메뉴 건너뛰기




Volumn 136, Issue 37, 2014, Pages 12844-12847

Superacidity in sulfated metal-organic framework-808

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICALS REMOVAL (WATER TREATMENT); CRYSTALLINE MATERIALS; DISSOCIATION; JAVA PROGRAMMING LANGUAGE; ORGANOMETALLICS; SINGLE CRYSTALS; X RAY DIFFRACTION ANALYSIS; ZIRCONIUM;

EID: 84921529033     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja507119n     Document Type: Article
Times cited : (487)

References (69)
  • 48
    • 84950248696 scopus 로고    scopus 로고
    • Two crystallographically independent S atoms were located in the difference Fourier maps with a refined occupancy value of 0.2 and assigned to two sulfate ligands coordinating to the SBU with chelating and bridging modes. The uncoordinated O atoms for the former could be located but with high thermal displacement parameters, which were refined isotropically; the uncoordinated O atoms for the latter could not be located due to disorder. Nevertheless, an area of large residual electron density in the vicinity of this S atom was identified in the difference Fourier maps, which we attribute to the two remaining O atoms being dynamically and/or positionally disordered
    • Two crystallographically independent S atoms were located in the difference Fourier maps with a refined occupancy value of 0.2 and assigned to two sulfate ligands coordinating to the SBU with chelating and bridging modes. The uncoordinated O atoms for the former could be located but with high thermal displacement parameters, which were refined isotropically; the uncoordinated O atoms for the latter could not be located due to disorder. Nevertheless, an area of large residual electron density in the vicinity of this S atom was identified in the difference Fourier maps, which we attribute to the two remaining O atoms being dynamically and/or positionally disordered.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.