Carbon monoxide bonding with Beo and BeCo3: Surprisingly high co stretching frequency of OCBeCO

Angewandte Chemie - International Edition

Volumn 54, Issue 1, 2015, Pages 124-128

  Chen, Mohua ^a   Zhang, Qingnan ^a   Zhou, Mingfei ^a   Andrada, Diego M ^a,b   Frenking, Gernot ^a,b  

^a FUDAN UNIVERSITY   (China)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

Beryllium carbonate; Bonding analysis; Carbonyl complexes; Donor acceptor interactions; Matrix isolation

Indexed keywords

CARBON MONOXIDE; ISOMERS; PLANTS (BOTANY); TEMPERATURE;

BERYLLIUM CARBONATE; BONDING ANALYSIS; CARBONYL COMPLEXES; DONOR-ACCEPTOR INTERACTION; MATRIX ISOLATION;

MATRIX ALGEBRA;

EID: 84920074004     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201406264     Document Type: Article

References (34)

1. Recent Reviews: M. F. Zhou, L. Andrews, C.W. Bauschlicher, Jr., Chem. Rev. 2001, 101, 1931
2. b) H. J. Himmel, A. J. Downs, T. M. Greene, Chem. Rev. 2002, 102, 4191
3. c) M. E. Jacox, Chem. Soc. Rev. 2002, 31, 108
4. d) G. J. Wang, M. F. Zhou, Int. Rev. Phys. Chem. 2008, 27, 1
5. e) Y. Gong, M. F. Zhou, L. Andrews, Chem. Rev. 2009, 109, 6765
6. f) L. Khriachtchev, M. Räsänen, R. B. Gerber, Acc. Chem. Res. 2009, 42, 183.
7. L. Khriachtchev, M. Pettersson, N. Runeberg, J. Lundell, J. M. Räsänen, Nature 2000, 406, 874.
8. a)W. Koch, J. R. Collins, G. Frenking, Chem. Phys. Lett. 1986, 132, 330
9. b) G. Frenking, W. Koch, J. Gauss, D. Cremer, J. Am. Chem. Soc. 1988, 110, 8007
10. c) G. Frenking, W. Koch, F. Reichel, D. Cremer, J. Am. Chem. Soc. 1990, 112, 4240
11. d) A. Veldkamp, G. Frenking, Chem. Phys. Lett. 1994, 226, 11.
12. G. Frenking, W. Koch, J. R. Collins, J. Chem. Soc. Chem. Commun. 1988, 1147.
13. a) C. A. Thompson, L. Andrews, J. Am. Chem. Soc. 1994, 116, 423
14. b) L. Andrews, T. J. Tague, J. Am. Chem. Soc. 1994, 116, 6856.
15. a) S. H. Strauss, Chemtracts: Inorg. Chem. 1997, 10, 77
16. b) A. J. Lupinetti, G. Frenking, S. H. Strauss, Angew. Chem. Int. Ed. 1998, 37, 2113
17. A. J.Lupinetti, G.Frenking, S. H.Strauss Angew. Chem. 1998, 110, 2229
18. A. J. Lupinetti, S. H. Strauss, G. Frenking, Prog. Inorg. Chem. 2001, 49, 1.
19. a) R. K. Szilagyi, G. Frenking, Organometallics 1997, 16, 4807
20. A. J. Lupinetti, V. Jonas, W. Thiel, S. H. Strauss, G. Frenking, Chem. Eur. J. 1999, 5, 2573
21. A. Diefenbach, F. M. Bickelhaupt, G. Frenking, J. Am. Chem. Soc. 2000, 122, 6449.
22. T. A. Albright, J. K. Burdett, M. H. Whangbo, Orbital Interactions in Chemistry,Wiley, New York, 1985, p. 82. Interestingly, the statement about the antibonding character of the HOMO of CO is not made in the second edition:
23. nd ed., Wiley, New York, 2013
24. b) U. Radius, F. M. Bickelhaupt, A.W. Ehlers, N. Goldberg, R. Hoffmann, Inorg. Chem. 1998, 37, 1080.
25. For a discussion of the bonding situation in CO, see:G. Frenking, C. Loschen, A. Krapp, S. Fau, S. H. Strauss, J. Comput. Chem. 2007, 28, 117.
26. a) A. J. Lupinetti, S. Fau, G. Frenking, S. H. Strauss, J. Phys. Chem. A 1997, 101, 9551
27. b) A. S. Goldman, K. Krogh-Jespersen, J. Am. Chem. Soc. 1996, 118, 12159.
28. Slightly higher C-O stretching mode values have been reported for positively charged carbonyl complexes: a) H. Willner, F. Aubke, Chem. Eur. J. 2003, 9, 1668
29. b) J. Schaefer, A. Kraft, S. Reininger, G. Santiso-Quinones, D. Himmel, N. Trapp, U. Gellrich, B. Breit, I. Krossing, Chem. Eur. J. 2013, 19, 12468.
30. A. Terheiden, E. Bernhardt, H. Willner, F. Aubke, Angew. Chem. Int. Ed. 2002, 41, 799;
31. a) A. Terheiden, E. Bernhardt, H. Willner, F. Aubke Angew. Chem. Int. Ed. 2002, 41, 799; Angew. Chem. 2002, 114, 823
32. b) M. Finze, E. Bernhardt, A. Terheiden, M. Berkei, H. Willner, D. Christen, H. Oberhammer, F. Aubke, J. Am. Chem. Soc. 2002, 124, 15385.
33. W. E. Thompson, M. E. Jacox, J. Chem. Phys. 1999, 111, 4487.
34. [7a], but the s donation is clearly stronger than the p backdonation: see Ref. [7c].