Carbon-nanotube-encapsulated FeF2 nanorods for high-performance lithium-ion cathode materials

ACS Applied Materials and Interfaces

Volumn 6, Issue 23, 2014, Pages 21223-21229

  Zhou, Jisheng ^a   Zhang, Di ^a   Zhang, Xiaoting ^a   Song, Huaihe ^a   Chen, Xiaohong ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

carbon nanotube; cathode; co pyrolysis; encapsulation; iron fluoride; lithium ion batteries

Indexed keywords

CARBON BLACK; CARBON NANOTUBES; CATHODE MATERIALS; CATHODES; ENCAPSULATION; FLUORINE COMPOUNDS; IONS; IRON COMPOUNDS; NANORODS; ORGANOMETALLICS; PYROLYSIS; SULFUR COMPOUNDS;

CONDUCTIVE CARBON BLACKS; COPYROLYSIS; CORE/SHELL STRUCTURE; ELECTROCHEMICAL PERFORMANCE; ELECTRONIC CONDUCTIVITY; IRON FLUORIDES; LITHIUM ION STORAGES; ONE-DIMENSIONAL MORPHOLOGIES;

LITHIUM-ION BATTERIES;

EID: 84917706044     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am506236n     Document Type: Article

References (34)

1. 3:C J. Electrochem. Soc. 2003, 150, A1209-A1218
2. Badway, F.; Cosandy, F.; Pereira, N.; Amatucci, G. G. Carbon Metal Fluoride Nanocomposites High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries J. Electrochem. Soc. 2003, 150, A1318-A1327
3. Plitz, I.; Badway, F.; Al-Sharab, J.; DuPasquier, A.; Cosandey, F.; Amatucci, G. G. Structure and Electrochemistry of Carbon-Metal Fluoride Nanocomposites Fabricated by Solid-State Redox Conversion Reaction J. Electrochem. Soc. 2005, 152, A307-A315
4. Wang, F.; Robert, R.; Chernova, N. A.; Pereira, N.; Omenya, F.; Badway, F.; Hua, X.; Ruotolo, M.; Zhang, R.; Wu, L.; Volkov, V.; Su, D.; Key, B.; Whittingham, M. S.; Grey, C. P.; Amatucci, G. G.; Zhu, Y.; Graetz, J. Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes J. Am. Chem. Soc. 2011, 133, 18828-18836
5. Li, C.; Gu, L.; Tsukimoto, S.; Tsukimoto, S.; Aken, P. A.; Maier, J. Low-Temperature Ionic-Liquid-Based Synthesis of Nanostructured Iron-Based Fluoride Cathodes for Lithium Batteries Adv. Mater. 2010, 22, 3650-3654
6. Li, C.; Gu, L.; Tong, J.; Tsukimoto, S.; Maier, J. A Mesoporous Iron-Based Fluoride Cathode of Tunnel Structure for Rechargeable Lithium Batteries Adv. Funct. Mater. 2011, 21, 1391-1397
7. 3 Nanoflowers on CNT Branches and Their Application to High Power Lithium Rechargeable Batteries Adv. Mater. 2010, 22, 5260-5264
8. 3/Ordered Mesoporous Carbon (OMC) Nanocomposites for Lithium Ion Batteries with Enhanced Electrochemical Performance J. Phys. Chem. C 2013, 117, 14939-14946
9. Zhao, X.; Hayner, C. M.; Kung, J. C.; Kung, H. H. Photothermal-Assisted Fabrication of Iron Fluoride-Graphene Composite Paper Cathodes for High-Energy Lithium-Ion Batteries Chem. Commun. 2012, 48, 9909-9911
10. 3 Nanoparticles: Facile Synthesis and Application as a High Capacity Cathode Material for Rechargeable Lithium Batteries Electrochim. Acta 2013, 111, 80-85
11. 2 Nanocomposites for Reversible Lithium Storage Adv. Energy Mater. 2013, 3, 308-313
12. Prakash, R.; Mishra, A. K.; Roth, A.; Kübel, C.; Scherer, T.; Ghafari, M.; Hahn, H.; Fichtner, M. A Ferrocene-Based Carbon-Iron Lithium Fluoride Nanocomposite as a Stable Electrode Material in Lithium Batteries J. Mater. Chem. 2010, 20, 1871-1876
13. Zhou, J.; Song, H.; Chen, X.; Zhi, L.; Yang, S.; Huo, J.; Yang, W. Carbon-Encapsulated Metal Oxide Hollow Nanoparticles and Metal Oxide Hollow Nanoparticles: A General Synthesis Strategy and Its Application to Lithium-Ion Batteries Chem. Mater. 2009, 21, 2935-2940
