An electrochemical and theoretical evaluation of 4,6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solutions

Corrosion Science

Volumn 90, Issue , 2015, Pages 544-553

  Yildiz, Reşit ^a  

^a CUKUROVA UNIVERSITY   (Turkey)

Author keywords

A. Mild steel; B. EIS; B. Modelling studies; B. SEM; C. Acid corrosion

Indexed keywords

ADSORPTION; CARBON STEEL; ELECTROCHEMICAL CORROSION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; HYDROCHLORIC ACID; QUANTUM CHEMISTRY; SCANNING ELECTRON MICROSCOPY;

ACID CORROSION; B. EIS; LANGMUIR ADSORPTION MODEL; LINEAR POLARIZATION RESISTANCE; MODELLING STUDIES; POTENTIAL OF ZERO CHARGE; POTENTIODYNAMIC MEASUREMENT; QUANTUM CHEMICAL CALCULATIONS;

CORROSION INHIBITORS;

EID: 84913553890     PISSN: 0010938X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.corsci.2014.10.047     Document Type: Article

References (86)

1. Strickland D.M. The resistivity of iron and its application to the chemical industry. Ind. Eng. Chem. 1923, 15:566-569.
2. Hatfield J.D., Slack A.V., Crow G.L., Shaffer H.B. Corrosion in fertilizer equipment, corrosion of metals by liquid mixed fertilizers. J. Agric. Food Chem. 1958, 6:524-531.
3. Ji G., Shukla S.K., Dwivedi P., Sundaram S., Prakash R. Inhibitive effect of Argemone mexicana plant extract on acid corrosion of mild steel. Ind. Eng. Chem. Res. 2011, 50:11954-11959.
4. Amin M.A., Abd EI-Rehim S.S., EI-Sherbini E.E.F., Bayoumi R.S. The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies. Electrochim. Acta 2007, 52:3588-3600.
5. Emregül K.C., Hayvali M. Studies on the effect of vanillin and protocatechual-dehyde on the corrosion of steel in hydrochloric acid. Mater. Chem. Phys. 2004, 83:209-216.
6. Döner A., Şahin E.A., Kardaş G., Serindağ O. Investigation of corrosion inhibition effect of 3-[(2-hydroxy-benzylidene)amino]-2-thioxo-thiazolidin-4-one on corrosion of mild steel in the acidic medium. Corros. Sci. 2013, 66:278-284.
7. Solmaz R. Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid. Corros. Sci. 2010, 52:3321-3330.
8. Solmaz R. Investigation of corrosion inhibition mechanism and stability of Vitamin B1 on mild steel in 0.5M HCl solution. Corros. Sci. 2014, 81:75-84.
9. Döner A., Yüce A.O., Kardaş G. Inhibition effect of rhodanine-N-acetic acid on copper corrosion in acidic media. Ind. Eng. Chem. Res. 2013, 52:9709-9718.
10. Solmaz R., Şahin E.A., Döner A., Kardaş G. The investigation of synergistic inhibition effect of rhodanine and iodide ion on the corrosion of copper in sulphuric acid solution. Corros. Sci. 2011, 53:3231-3240.
11. Emregül K.C., Atakol O. Corrosion inhibition of mild steel with Schiff base compounds in 1M HCl. Mater. Chem. Phys. 2003, 82:188-193.
12. 4. Corros. Sci. 2011, 53:4223-4232.
13. Solmaz R., Kardaş G., Yazici B., Erbil M. Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1,3,4-thiadiazole on mild steel in hydrochloric acid media. Colloid Surf. A 2008, 312:7-17.
14. Mert B.D., Mert M.E., Kardaş G., Yazici B. Experimental and theoretical investigation of 3-amino-1,2,4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium. Corros. Sci. 2011, 53:4265-4272.
15. Özcan M., Karadağ F., Dehri I. Interfacial behavior of cysteine between mild steel and sulfuric acid as corrosion inhibitor. Acta Phys. Chim. Sin. 2008, 24:1387-1392.
16. Yildiz R., Doğan T., Dehri I. Evaluation of corrosion inhibition of mild steel in 0.1M HCl by 4-amino-3-hydroxynaphthalene-1-sulphonic acid. Corros. Sci. 2014, 85:215-221.
