. Aycard M., Derenne S., Largeau C., Mongenot T., Tribovillard N., Baudin F. Formation pathways of proto-kerogens in Holocene sediments of the upwelling influenced Cariaco Trench, Venezuela. Organic Geochemistry 2003, 34:701-718.
9. Bottrell S.H., Raiswell R. Sulphur isotopes and microbial sulphur cycling in sediments. Microbial Sediments 2000, 96-104. Springer, Berlin Heidelberg. R. Riding, S. Awramik (Eds.).
10. Brassell S.C., Lewis C.A., De Leeuw J.W., de Lange F., Damsté J.S. Isoprenoid thiophenes: novel products of sediment diagenesis?. Nature 1986, 320:160-162.
11. Brüchert V., Pratt L.M. Contemporaneous early diagenetic formation of organic and inorganic sulfur in estuarine sediments from St. Andrew Bay, Florida, USA. Geochimica et Cosmochimica Acta 1996, 60:2325-2332.
12. Dale A.W., Bruchert V., Alperin M., Regnier P. An integrated sulfur isotope model for Namibian shelf sediments. Geochimica et Cosmochimica Acta 2009, 73:1924-1944.
13. Damsté J., Rijpstra I., Coolen M., Schouten S., Volkman J. Rapid sulfurisation of highly branched isoprenoid (HBI) alkenes in sulfidic Holocene sediments from Ellis Fjord, Antarctica. Organic Geochemistry 2007, 38:128-139.
14. Damsté J.S.S., De Leeuw J.W. Analysis, structure and geochemical significance of organically-bound sulphur in the geosphere: state of the art and future research. Organic Geochemistry 1990, 16:1077-1101.
15. Damsté J.S.S., De Leeuw J.W., Dalen A.K.-V., de Zeeuw M.A., de Lange F., Rijpstra W., Schenck P.A. The occurrence and identification of series of organic sulphur compounds in oils and sediment extracts. I. A study of Rozel Point Oil (U.S.A.). Geochimica et Cosmochimica Acta 1987, 51:2369-2391.
16. de Graaf W., Damsté J.S., De Leeuw J.W. Laboratory simulation of natural sulphurization: I. Formation of monomeric and oligomeric isoprenoid polysulphides by low-temperature reactions of inorganic polysulphides with phytol and phytadienes. Geochimica et Cosmochimica Acta 1992, 56:4321-4328.
17. Eglinton T.I., Irvine J.E., Vairavamurth, Zhou W., Manowitz B. Formation and diagenesis of macromolecular organic sulfur in Peru margin sediments. Organic Geochemistry 1994, 22:781-799.
18. Francois R. A study of sulphur enrichment in the humic fraction of marine sediments during early diagenesis. Geochimica et Cosmochimica Acta 1987, 51:17-27.
19. 20 isoprenoid thiophenes in modern sediments. Organic Geochemistry 1992, 18:83-91.
20. Gelin F., Kok M.D., De Leeuw J.W., Damsté J.S.S. Laboratory sulfurisation of the marine microalga Nannochloropsis salina. Organic Geochemistry 1998, 29:1837-1848.
21. C contents of sedimentary organic compounds: principles and evidence. Marine Geology 1993, 113:111-125.
22. Kohnen M.E.L., Damsté J.S., Kock-van Dalen A.C., Ten Haven H.L., Rullkötter J., De Leeuw J.W. Origin and diagenetic transformations of C25 and C30 highly branched isoprenoid sulphur compounds: Further evidence for the formation of organically bound sulphur during early diagenesis. Geochimica et Cosmochimica Acta 1990, 54:3053-3063.
23. 30 highly branched isoprenoid sulphur compounds: further evidence for the formation of organically bound sulphur during early diagenesis. Geochimica et Cosmochimica Acta 1990, 54:3053-3063.
24. Kok M., Schouten S., Damsté J.S. Formation of insoluble, nonhydrolyzable, sulfur-rich macromolecules via incorporation of inorganic sulfur species into algal carbohydrates. Geochimica et Cosmochimica Acta 2000, 64:2689-2699.
25. Krein E.B., Aizenshtat Z. The formation of isoprenoid sulfur compounds during diagenesis: simulated sulfur incorporation and thermal transformation. Organic Geochemistry 1994, 21:1015-1025.