14. Zhou, J.; Song, H.; Chen, X.; Huo, J. Diffusion of Metal in a Confined Nanospace of Carbon Nanotubes Induced by Air Oxidation J. Am. Chem. Soc. 2010, 132, 11402
15. 4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries Adv. Funct. Mater. 2008, 18, 3941-3946
16. Wu, P.; Du, N.; Zhang, H.; Yu, J.; Yang, D. Carbon Nanocapsules as Nanoreactors for Controllable Synthesis of Encapsulated Iron and Iron Oxide: Magnetic Properties and Reversible Lithium Storage J. Phys. Chem. C 2011, 115, 3612-3620
17. 3 Nanoparticles-Filled Carbon Nanotubes Chem. Commun. 2010, 46, 8576-8578
18. 2 Microboxes via Selective Leaching for Highly Reversible Lithium Storage Energy Environ. Sci. 2014, 7, 1013-1017
19. 3 Nanorods for Highly Reversible Lithium Storage Small 2014, 10, 1741-1745
20. Ni, J.; Gao, L.; Lu, L. Carbon Coated Lithium Cobalt Phosphate for Li-Ion Batteries: Comparison of Three Coating Techniques J. Power Sources 2013, 221, 35-41
21. 4 Cathode Materials for Lithium-Ion Batteries Energy Environ. Sci. 2012, 5, 5163-5185
22. 3 Nanowires Chem. Mater. 2007, 19, 3364-3366
23. 2-Carbon Core-Shell Composite and Its Application in Lithium Ion Batteries J. Alloys Compd. 2014, 606, 226-230
24. Huo, J.; Song, H.; Chen, X. Preparation of Carbon-Encapsulated Iron Nanoparticles by Co-carbonization of Aromatic Heavy Oil and Ferrocene Carbon 2004, 42, 3177-3182
25. Huo, J.; Song, H.; Chen, X.; Lian, W. Formation and Transformation of Carbon-Encapsulated Iron Carbide/Iron Nanorods Carbon 2006, 44, 2849-2852
26. Wu, B.; Song, H.; Zhou, J.; Chen, X. Formation Mechanism of Carbon-Encapsulated Iron Nanorods in a Co-carbonization Process Carbon 2011, 49, 890-894
27. Song, H.; Chen, X. Large-Scale Synthesis of Carbon-Encapsulated Iron Carbide Nanoparticles by Co-carbonization of Durene with Ferrocene Chem. Phys. Lett. 2003, 374, 400-404
28. Zhou, J.; Song, H.; Fu, B.; Wu, B.; Chen, X. Synthesis and High-Rate Capability of Quadrangular Carbon Nanotubes with One Open End as Anode Materials for Lithium-Ion Batteries J. Mater. Chem. 2010, 20, 2794-2800
29. Wu, B.; Song, H.; Zhou, J.; Chen, X. Iron Sulfide-Embedded Carbon Microsphere Anode Material with High-Rate Performance for Lithium-Ion Batteries Chem. Commun. 2011, 47, 8653-8655
30. 4 Core/Shell Composites Mater. Sci. Eng., B 2010, 170, 51-57
31. Wang, S.; Huang, X.; He, Y.; Huang, H.; Wu, Y.; Hou, L.; Liu, X.; Yang, T.; Zou, J.; Huang, B. Synthesis, Growth Mechanism, and Thermal Stability of Copper Nanoparticles Encapsulated by Multi-Layer Graphene Carbon 2012, 50, 2119-2125
32. Lee, S.; Hong, J.; Koo, J. H.; Lee, H.; Lee, S.; Choi, T.; Jung, H.; Koo, B.; Park, J.; Kim, H.; Kim, Y.-W.; Lee, T. Synthesis of Few-Layered Graphene Nanoballs with Copper Cores Using Solid Carbon Source ACS Appl. Mater. Interfaces 2013, 5, 2432-2437
33. Yamakawa, N.; Jiang, M.; Key, B.; Grey, C. P. Identifying the Local Structures Formed during Lithiation of the Conversion Material, Iron Fluoride, in a Li-Ion Battery: A Solid-State NMR, X-ray Diffraction, and Pair Distribution Function Analysis Study J. Am. Soc. Chem. 2009, 131, 10525-10536
34. Li, L.; Meng, F.; Jin, S. High-Capacity Lithium-Ion Battery Conversion Cathodes Based on Iron Fluoride Nanowires and Insights into the Conversion Mechanism Nano Lett. 2012, 12, 6030-6037