메뉴 건너뛰기




Volumn 12, Issue 1, 2015, Pages 67-78

Technical note: Large overestimation of pCO2 calculated from pH and alkalinity in acidic, organic-rich freshwaters

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; ALKALINITY; BIOGEOCHEMISTRY; BUFFERING; CARBON DIOXIDE; CARBON FLUX; CONCENTRATION (COMPOSITION); DISSOLVED ORGANIC CARBON; FRESHWATER; PH;

EID: 84920735778     PISSN: 17264170     EISSN: 17264189     Source Type: Journal    
DOI: 10.5194/bg-12-67-2015     Document Type: Article
Times cited : (264)

References (50)
  • 1
    • 84898609554 scopus 로고    scopus 로고
    • Evaluating a fast headspace method for measuring DIC and subsequent calculation of pCO2 in freshwater systems
    • Åberg, J. and Wallin M. B.: Evaluating a fast headspace method for measuring DIC and subsequent calculation of pCO2 in freshwater systems, Inland Wat. 4,157-166, 2014.
    • (2014) Inland Wat. , vol.4 , pp. 157-166
    • Åberg, J.1
  • 3
    • 29944438802 scopus 로고    scopus 로고
    • In-Situ measurements of dissolved gases (CO2 and CH4) in a wide range of concentrations in a tropical reservoir using an equilibrator
    • Abril, G., Richard, S., and Guérin, F.: In-Situ measurements of dissolved gases (CO2 and CH4) in a wide range of concentrations in a tropical reservoir using an equilibrator, Sc. Total Envir., 354, 246-251, 2006.
    • (2006) Sc. Total Envir. , vol.354 , pp. 246-251
    • Abril, G.1    Richard, S.2    Guérin, F.3
  • 7
    • 84908180945 scopus 로고    scopus 로고
    • Carbon cycling of Lake Kivu (East Africa): Net autotrophy in the epilimnion and emission of CO2 to the atmosphere sustained by geogenic inputs
    • Borges, A. V.,Morana, C., Bouillon, S., Servais, P., Descy, J.-P., and Darchambeau, F.: Carbon cycling of Lake Kivu (East Africa): net autotrophy in the epilimnion and emission of CO2 to the atmosphere sustained by geogenic inputs, PLoS ONE, 9, e109500, doi:10.1371/journal.pone.0109500, 2014.
    • (2014) PLoS ONE , vol.9 , pp. e109500
    • Borges, V.1    Morana A, C.2    Bouillon, S.3    Servais, P.4    Descy, J.-P.5    Darchambeau, F.6
  • 8
    • 82455163926 scopus 로고    scopus 로고
    • Significant efflux of carbon dioxide from streams and rivers in the United States
    • Butman, D. and Raymond, P.A.: Significant efflux of carbon dioxide from streams and rivers in the United States, Nature Geosci., 4, 839-842, 2011.
    • (2011) Nature Geosci. , vol.4 , pp. 839-842
    • Butman, D.1    Raymond, P.A.2
  • 9
    • 0031826165 scopus 로고    scopus 로고
    • Acid-base properties of dissolved organic matter in the estuarine waters of Georgia, USA
    • Cai, W.-J., Wang, Y., and Hodson, R. E.: Acid-base properties of dissolved organic matter in the estuarine waters of Georgia, USA, Geochim. Cosmochim. Ac., 62, 473-483, 1998.
    • (1998) Geochim. Cosmochim. Ac. , vol.62 , pp. 473-483
    • Cai, W.-J.1    Wang, Y.2    Hodson, R.E.3
  • 10
    • 46549089178 scopus 로고    scopus 로고
    • A comparative overview of weathering intensity and HCO 3 flux in the world's major rivers with emphasis on the Changjiang, Huanghe, Zhujiang (Pearl) and Mississippi Rivers
    • Cai, W.-J., Guo, X., Chen, C. T. A., Dai, M., Zhang, L., Zhai, W., Lohrenz, S. E., Yin, K., Harrison, P. J., and Wang, Y.: A comparative overview of weathering intensity and HCO 3 flux in the world's major rivers with emphasis on the Changjiang, Huanghe, Zhujiang (Pearl) and Mississippi Rivers, Cont. Shelf Res., 28, 1538-1549, 2008.
