Wet oxidation of glycerol into fine organic acids: Catalyst selection and kinetic evaluation

Brazilian Journal of Chemical Engineering

Volumn 31, Issue 4, 2014, Pages 913-923

  Brainer, J E N ^a   Sales, D C S ^a   Medeiros, E B M ^b   Lima Filho, N M ^a   Abreu, C A M ^a  

^a FEDERAL UNIVERSITY OF PERNAMBUCO   (Brazil)

^b FEDERAL UNIVERSITY OF PARAÍBA   (Brazil)

Author keywords

Catalysts; Glyceric acid; Glycerol oxidation; Kinetics; Modeling

Indexed keywords

ACTIVATED CARBON; ACTIVATION ENERGY; ATMOSPHERIC PRESSURE; CATALYSTS; ENZYME KINETICS; EQUILIBRIUM CONSTANTS; KINETICS; MODELS; ORGANIC ACIDS; OXIDATION;

ADSORPTION EQUILIBRIUM CONSTANTS; GLYCERIC ACID; GLYCEROL CONVERSIONS; GLYCEROL OXIDATION; KINETIC EVALUATIONS; LIQUID-PHASE OXIDATION OF GLYCEROL; MECHANICALLY AGITATED SLURRY REACTOR; SELECTIVE FORMATION;

GLYCEROL;

EID: 84913588225     PISSN: 01046632     EISSN: None     Source Type: Journal    
DOI: 10.1590/0104-6632.20140314s00002655     Document Type: Article

References (25)

1. Alardin, F., Ruiz, P., Delmonb, B. and Devillers, M., Bismuth-promoted palladium catalysts for the selective oxidation of glyoxal into glyoxalic acid. Appl. Catal. A: General, 215, 125-136 (2001).
2. Behr, A., Eilting, J., Irawaldi, K., Leschinski, J. and Lindner, F., Improved utilization of renewable resources: New important derivatives of glycerol. Green Chem., 10, 13 (2008).
3. Boehm, H. P., Some aspects of the surface chemistry of carbon blacks on other carbons. Carbon, 32, 759-769 (1994).
4. Boehm, H. P., Surface oxides on carbon and their analysis: A critical assessment. Carbon, 40, 145-149 (2002).
5. Carrettin, S., McMorn, P., Johnston, P. Griffin, K., Kiely, C. J. and Hutchings, G. J., Oxidation of glycerol using supported Pt, Pd and Au catalysts. Phys. Chem. Chem. Phys., 5, 1329-1336 (2003).
6. Corma, A., Iborra, S. and Velty, A., Chemical routes for the transformation of biomass into chemicals. Chem. Rev., 107, 2411-2502 (2007).
7. Demirel-Gülen, S., Lucas, M. and Claus, P., Liquid phase oxidation of glycerol over carbon support gold catalysts. Catal. Today, 102-103,166-172 (2005).
8. Demirel, S., Lucas, M., Warna, J., Salmi, T., Murzin, D. and Claus, P., Reaction kinetics and modeling of the gold catalysed glycerol oxidation. Top. Catal., 44, 299-305 (2005).
9. Ferretti, C. A., Soldano, A., Apesteguía, C. R. and Cosimo, J. I. Di, Monoglyceride synthesis by glycerolysis of methyl oleate on solid acid-base. Chem. Eng. J., 161, 346-354 (2010).
10. Fordham, P., Besson, M. and Gallezot, P., Selective catalytic oxidation of glyceric acid to tartronic and hydroxypyruvic acids. Appl. Catal. A: General, 133,179-184 (1995).
11. Gallezot, P., Selective oxidation with air on metal catalysts. Catal. Today, 37, 405-418 (1997).
12. Guo, L., Zhou, J., Mao, J., Guo, X. and Zhang, S., Supported Cu catalysts for the selective hydrogenolysis of glycerol to propanediols. Appl. Catal. A: Chem., 367, 93-98 (2009).
13. Hu, W., Lowry, B. and Varma, A., Kinetic Study of Glycerol Oxidation Network over Pt-Bi/C Catalyst. Appl. Catal. B: Environmental, 106, 123-132 (2011).
14. Ketchie, W. C., Murayama, M. and Davis, R. J., Promotional effect of hydroxyl on the aqueous phase oxidation of carbon monoxide and glycerol over supported Au catalysts. Top. Catal., 44, 307-317 (2007a).
15. Ketchie, W. C., Murayama, M. and Davis, R. J., Selective oxidation of glycerol over carbon-supported AuPd catalysts. J. of Catalysis, 250, 264-273 (2007b).
16. Kimura, H., Tsuto, K., Wakisaka, T., Kazumi, Y. and Inaya, Y., Selective oxidation of glycerol on a platinum-bismuth catalyst. Appl. Catal. A: Gen., 96, 217-228 (1993).
17. Kimura, H., Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed bed reactor. Appl. Catal. A: Gen., 105, 147-158 (1993).
18. Lehr, V., Sarlea, M., Ott, L. and Vogel, H., Catalytic dehydration of biomass-derived polyols in suband supercritical water. Catal. Today, 121, 121-129 (2007).
19. Luo, N., Fu, X., Cao, F., Xiao, T. and Edwards, P. P., Luo, N., Fu, X., Cao, F., Xiao, T. and Edwards, P. P., Glycerol aqueous phase reforming for hydrogen generation over Pt catalyst -Effect of catalyst composition and reaction conditions. Fuel, 87, 3483-3489 (2008).
20. Mallat, T. and Baiker, A., Catalyst potential: A key for controlling alcohol oxidation. Catal. Today, 24, 143-150 (1995).
21. McCoy, M., Glicerin surplus. Chem. Eng. News, 84, 7 (2006).
22. Tullo, A. H., A living plant. Chem. Eng. News, 85, 53 (2007).
23. Verde, Y., Alonso, G., Zhang, R. V. H., Jacobson, A. J. and Keer, A., Pt/C obtained from carbon with different treatments and (NH4)2PtCl6 as a Pt precursor. Appl. Catal. A: Gen., 277, 201-207 (2004).
24. Villermaux, J., Génie de la réaction chimique conception et fonctionnement des réacteurs. Technique et Documentation Lavoisier, Paris (1993). (In French).
25. Worz, N., Brandner, A., Claus, P., Platinum-Bismuthcatalyzed oxidation of glycerol: Kinetics and the origin of selective deactivation. J. Phys. Chem. C, 114, 1164-1172 (2009).