Fast estimation of the equilibrium adsorption constants of ionic surfactants with account for ion-specific effects

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 467, Issue , 2015, Pages 143-148

  Karakashev, Stoyan I ^a   Smoukov, Stoyan K ^b  

^a UNIVERSITY OF SOFIA   (Bulgaria)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

Adsorption capacity; Adsorption layers; Ion specific effects; Ionic surfactants

Indexed keywords

ADSORPTION; COST BENEFIT ANALYSIS; COST EFFECTIVENESS; EMULSIFICATION; EQUILIBRIUM CONSTANTS; FLOTATION; INDUSTRIAL RESEARCH; IONS; MINERAL INDUSTRY;

ACCURATE ESTIMATION; ADSORPTION CAPACITIES; ADSORPTION CONSTANT; ADSORPTION LAYER; EQUILIBRIUM ADSORPTION CONSTANT; IONIC SURFACTANTS; QUANTITATIVE SCREENING; SPECIFIC EFFECTS;

SURFACE ACTIVE AGENTS;

5,5 DIMETHYL 1 PYRROLINE 1 OXIDE; AMMONIA; ANION; CARBOXYLIC ACID; CATION; COUNTERION; DIETHYL DECYL PHOSPHINE OXIDE; IONIC SURFACTANT; MINERAL; OXIDE; SULFATE; SURFACE WATER; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; CALCULATION; CHEMICAL STRUCTURE; COST BENEFIT ANALYSIS; EMULSION; ENERGY TRANSFER; EQUILIBRIUM ADSORPTION CONSTANT; HYDROPHILICITY; INDUSTRY AND INDUSTRIAL PHENOMENA; OIL INDUSTRY; QUANTITATIVE ANALYSIS; TENSION;

EID: 84916620054     PISSN: 09277757     EISSN: 18734359     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2014.11.016     Document Type: Article

References (24)

1. Kralchevsky P.A., Danov K.D., Denkov N.D. Chemical physics of colloid systems and interfaces. Handbook of Surface and Colloid Chemistry 2008, 179-379. CRC Press, Boca Raton. K.S. Birdi (Ed.).
2. Karakashev S.I., Nguyen A.V., Miller J.D. Equilibrium adsorption of surfactants at the gas-liquid interface. In: Interfacial processes molecular aggregation of surfactants. Adv. Polym. Sci. 2008, 218:25-55.
3. Fainerman V.B. Equation of state of a nonideal mixed surface layer and adsorption isotherms at the solution-air surface. Zhur. Fizich. Khim. 1986, 60:681-685.
4. Fainerman V.B., Lucassen-Reynders E.H. Adsorption of single and mixed ionic surfactants at fluid interfaces. Adv. Colloid Interface Sci. 2002, 96:295-323.
5. Fainerman V.B., Möbius D., Miller R. Surfactant chemistry, interfacial properties, applications. Studies in Interface Science 2001, Elsevier, Amsterdam. R. Miller, D. Möbius (Eds.).
6. Karakashev S., Manev E., Nguyen A. Interpretation of negative values of the interaction parameter in the adsorption equation through the effects of surface layer heterogeneity. Adv. Colloid Interface Sci. 2004, 112:31-36.
7. Manev E.D., Sazdanova S.V., Tsekov R., Karakashev S.I., Nguyen A.V. Adsorption of ionic surfactants. Colloids Surf. A 2008, 319:29-33.
8. Ivanov I.B., Ananthapadmanabhan K.P., Lips A. Adsorption and structure of the adsorbed layer of ionic surfactants. Adv. Colloid Interface Sci. 2006, 123-126:189-212.
9. Ivanov I.B., Danov K.D., Dimitrova D., Boyanov M., Ananthapadmanabhan K.P., Lips A. Equations of state and adsorption isotherms of low molecular non-ionic surfactants. Colloids Surf. A 2010, 354:118-133.
10. Helfand E., Frisch H., Lebowitz J. Theory of the two and one-dimensional sphere fluids. J. Chem. Phys. 1961, 34:1037-1042.
11. Baxter R.J. Percus-Yevick equation for hard spheres with surface adhesion. J. Chem. Phys. 1969, 49:2770-2774.
12. Karakashev S., Tsekov R., Manev E. Adsorption of alkali dodecyl sulfates on air/water surface. Langmuir 2001, 17:5403-5405.
13. Slavchov R.I., Karakashev S.I., Ivanov I.B. Ionic surfactants and ion-specific effects: adsorption, micellization, thin liquid films. Surfactant Science and Technology: Retrospects and Prospects 2014, 593. Taylor & Francis Group, Boca Raton. L.S. Romsted (Ed.).
14. Karakashev S.I. How to determine the adsorption energy of the surfactant's hydrophilic head? How to estimate easily the surface activity of every simple surfactant?. J. Colloid Interface Sci. 2014, 432:98-104.
15. Robinson R.A., Stokes R.H. Electrolyte Solutions 1959, Butterworth & Co. Ltd, Devon. 2nd ed.
16. Lyklema J. Fundamentals of Interface and Colloid Science 1995, Academic Press, London.
17. Ivanov I.B., Marinova K.G., Danov K.D., Dimitrova D., Ananthapadmanabhan K.P., Lips A. Role of the counterions on the adsorption of ionic surfactants. Adv. Colloid Interface Sci. 2007, 134-135:105-124.
18. Fainerman V.B., Miller R., Mohwald H. General relationships of the adsorption behavior of surfactants at the water/air interface. J. Phys. Chem. B 2002, 106:809-819.
19. Lunkenheimer K., Czichocki G., Hirte R., Barzyk W. Novel results on the adsorption of ionic surfactants at the air/water interface - sodium-N-alkyl sulfates. Colloids Surf. A 1995, 101:187-197.
20. Medrzycka K., Zwierzykowski W. Adsorption of alkyltrimethylammonium bromides at the various interfaces. J. Colloid Interface Sci. 2000, 230:67-72.
21. Vandenbogaert R., Joos P. Diffusion-controlled adsorption-kinetics for a mixture of surface-active agents at the solution-air interface. J. Phys. Chem. 1980, 84:190-194.
22. Makievski A.V., Grigoriev D.O. Adsorption of alkyl dimethyl phosphine oxides at the solution/air interface. Colloids Surf. A 1998, 143:233-242.
23. Blunk D., Tessendorf R., Buchavzov N., Strey R., Stubenrauch C. Purification, surface tensions, and miscibility gaps of alkyldimethyl and alkyldiethylphosphine oxides. J. Surfact. Deterg. 2007, 10:155-165.
24. Hayami Y., Wataya A., Takiue T., Ikeda N., Matsubara H., Aratono M. Adsorption and micelle formation of alkylammonium chloride-alkyltrimethylammonium chloride mixtures. J. Colloid Interface Sci. 2007, 310:240-245.