    • (2008) Cont.Shelf Res. , vol.28 , pp. 1538-1549
    • Cai, W.-J.1    Guo, X.2    Chen, C.T.A.3    Dai, M.4    Zhang, L.5    Zhai, W.6    Lohrenz, S.E.7    Yin, K.8    Harrison, P.J.9    Wang, Y.10
  • 11
    • 0028161575 scopus 로고
    • Carbon dioxide supersaturation in the surface waters of lakes
    • Cole, J. J., Caraco, N., Kling, G.W., and Kratz, T. K.: Carbon dioxide supersaturation in the surface waters of lakes, Science, 265, 1568-1570, 1994.
    • (1994) Science , vol.265 , pp. 1568-1570
    • Cole, J.J.1    Caraco, N.2    Kling, G.W.3    Kratz, T.K.4
  • 14
    • 0024476542 scopus 로고
    • The role of organic acids in the acidification of surface waters in the eastern US
    • Driscoll, C. T., Fuller, R., D., and Schecher, W. D.: The role of organic acids in the acidification of surface waters in the eastern US, Water Air Soil Pollut., 43, 21-40, 1989.
    • (1989) Water Air Soil Pollut. , vol.43 , pp. 21-40
    • Driscoll, C.T.1    Fuller, R.D.2    Schecher, W.D.3
  • 15
    • 0035739934 scopus 로고    scopus 로고
    • Direct and indirect pCO2 measurements in a wide range of pCO2 and salinity values
    • Frankignoulle, M. and Borges, A. V.: Direct and indirect pCO2 measurements in a wide range of pCO2 and salinity values, Aquat. Geochem., 7, 267-273, 2001.
    • (2001) Aquat. Geochem. , vol.7 , pp. 267-273
    • Frankignoulle, M.1    Borges, A.V.2
  • 16
    • 0035137269 scopus 로고    scopus 로고
    • A new design of equilibrator to monitor carbon dioxide in highly dynamic and turbid environments
    • Frankignoulle, M., Borges, A. V., and Biondo, R.: A new design of equilibrator to monitor carbon dioxide in highly dynamic and turbid environments, Water Res., 35, 1344-1347, 2001.
    • (2001) Water Res. , vol.35 , pp. 1344-1347
    • Frankignoulle, M.1    Borges, A.V.2    Biondo, R.3
  • 17
    • 0001490333 scopus 로고
    • Determination of the equivalence point in potentiometric titrations of seawater with hydrochloric acid
    • Gran, G.: Determination of the equivalence point in potentiometric titrations of seawater with hydrochloric acid, Oceanol. Acta, 5, 209-218, 1952.
    • (1952) Oceanol. Acta , vol.5 , pp. 209-218
    • Gran, G.1
  • 19
    • 0040735060 scopus 로고
    • The ionization constant of HCO 3 from 0 to 50-C
    • Harned, H. S. and Scholes, S. R.: The ionization constant of HCO 3 from 0 to 50-C, J. Am. Chem. Soc., 63, 1706-1709, 1941.
    • (1941) J. Am. Chem. Soc. , vol.63 , pp. 1706-1709
    • Harned, H.S.1    Scholes, S.R.2
  • 20
    • 33947440119 scopus 로고
    • The ionization constant of carbonic acid in water and the solubility of carbon dioxide in water and aqueous salt solutions from 0 to 50-C
    • Harned, H. S. and Davis, R. D.: The ionization constant of carbonic acid in water and the solubility of carbon dioxide in water and aqueous salt solutions from 0 to 50-C, J. Am. Chem. Soc., 65, 2030-2037, 1943.
    • (1943) J. Am. Chem. Soc. , vol.65 , pp. 2030-2037
    • Harned, H.S.1    Davis, R.D.2
  • 21
    • 0025500879 scopus 로고
    • Acid neutralizing capacity, alkalinity, and acid-base status of natural waters containing organic acids
    • Hemond, H. F.: Acid neutralizing capacity, alkalinity, and acid-base status of natural waters containing organic acids, Environ. Sci. Technol., 24, 1486-1489, 1990.
    • (1990) Environ. Sci. Technol. , vol.24 , pp. 1486-1489
    • Hemond, H.F.1
  • 22
    • 0029256769 scopus 로고
    • A method for measuring free CO2 in upland streamwater using headspace analysis
    • Hope, D., Dawson, J. J. C., Cresser, M. S., and Billett, M. F.: A method for measuring free CO2 in upland streamwater using headspace analysis, J. Hydrol., 166, 1-14, 1995.