17. Caliskan N., Akbas E. The inhibition effect of some pyrimidine derivatives on austenitic stainless steel in acidic media. Mater. Chem. Phys. 2011, 126:983-988.
18. Masoud M.S., Khalil E.A., Ramadan A.M., Gohar Y.M., Sweyllam A. Spectral, electrical conductivity and biological activity properties of some new azopyrimidine derivatives and their complexes. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2007, 67:669-677.
19. Wang L. Inhibiting effect of 2-mercaptopyrimidine on the corrosion of a low carbon steel in phosphoric acid. Corros. Sci. 2001, 43:1637-1644.
20. Abdallah M., Helal E.A., Fouda A.S. Aminopyrimidine derivatives as inhibitors for corrosion of 1018 carbon steel in nitric acid solution. Corros. Sci. 2006, 48:1639-1654.
21. Çalişkan N., Akbaş E. The inhibition effect of some pyrimidine derivatives on austenitic stainless steel in acidic media. Mater. Chem. Phys. 2011, 16:983-988.
22. Khaled K.F. Studies of the corrosion inhibition of copper in sodium chloride solutions using chemical and electrochemical measurements. Mater. Chem. Phys. 2011, 125:427-433.
23. Mert B.D., Yüce A.O., Kardaş G., Yazici B. Inhibition effect of 2-amino-4-methylpyridine on mild steel corrosion: experimental and theoretical investigation. Corros. Sci. 2014, 85:287-295.
24. Masoud M.S., Awad M.K., Shaker M.A., El-Tahawy M.M.T. The role of structural chemistry in the inhibitive performance of some aminopyrimidines on the corrosion of steel. Corros. Sci. 2010, 52:2387-2396.
25. Döner A., Solmaz R., Özcan M., Kardaş G. Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corros. Sci. 2011, 53:2902-2913.
26. Obot I.B., Gasem Z.M. Theoretical evaluation of corrosion inhibition performance of some pyrazine derivatives. Corros. Sci. 2014, 83:359-366.
27. 4 solution. Corros. Sci. 2014, 78:29-42.
28. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, J.A. Montgomery Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J.E. Knox, H.P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, Gaussian 03, Revision B. 03, Gaussian Inc, Pittsburgh, PA, 2003.
29. Gauss View, Version 3.0, Gaussian Inc., Pittsburgh, PA, 2003.
30. Solmaz R., Altunbaş E., Kardaş G. Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiff base on mild steel. Mater. Chem. Phys. 2011, 125:796-801.
31. Yüce A.O., Kardaş G. Adsorption and inhibition effect of 2-thiohydantoin on mild steel corrosion in 0.1M HCl. Corros. Sci. 2012, 58:86-94.
32. Reznik V.S., Akamsin V.D., Khodyrev Yu.P., Galiakberov R.M., Efremov Yu.Ya., Tiwari L. Mercaptopyrimidines as inhibitors of carbon dioxide corrosion of iron. Corros. Sci. 2008, 50:392-403.
33. Musa A.Y., Kadhum A.A.H., Mohamad A.B., Takriff M.S., Daud A.R., Kamarudin S.K. On the inhibition of mild steel corrosion by 4-amino-5-phenyl-4H-1, 2,4-trizole-3-thiol. Corros. Sci. 2012, 58:86-94.
34. Li C., Guo X., Shen S., Song P., Xu T., Wen Y., Yang H. Adsorption and corrosion inhibition of phytic acid calcium on the copper surface in 3wt% NaCl solution. Corros. Sci. 2014, 83:147-154.
35. Solmaz R., Kardaş G., Çulha M., Yazici B., Erbil M. Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media. Electrochim. Acta 2008, 53:5941-5952.
36. Erbil M. Determination of corrosion rates by analysis of AC impedance diagrams. Chim. Acta Turc. 1988, 1:59-70.
37. T. Tüken, B. Yazici, M. Erbil, An investigation on natural occurring corrosion inhibitors, in: Proceedings of Ninth European Symposium on Corrosion Inhibitors (9SEIC), Ann. Univ. Ferrara, N.S., Sez. V, Suppl. No. 11, 2000, pp. 115-126.
