Process intensification of the Suzuki-Miyaura reaction over sol-gel entrapped catalyst silia cat DPP-Pd under conditions of continuous flow

Organic Process Research and Development

Volumn 18, Issue 11, 2014, Pages 1550-1555

  Pandarus, Valerica ^a   Gingras, Geneviève ^a   Béland, François ^a   Ciriminna, Rosaria ^b   Pagliaro, Mario ^b  

^a SiliCycle Inc   (Canada)

^b CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CHEMICAL REACTIONS; SOL-GELS;

ARYL HALIDES; CONCENTRATED SOLUTION; CONTINUOUS FLOWS; PD CATALYST; PROCESS INTENSIFICATION; SUZUKI-MIYAURA REACTION;

SOL-GEL PROCESS;

EID: 84913570355     PISSN: 10836160     EISSN: 1520586X     Source Type: Journal    
DOI: 10.1021/op4003449     Document Type: Article

References (12)

1. Dumrath, A.; Lübbe, C.; Beller, M. Palladium-Catalyzed Cross-Coupling Reactions-Industrial Applications. In Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Molnár, A., Ed.; Wiley-VCH: Weinheim, 2013; pp 445-489.
2. Köhler, K.; Wussow, K.; Wirth, A. S. Palladium-Catalyzed Cross-Coupling Reactions: A General Introduction. In Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Molnár, A., Ed.; Wiley-VCH, Weinheim, 2013; pp 1-30.
3. Pagliaro, M.; Pandarus, V.; Ciriminna, R.; Béland, F.; Demma Carà, P. ChemCatChem 2012, 4, 432-445
4. Reynolds, W. R.; Frost, C. G. Coupling Reactions in Continuous-Flow Systems. In Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Molnár, A., Ed.; Wiley-VCH, Weinheim, 2013; pp 409-443.
5. Pandarus, V.; Ciriminna, R.; Béland, F.; Gingras, G.; Drobot, M.; Jina, O.; Pagliaro, M. Tetrahedron Lett. 2013, 54, 1129-1132
6. http://www.silicycle.com/eu/applications/catalysis/use-of-siliacat-dpp-pd (last time accessed, January 20, 2014).
7. Lemay, M.; Pandarus, V.; Simard, M.; Marion, O.; Tremblay, L.; Béland, F. Top. Catal. 2010, 53, 1059
8. For detailed information, see at the URL: http://syrris.com/flow-products/asiaflow-chemistry (last time accessed, January 20, 2014).
9. Nagy, K. D.; Shen, B.; Jamison, T. F.; Jensen, K. F. Org. Process Res. Dev. 2012, 16, 976-981
10. Beutler, U.; Boehm, M.; Fuenfschilling, P. C.; Heinz, T.; Mutz, J.-P.; Onken, U.; Mueller, M.; Zaugg, W. Org. Process Res. Dev. 2007, 11, 892-898
11. Pandarus, V.; Desplantier-Giscard, D.; Gingras, G.; Béland, F.; Ciriminna, R.; Pagliaro, M. Org. Process Res. Dev. 2013, 17, 1492-1497
12. Pagliaro, M.; Ciriminna, R.; Palmisano, G. Chem. Soc. Rev. 2007, 36, 932-940