    • (1995) J. Hydrol. , vol.166 , pp. 1-14
    • Hope, D.1    Dawson, J.J.C.2    Cresser, M.S.3    Billett, M.F.4
  • 23
    • 0037660486 scopus 로고    scopus 로고
    • Is a universal model of organic acidity possible: Comparison of the acid/base properties of dissolved organic carbon in the boreal and temperate zones
    • Hruska, J., Köhler, S., Laudon, H., and Bishop, K.: Is a universal model of organic acidity possible: Comparison of the acid/base properties of dissolved organic carbon in the boreal and temperate zones, Environ. Sci. Technol., 37, 1726-1730, 2003.
    • (2003) Environ. Sci. Technol. , vol.37 , pp. 1726-1730
    • Hruska, J.1    Köhler, S.2    Laudon, H.3    Bishop, K.4
  • 24
    • 77749338044 scopus 로고    scopus 로고
    • CO2 supersaturation along the aquatic conduit in Swedish watersheds as constrained by terrestrial respiration, aquatic respiration and weathering
    • Humborg, C., Mörth, C. M., Sundbom, M., Borg, H., Blenckner, T., Giesler, R., and Ittekkot, V.: CO2 supersaturation along the aquatic conduit in Swedish watersheds as constrained by terrestrial respiration, aquatic respiration and weathering, Glob. Change Biol., 16, 1966-1978, 2010.
    • (2010) Glob. Change Biol. , vol.16 , pp. 1966-1978
    • Humborg, C.1    Mörth, C.M.2    Sundbom, M.3    Borg, H.4    Blenckner, T.5    Giesler, R.6    Ittekkot, V.7
  • 25
    • 80455174357 scopus 로고    scopus 로고
    • Contribution of non-carbonate anions to total alkalinity and overestimation of pCO2 in New England and New Brunswick rivers
    • Hunt, C. W., Salisbury, J. E., and Vandemark, D.: Contribution of non-carbonate anions to total alkalinity and overestimation of pCO2 in New England and New Brunswick rivers, Biogeosciences, 8, 3069-3076, 2011, http://www.biogeosciences.net/8/3069/2011/.
    • (2011) Biogeosciences , vol.8 , pp. 3069-3076
    • Hunt, C.W.1    Salisbury, J.E.2    Vandemark, D.3
  • 26
    • 77954650724 scopus 로고    scopus 로고
    • Direct and continuous measurement of dissolved carbon dioxide in freshwater aquatic systems-method and applications
    • Johnson, M. J., Billett, M. F., Dinsmore, K. J., Wallin, M., Dyson, K. E., and Jassal, R. S.: Direct and continuous measurement of dissolved carbon dioxide in freshwater aquatic systems-method and applications, Ecohydrol., 3, 68-78, 2010.
    • (2010) Ecohydrol. , vol.3 , pp. 68-78
    • Johnson, M.J.1    Billett, M.F.2    Dinsmore, K.J.3    Wallin, M.4    Dyson, K.E.5    Jassal, R.S.6
  • 27
    • 0009556892 scopus 로고
    • A computer program for hydrochemical problems in karstic water
    • Kempe, S.: A computer program for hydrochemical problems in karstic water. Annales de Spéleólogie 30, 699-702, 1975.
    • (1975) Annales de Spéleólogie , vol.30 , pp. 699-702
    • Kempe, S.1
  • 28
    • 0021573149 scopus 로고
    • Sinks of the anthropogenically enhanced carbon cycle in surface freshwaters
    • Kempe, S.: Sinks of the anthropogenically enhanced carbon cycle in surface freshwaters, J. Geophys. Res., 89, 4657-4676, 1984.
    • (1984) J. Geophys. Res. , vol.89 , pp. 4657-4676
    • Kempe, S.1
  • 29
  • 30
    • 33846633333 scopus 로고
    • Flux of gases across the air-sea interface
    • Liss, P. S. and Slater P. G,: Flux of gases across the air-sea interface. Nature, 233, 327-329, 1974.
