Simultaneous determination of three Flory-Huggins interaction parameters in polymer/solvent/nonsolvent systems by viscosity and cloud point measurements

Polymer

Volumn 55, Issue 26, 2014, Pages 6795-6802

  Xu, Li ^a   Qiu, Feng ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

Interaction parameter; Intrinsic viscosity; Thermodynamics

Indexed keywords

FREE ENERGY; TERNARY SYSTEMS; THERMODYNAMICS; VISCOSITY;

BINODAL CURVES; CLOUD POINT MEASUREMENTS; COMPLEX EQUIPMENT; FLORY-HUGGINS FREE ENERGIES; FLORY-HUGGINS INTERACTION PARAMETER; INTERACTION PARAMETERS; INTRINSIC VISCOSITY; SIMULTANEOUS DETERMINATIONS;

PARAMETER ESTIMATION;

EID: 84914154698     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2014.10.045     Document Type: Article

References (41)

1. J.A. Gonzalez-Leon, and A.M. Mayes Phase behavior prediction of ternary polymer mixtures Macromolecules 36 7 2003 2508 2515
2. P. van de Witte, P.J. Dijkstra, J.W.A. van den Berg, and J. Feijen Phase separation processes in polymer solutions in relation to membrane formation J Membr Sci 117 1-2 1996 1 31
3. F.W. Altena, and C.A. Smolders Calculation of liquid liquid-phase separation in a ternary-system of a polymer in a mixture of a solvent and a nonsolvent Macromolecules 15 6 1982 1491 1497
4. L. Yilmaz, and A.J. McHugh Analysis of nonsolvent-solvent-polymer phase diagrams and their relevance to membrane formation modeling J Appl Polym Sci 31 4 1986 997 1018
5. J.Y. Lai, S.F. Lin, F.C. Lin, and D.M. Wang Construction of ternary phase diagrams in nonsolvent/solvent/PMMA systems J Polym Sci Part B Polym Phys 36 4 1998 607 615
6. Y.M. Wei, Z.L. Xu, X.T. Yang, and H.L. Liu Mathematical calculation of binodal curves of a polymer/solvent/nonsolvent system in the phase inversion process Desalination 192 1-3 2006 91 104
7. G.R. Guillen, Y. Pan, M. Li, and E.M. Hoek Preparation and characterization of membranes formed by nonsolvent induced phase separation: a review Ind Eng Chem Res 50 7 2011 3798 3817
8. C. Cohen, G.B. Tanny, and S. Prager Diffusion-controlled formation of porous structures in ternary polymer systems J Polym Sci Polym Phys Ed 17 3 1979 477 489
9. A.J. Reuvers, and C.A. Smolders Formation of membranes by means of immersion precipitation: part II. The mechanism of formation of membranes prepared from the system cellulose acetate-acetone-water J Membr Sci 34 1 1987 67 86
10. A.J. Reuvers, J.W.A. Van den Berg, and C.A. Smolders Formation of membranes by means of immersion precipitation: part I. A model to describe mass transfer during immersion precipitation J Membr Sci 34 1 1987 45 65
11. C.S. Tsay, and A.J. McHugh A technique for rapid measurement of diffusion coefficients Ind Eng Chem Res 31 1 1992 449 452
12. J.M. Cheng, D.M. Wang, F.C. Lin, and J.Y. Lai Formation and gas flux of asymmetric PMMA membranes J Membr Sci 109 1 1996 93 107
13. H.K. Lee, J.Y. Kim, Y.D. Kim, J.Y. Shin, and S.C. Kim Liquid-liquid phase separation in a ternary system of segmented polyetherurethane/dimethylformamide/water: effect of hard segment content Polymer 42 8 2001 3893 3900
14. 13 in the casting solutions J Membr Sci 174 1 2000 87 96
15. H. Yamakawa Correlations between the excluded volumes and the second virial coefficients of linear polymer chains J Chem Phys 48 5 1968 2103
16. C.M. Kok, and A. Rudin Prediction of osmotic pressures of polymer solutions J Appl Polym Sci 26 11 1981 3575 3582
17. C.M. Kok, and A. Rudin Prediction of second virial coefficients from intrinsic viscosities J Appl Polym Sci 26 11 1981 3583 3597
18. C.M. Kok, and A. Rudin Prediction of Flory-Huggins interaction parameters from intrinsic viscosities J Appl Polym Sci 27 2 1982 353 362
