Evidence from in situ X-ray absorption spectroscopy for the involvement of terminal disulfide in the reduction of protons by an amorphous molybdenum sulfide electrocatalyst

Journal of the American Chemical Society

Volumn 137, Issue 1, 2015, Pages 314-321

  Lassalle Kaiser, Benedikt ^a,b   Merki, Daniel ^c   Vrubel, Heron ^c   Gul, Sheraz ^a   Yachandra, Vittal K ^a   Hu, Xile ^c   Yano, Junko ^a  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b SYNCHROTRON SOLEIL   (France)

^c EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS FILMS; ELECTROCATALYSTS; ELECTRONIC STRUCTURE; HYDROGEN; HYDROGEN BONDS; MOLYBDENUM; MOLYBDENUM COMPOUNDS; PROTONS; TRANSITION METALS; X RAY ABSORPTION SPECTROSCOPY;

ENERGY APPLICATIONS; IN-SITU X-RAY ABSORPTION SPECTROSCOPY; MOLYBDENUM SULFIDE; RATE-LIMITING STEPS; REACTION MECHANISM; REDUCTION OF PROTONS; SPECTROSCOPIC FEATURES; TRANSITION METAL SULFIDES;

SULFUR COMPOUNDS;

HYDROGEN; MOLYBDENUM; NITRIC ACID; PROTON; SULFIDE; SULFUR; DISULFIDE; MOLYBDENUM DISULFIDE;

ARTICLE; CATALYST; CRYSTAL STRUCTURE; DISULFIDE BOND; ELECTROCHEMICAL ANALYSIS; ELECTROCHEMISTRY; PH; PROTON TRANSPORT; REACTION ANALYSIS; REDUCTION KINETICS; SPECTRUM; X RAY ABSORPTION SPECTROSCOPY; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION;

CATALYSIS; DISULFIDES; ELECTROCHEMICAL TECHNIQUES; HYDROGEN; MOLECULAR STRUCTURE; MOLYBDENUM; OXIDATION-REDUCTION; PROTONS; X-RAY ABSORPTION SPECTROSCOPY;

EID: 84921047276     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja510328m     Document Type: Article

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