    • (1974) Nature , vol.233 , pp. 327-329
    • Liss, P.S.1    Slater, P.G.2
  • 31
    • 84893232044 scopus 로고    scopus 로고
    • Dynamic seasonal nitrogen cycling in response to anthropogenic N loading in a tropical catchment, Athi-Galana-Sabaki River, Kenya
    • Marwick, T. R., Tamooh, F., Ogwoka, B., Teodoru, C., Borges, A. V., Darchambeau, F., and Bouillon S.: Dynamic seasonal nitrogen cycling in response to anthropogenic N loading in a tropical catchment, Athi-Galana-Sabaki River, Kenya, Biogeosciences, 11, 1-18, doi:10.5194/bg-11-1-2014, 2014a
    • (2014) Biogeosciences , vol.11 , pp. 1-18
    • Marwick, T.R.1    Tamooh, F.2    Ogwoka, B.3    Teodoru, C.4    Borges, A.V.5    Darchambeau, F.6    Bouillon, S.7
  • 32
    • 84906068556 scopus 로고    scopus 로고
    • Disproportionate contribution of riparian inputs to organic carbon pools in freshwater systems
    • Marwick, T. R., Borges A. V., Van Acker K., Darchambeau F., and Bouillon S.: Disproportionate contribution of riparian inputs to organic carbon pools in freshwater systems, Ecosystems, 17, 974-989, 2014b.
    • (2014) Ecosystems , vol.17 , pp. 974-989
    • Marwick, T.R.1    Borges, A.V.2    Van Acker, K.3    Darchambeau, F.4    Bouillon, S.5
  • 33
    • 0023524637 scopus 로고
    • Global chemical weathering of surficial rocks estimated from river dissolved loads
    • Meybeck, M.: Global chemical weathering of surficial rocks estimated from river dissolved loads, American J. Science, 287, 401-428, 1987.
    • (1987) American J. Science , vol.287 , pp. 401-428
    • Meybeck, M.1
  • 34
    • 33746004836 scopus 로고
    • The thermodynamics of the carbonic acid system in seawater
    • Millero, F. J.: The thermodynamics of the carbonic acid system in seawater, Geochim. Cosmochim. Ac., 43, 1651-1661, 1979.
    • (1979) Geochim. Cosmochim. Ac. , vol.43 , pp. 1651-1661
    • Millero, F.J.1
  • 35
    • 18844477982 scopus 로고    scopus 로고
    • An assessment of excess carbon dioxide partial pressures in natural waters based on pH and alkalinity measurements, Sc
    • Neal, C., House, W. A., and Down, K.: An assessment of excess carbon dioxide partial pressures in natural waters based on pH and alkalinity measurements, Sc. Total Envir., 210/211, 173-185, 1998.
    • (1998) Total Envir. , vol.210-211 , pp. 173-185
    • Neal, C.1    House, W.A.2    Down, K.3
  • 36
    • 84944815722 scopus 로고
    • Oceanic CO2 system: An evaluation of ten methods of investigation
    • Park, P. K.: Oceanic CO2 system: An evaluation of ten methods of investigation, Limnol. Oceanogr., 14, 179-186, 1969.
    • (1969) Limnol. Oceanogr. , vol.14 , pp. 179-186
    • Park, P.K.1
  • 37
    • 0003396170 scopus 로고    scopus 로고
    • User's guide to PHREEQC (version 2)-A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
    • Parkhurst, D. L. and Appelo, C. A. J.: User's guide to PHREEQC (version 2)-A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations: US Geol. Surv.Water-Resour. Investigat. Report, 99-4259, 312 pp., 1999.
    • (1999) US Geol. Surv.Water-Resour. Investigat. Report 99-4259
    • Parkhurst, D.L.1    Appelo, C.A.J.2
  • 38
    • 84875388448 scopus 로고    scopus 로고
    • Export and degassing of terrestrial carbon through watercourses draining a temperate podsolised catchment
    • Polsenaere, P., Savoye, N., Etcheber, H., Canton, M., Poirier, D., Bouillon, S., and Abril ,G.: Export and degassing of terrestrial carbon through watercourses draining a temperate podsolised catchment, Aquatic Sciences, 75, 299-319, 2013.
    • (2013) Aquatic Sciences , vol.75 , pp. 299-319
    • Polsenaere, P.1    Savoye, N.2    Etcheber, H.3    Canton, M.4    Poirier, D.5    Bouillon, S.6    Abril, G.7
  • 39
    • 0030616495 scopus 로고    scopus 로고
    • Carbon dioxide concentration and atmospheric flux in the Hudson River
    • Raymond, P. A., Caraco, N. F., and Cole J. J.: Carbon dioxide concentration and atmospheric flux in the Hudson River, Estuaries, 20, 381-390, 1997.
