Pyro-synthesis of a high rate nano-Li3V2(PO4)3/C cathode with mixed morphology for advanced Li-ion batteries

Scientific Reports

Volumn 4, Issue , 2015, Pages

  Kang, Jungwon ^a   Mathew, Vinod ^a   Gim, Jihyeon ^a   Kim, Sungjin ^a   Song, Jinju ^a   Im, Won Bin ^a   Han, Junhee ^b   Lee, Jeong Yong ^b,c   Kim, Jaekook ^a  

^a Chonnam National University   (South Korea)

^b Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^c Institute for Basic Science   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84919731886     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep04047     Document Type: Article

References (40)

1. Whittingham, M. S. Lithium batteries and cathode materials. Chem. Rev. 104, 4271-4302 (2004).
2. Padhi, A. K., Nanjundaswamy, K. S. & Goodenough, J. B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J. Electrochem. Soc. 144, 1188-1194 (1997).
3. 4 nanoparticles embedded in a nanoporous carbon matrix: Superior cathode material for electrochemical energy-storage devices. Adv. Mater. 21, 2710-2714 (2009).
4. 4 as the cathode for lithium batteries. Electrochem. Solid State Lett. 5, A135-A137 (2002).
5. 3/Carbon cathode for rechargeable lithium batteries. Adv. Mater. 14, 1525-1528 (2002).
6. 4 for lithium secondary batteries. J. Power Sources 97-98, 430-432 (2004).
7. Padhi, A. K., Nanjundaswamy, K. S., Masquelier, C., Okada, S. & Goodenough, J. B. Effect of structure on the Fe31/Fe21 redox couple in iron phosphates. J. Electrochem. Soc. 144, 1609-1613 (1997).
8. Nagaura, T. & Tozawa, K. Lithium ion rechargeable battery. Prog. Batteries Sol. Cells 9, 209-217 (1990).
9. 6 and LiBoB EC/ DEC electrolytes. Electrochem. Commun. 6, 39-43 (2004).
10. Chang, C. et al. Hydrothermal synthesis of carbon-coated lithium vanadium phosphate. Electrochim. Acta 54, 623-627 (2008).
11. 3/graphene nanocomposites as cathodematerial for lithium ion batteries. Chem. Commun. 47, 9110-9112 (2011).
12. Ren, M. M., Zhou, Z., Gao, X. P., Peng, W. X. & Wei, J. P. Core2shell Li3V2(PO4)3@C composites as cathode materials for lithium-ion batteries. J. Phys. Chem. C 112, 5689-5693 (2008).
13. Wang, C., Liu,H. & Yang, W. An integrated core-shell structured Li3V2(PO4)3@ C cathode material of LIBs prepared by a momentary freeze-drying method. J. Mater. Chem. 22, 5281-5285 (2012).
14. 4 nanoparticles in polyol medium and their electrochemical properties. Electrochem. Solid-State Lett. 9, A439-A442 (2006).
15. 3/carbon composite for high-rate lithium-ion batteries. Eletrochem. Commun. 12, 1674-1677 (2010).
16. 3 cathode materials by a low temperature solid-state reaction. J. Power Sources 195, 2844-2850 (2010).
17. 3/C cathode materials. Electrochim. Acta 56, 4139-4145 (2011).
18. 3 with high performance by optimized solid-state synthesis routine. J. Power Sources 162, 651-657 (2006).
19. 3/carbon. Electrochim.Acta 53, 474-479 (2007).
20. 3. J. Power Sources 119-121, 278-284 (2003).
21. 3/C positive material by one-step solid-state reaction. Electrochim. Acta 54, 2253-2258 (2009).
22. 3/C cathode prepared by pyro-synthesis for sodium-ion batteries. J. Mater. Chem. 22, 20857-20860 (2012).
23. 3/C thin film with high rate capability as a cathode material for lithium-ion batteries. Eletrochem. Commun. 12, 52-55 (2010).
24. Gim, J. et al. Pyro-synthesis of functional nanocrystals. Sci Rep. 2, 946 (2012).
25. Gao, C., Liu, H., Liu, G., Zhang, J. & Wang, W. High-rate performance of xLiFePO4·yLi3V2(PO4)3/C composite cathode materials. Mater. Sci. Eng. B 178, 272-276 (2013).
26. 3/C cathode for lithium-ion batteries. Mater. Res. Bull. 47, 4300-4304 (2012).
27. 7 compounds for rechargeable lithium batteries. ECS Trans. 50, 79-88 (2013).
28. Laoutid, F., Bonnaud, L., Alexandre, M., Lopez-Cuesta, J. M. & Dubois, Ph. New prospects in flame retardant polymer materials: From fundamentals to nanocomposites. Mat. Sci. Eng. R 63, 100-125 (2009).
29. 3. J. Am. Chem. Soc. 125, 10402-10411 (2003).
30. 3/graphene as cathode materials for lithium ion batteries. J. Mater. Chem. 22, 11039-11047 (2012).
31. 3 with enhanced Capacity. J. Phys. Chem. B 112, 11250-11257 (2008).
32. 3 as cathode materials for lithium batteries. J. Power Sources 195, 5374-5378 (2010).
33. Barker, J., Saidi, M. Y. & Swoyer, J. L. A carbothermal reduction method for the preparation of electroactive materials for lithium ion applications. J. Electrochem. Soc. 150, A684-A688 (2003).
34. 3/C synthesized in similar soft chemical route. J. Solid State Electrochem. 17, 1-8 (2013).
35. 4 nanoparticles in polyol medium. J.Electrochem. Soc. 158, A736-A740 (2011).
36. 3/C composites with high-rate capability prepared by a maltose-based sol-gel route. Electrochim. Acta. 55, 6761-6767 (2010).
37. 3/C-based composites for lithiumion batteries. ACS Appl. Mater. Interfaces 3, 3772-3776 (2011).
38. 3 using synchrotron based in situ X-ray diffraction and absorption. J. Alloys Cds. 569, 76-81 (2013).
39. 3 nanorods as cathode material for lithium-ion batteries. Electrochim.Acta 55, 8461-8465 (2010).
40. Larson, A. C. & Von Dreele, R. B. General Structure Analysis System (GSAS). Los Alamos National Laboratory Report LAUR 86-748 (1994), http://www.ccp14.ac. uk/solution/gsas/ (accessed on 15/01/2014).