26. Li X., Cutter G.A., Thunell R.C., Tappa E., Gilhooly W.P., Lyons T.W., Astor Y., Scranton M.I. Particulate sulfur species in the water column of the Cariaco Basin. Geochimica et Cosmochimica Acta 2011, 75:148-163.
27. Li X., Gilhooly W.P., Zerkle A.L., Lyons T.W., Farquhar J., Werne J.P., Varela R., Scranton M.I. Stable sulfur isotopes in the water column of the Cariaco Basin. Geochimica et Cosmochimica Acta 2010, 74:6764-6778.
28. Lin H., Peterson L., Overpeck J., Trumbore S., Murray D. Later Quaternary climate change from d18O records of multiple species of planktonic foraminifera: High-resolution records from the anoxic Cariaco Basin, Venezuela. Paleooceanography 1997, 12:415-427.
29. LaLonde R., Ferrara L., Hayes M. Low-temperature, polysulfide reactions of conjugated ene carbonyls: a reaction model for the geologic origin of S-heterocycles. Organic Geochemistry 1987, 11:563-571.
30. Lyons T.W., Werne J.P., Hollander D.J., Murray R.W. Contrasting sulfur geochemistry and Fe/Al and Mo/Al ratios across the last oxic-to-anoxic transition in the Cariaco Basin, Venezuela. Chemical Geology 2003, 195:131-157.
31. 33S in small amounts of dissolved sulfate. Chemical Geology 2013, 345:50-61.
32. Putschew A., Scholz-Böttcher B.M., Rullkötter J. Early diagenesis of organic matter and related sulphur incorporation in surface sediments of meromictic Lake Cadagno in the Swiss Alps. Organic Geochemistry 1996, 25:379-390.
33. Rickard D., Luther G.I. Chemistry of iron sulfides. Chemical Reviews 2007, 107:514-562.
34. Rowland S., Rockey C., Al-Lihaibi S.S., Wolff G.A. Incorporation of sulphur into phytol derivatives during simulated early diagenesis. Organic Geochemistry 1993, 20:1-5.
35. Schmid J.C., Connan J., Albrecht P. Occurrence and geochemical significance of long-chain dialkylthiacyclopentanes. Nature 1987, 329:54-56.
36. Schouten S., de Graaf W., Damsté J.S., van Driel G., De Leeuw J.W. Laboratory simulation of natural sulphurization: II. Reaction of multi-functionalized lipids with inorganic polysulphides at low temperatures. Organic Geochemistry 1994, 22:825-834.
37. Schwarzenbach G., Fischer A. Die acidität der sulfane und die zusammensetzung wässeriger polysulfidlösungen. Helvetica Chimica Acta 1960, 43:1365-1390.
38. Shipboard Scientific Party, 1997. In: Proceedings of the Ocean Drilling Program, Initial Reports. College Station, TX.
39. Vairavamurthy A., Mopper K. Geochemical formation of organosulphur compounds (thiols) by addition of HS to sedimentary organic matter. Nature 1987, 329:623-625.
40. Vairavamurthy A., Zhou W., Eglinton T., Manowitz B. Sulfonates: a novel class of organic sulfur compounds in marine sediments. Geochimica et Cosmochimica Acta 1994, 58:4681-4687.
41. Vandenbroucke M., Largeau C. Kerogen origin, evolution and structure. Organic Geochemistry 2007, 38:719-833.
42. Wakeham S., Damsté J.S., Kohnen M., De Leeuw J.W. Organic sulfur compounds formed during early diagenesis in Black Sea sediments. Geochimica et Cosmochimica Acta 1995, 59:521-533.
43. Werne J., Hollander D., Behrens A., Schaeffer P., Albrecht P., Damsté J. Timing of early diagenetic sulfurization of organic matter: a precursor-product relationship in early Holocene sediments of the anoxic Cariaco Basin, Venezuela. Geochimica et Cosmochimica Acta 2000, 65:1741-1751.
44. Werne J., Lyons T., Hollander D., Formolo M., Damsté J. Reduced sulfur in euxinic sediments of the Cariaco Basin: sulfur isotope constrains on organic sulfur formation. Chemical Geology 2003, 195:159-179.
45. Werne J., Lyons T., Hollander D., Schouten S., Hopmans E., Damsté J. Investigating pathways of diagenetic organic matter sulfurization using compound-specific sulfur isotope analysis. Geochimica et Cosmochimica Acta 2008, 72:3489-3502.