19. J.W. Qian, and A. Rudin Prediction of thermodynamic properties of polymer solutions Euro Polym J 28 7 1992 725 732
20. S. Ioan, and M. Bercea Second virial coefficient of oligo- and polyacrylonitrile Polym Test 21 2 2002 233 239
21. R. Dong, M. Keuser, X. Zeng, J. Zhao, Y. Zhang, and C. Wu Viscometric measurement of the thermodynamics of PAN terpolymer/DMSO/water system and effect of fiber forming conditions on the morphology of PAN precursor J Polym Sci Part B Polym Phys 46 19 2008 1997 2011
22. R. Dong, J. Zhao, Y. Zhang, and D. Pan Morphology control of polyacrylonitrile (PAN) fibers by phase separation technique J Polym Sci Part B Polym Phys 47 3 2009 261 275
23. J. Barzin, and B. Sadatnia Theoretical phase diagram calculation and membrane morphology evaluation for water/solvent/polyethersulfone systems Polymer 48 6 2007 1620 1631
24. V. Soria, C.M. Gómez, R. García, and A. Campos Excluded volume in ternary polymer systems J Chem Soc Faraday Trans 88 11 1992 1555 1559
25. M. Karimi, W. Albrecht, M. Heuchel, M.H. Kish, J. Frahn, and T. Weigel Determination of water/polymer interaction parameter for membrane-forming systems by sorption measurement and a fitting technique J Membr Sci 265 1-2 2005 1 12
26. V.R.V. Gowariker, and N.V. Sreedhar Journal of Polymer Science 1986 John Wiley New York [Chapter 12]
27. S. Ioan, G. Grigorescu, C. Ioan, and B.C. Simionescu Excluded volume effect in polyacrylonitrile solutions Polym Bull 33 1 1994 119 125
28. J. Pouchlý, and A. Živný Correlation of data on intrinsic viscosities in mixed solvents by means of the modified Flory-Huggins equation Die Makromol Chem 184 10 1983 2081 2096
29. A. Malkin, S. Ilyin, T. Roumyantseva, and V. Kulichikhin Rheological evidence of gel formation in dilute poly(acrylonitrile) solutions Macromolecules 46 1 2013 257 266
30. B. Celda, C. Gómez, R. Gavara, R. Tejero, and A. Campos Coil expansion and dimensions of poly (dimethylsiloxane) in alkane/2-butanone mixtures Die Makromol Chem 188 12 1987 2909 2920
31. L.J. Tan, D. Pan, and N. Pan Gelation behavior of polyacrylonitrile solution in relation to aging process and gel concentration Polymer 49 26 2008 5676 5682
32. R.M. Boom, T. Vandenboomgaard, J.W.A. Vandenberg, and C.A. Smolders Linearized cloudpoint curve correlation for ternary-systems consisting of one polymer, one solvent and one nonsolvent Polymer 34 11 1993 2348 2356
33. L. Zeman, and G. Tkacik Thermodynamic analysis of a membrane-forming system water/N-methyl-2-pyrrolidone/polyethersulfone J Membr Sci 36 0 1988 119 140
34. L. Tan, D. Pan, and N. Pan Thermodynamic study of a water-dimethylformamide-polyacrylonitrile ternary system J Appl Polym Sci 110 6 2008 3439 3447
35. H. Fashandi, and M. Karimi Pore formation in polystyrene fiber by superimposing temperature and relative humidity of electrospinning atmosphere Polymer 53 25 2012 5832 5849
36. M.J. Han, and D. Bhattacharyya Morphology and transport study of phase inversion polysulfone membranes Chem Eng Commun 128 1 1994 197 209
37. J.Y. Kim, H.K. Lee, K.J. Baik, and S.C. Kim Liquid-liquid phase separation in polysulfone/solvent/water systems J Appl Polym Sci 65 13 1997 2643 2653
38. J. Chen, H.Y. Ge, H.S. Liu, G.Z. Li, and C.G. Wang The phase separation mechanism during coagulation process in PAN wet-spinning J Funct Mater 40 3 2009 523 526
39. J. Zhang, Y. Zhang, and J. Zhao Thermodynamic study of non-solvent/dimethyl sulfoxide/polyacrylonitrile ternary systems: effects of the non-solvent species Polym Bull 67 6 2011 1073 1089
40. Y. Yip, and A.J. McHugh Modeling and simulation of nonsolvent vapor-induced phase separation J Membr Sci 271 1 2006 163 176
41. M.M. Iovleva, V.N. Smirnova, and G.A. Budnitskii The solubility of polyacrylonitrile Fiber Chem 33 4 2001 262 264