    • (1997) Estuaries , vol.20 , pp. 381-390
    • Raymond, P.A.1    Caraco, N.F.2    Cole, J.J.3
  • 41
    • 27644499263 scopus 로고    scopus 로고
    • Temperature independence of carbon dioxide supersaturation in global lakes
    • Sobek, S., Tranvik L. J., and Cole, J. J.: Temperature independence of carbon dioxide supersaturation in global lakes, Global Biogeochem. Cy., 19, GB2003, doi:10.1029/2004GB002264, 2005.
    • (2005) Global Biogeochem. Cy. , vol.19 , pp. GB2003
    • Sobek, S.1    Tranvik, L.J.2    Cole, J.J.3
  • 43
  • 44
    • 70349237545 scopus 로고    scopus 로고
    • Patterns in pCO2 in boreal streams and rivers of northern Quebec, Canada
    • Teodoru, C. R., del Giorgio P. A., Prairie Y. T., and Camire M., Patterns in pCO2 in boreal streams and rivers of northern Quebec, Canada, Global Biogeochem. Cy., 23, GB2012, doi:10.1029/2008GB003404, 2009.
    • (2009) Global Biogeochem. Cy. , vol.23 , pp. GB2012
    • Teodoru, C.R.1    Del Giorgio, P.A.2    Prairie, Y.T.3    Camire, M.4
  • 45
    • 84920734041 scopus 로고    scopus 로고
    • Spatial variability and temporal dynamics of greenhouse gas (CO2, CH4, N2O) concentrations and fluxes along the Zambezi River mainstem and major tributaries
    • Teodoru, C. R., Nyoni, F. C., Borges, A. V., Darchambeau, F., Nyambe, I., and Bouillon, S.: Spatial variability and temporal dynamics of greenhouse gas (CO2, CH4, N2O) concentrations and fluxes along the Zambezi River mainstem and major tributaries, Biogeosciences Discuss., 11, 16391-16445, doi:10.5194/bgd-11-16391-2014, 2014.
    • (2014) Biogeosciences Discuss. , vol.11 , pp. 16391-16445
    • Teodoru, C.R.1    Nyoni, F.C.2    Borges, A.V.3    Darchambeau, F.4    Nyambe, I.5    Bouillon, S.6
  • 46
    • 0028183516 scopus 로고
    • Limnological Features of Lakes on the Sepik-Ramu Floodplain, Papua New Guinea Aust, J
    • Vyverman,W.: Limnological Features of Lakes on the Sepik-Ramu Floodplain, Papua New Guinea Aust, J. Mar. Freshwater Res., 45, 1209-1224, 1994.
    • (1994) Mar. Freshwater Res. , vol.45 , pp. 1209-1224
    • Vyvermanw1
  • 47
    • 84898637394 scopus 로고    scopus 로고
    • Representative regional sampling of carbon dioxide and methane concentrations in hemiboreal headwater streams reveal underestimates in less systematic approaches
    • Wallin, M. B., Löfgren, S., Erlandsson, M., and Bishop, K.: Representative regional sampling of carbon dioxide and methane concentrations in hemiboreal headwater streams reveal underestimates in less systematic approaches, Glob. Biogeochem. Cy., 28, 465-479, 2014.
    • (2014) Glob. Biogeochem. Cy. , vol.28 , pp. 465-479
    • Wallin, M.B.1    Löfgren, S.2    Erlandsson, M.3    Bishop, K.4
  • 49
    • 35348989790 scopus 로고
    • Carbon dioxide in water and seawater: The solubility of a non-ideal gas
    • Weiss, R. F.: Carbon dioxide in water and seawater: the solubility of a non-ideal gas, Mar. Chem., 2, 203-215, 1974.
    • (1974) Mar. Chem. , vol.2 , pp. 203-215
    • Weiss, R.F.1
  • 50
    • 0019690831 scopus 로고
    • Determinations of carbon dioxide and methane by dual catalyst flame ionization chromatography and nitrous oxide by electron capture chromatography
    • Weiss, R. F.: Determinations of carbon dioxide and methane by dual catalyst flame ionization chromatography and nitrous oxide by electron capture chromatography, J. Chromatogr. Sci., 19, 611-616, 1981.
    • (1981) J. Chromatogr. Sci. , vol.19 , pp. 611-616
    • Weiss, R.F.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.