38. Özcan M., Karadağ F., Dehri I. Investigation of adsorption characteristics of methionine at mild steel/sulfuric acid interface. An experimental and theoretical study. Colloid Surf. A 2008, 316:55-61.
39. Behpour M., Ghoreishi S.M., Soltani N., Salavati-Niasari M. The inhibitive effect of some bis- N, S-bidentate Schiff bases on corrosion behavior of 304 stainless steel in hydrochloric acid solution. Corros. Sci. 2009, 51:1073-1082.
40. Ma H., Cheng X., Li G., Chen S., Quan Z., Zhao S., Niu L. The influence of hydrogen sulfide on corrosion of iron under different conditions. Corros. Sci. 2000, 42:1669-1683.
41. ○ into a capacitance. Corrosion 2001, 57:747-748.
42. Özcan M., Dehri I. Determination of impedance parameters for mild steel/HCl interface using integration method. Corros. Sci. 2012, 54:201-204.
43. Goulart C.M., Esteves-Souza A., Martinez-Huitle C.A., Ferreira Rodrigues C.J., Medeiros Maciel M.A., Echevarria A. Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors. Corros. Sci. 2013, 67:281-291.
44. Prabhu R.A., Venkatesha T.V., Shanbhag A.V., Kulkarni G.M., Kalkhambkar R.G. Inhibition effects of some Schiff's bases on the corrosion of mild steel in hydrochloric acid solution. Corros. Sci. 2008, 50:3356-3362.
45. Tang Y., Yang X., Yang W., Chen Y., Wan R. Experimental and molecular dynamics studies on corrosion inhibition of mild steel by 2-amino-5-phenyl-1,3,4-thiadiazole. Corros. Sci. 2010, 52:242-249.
46. Sherif E.S.M. Electrochemical investigations on the corrosion inhibition of aluminum by 3-amino-1,2,4-triazole-5-thiol in naturally aerated stagnant seawater. J. Ind. Eng. Chem. 2013, 19:1884-1889.
47. Yadav D.K., Maiti B., Quraishi M.A. Electrochemical and quantum chemical studies of 3,4-dihydropyrimidin-2(1H)-ones as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros. Sci. 2010, 52:3586-3598.
48. Kumar C.B.P., Mohana K.N. Corrosion inhibition efficiency and adsorption characteristics of some Schiff bases at mild steel/hydrochloric acid interface. J. Taiwan Inst. Chem. Eng. 2014, 45:1031-1042.
49. Bockris J.O.M., Reddy A.K.N. Modern Electrochemistry 1976, vol. 2. Plenum Publishing Corporation, West 17th, Street, New York, 227.
50. Keleş H., Keleş M., Dehri I., Serindağ O. The inhibitive effect of 6-amino-mcresol and its Schiff base on the corrosion of mild steel in 0.5M HCI medium. Mater. Chem. Phys. 2008, 112:173-179.
51. Keleş H., Keleş M., Dehri I., Serindağ O. Adsorption inhibitive properties of aminobiphenyl its Schiff base on mild steel corrosion in 0.5M HCl medium. Colloids Surf., A: Physicochem. Eng. Aspects 2008, 320:138-145.
52. 4 solutions by a newly synthesized glycine derivative. Corros. Sci. 2011, 53:873-885.
53. Lebrini M., Robert F., Vezin H., Roos C. Electrochemical and quantum chemical studies of some indole derivatives as corrosion inhibitors for C38 steel in molar hydrochloric acid. Corros. Sci. 2010, 52:3367-3376.
54. Bahrami M.J., Hosseini S.M.A., Pilvar P. Experimental and theoretical investigation of organic compounds as inhibitors for mild steel corrosion in sulfuric acid medium. Corros. Sci. 2010, 52:2793-2803.
55. Moretti G., Guidi F., Grion G. Tryptamine as a green iron corrosion inhibitor in 0.5M deaerated sulphuric acid. Corros. Sci. 2004, 46:387-403.
56. Yildiz R., Döner A., Doğan T., Dehri I. Experimental studies of 2-pyridinecarbonitrile as corrosion inhibitor for mild steel in hydrochloric acid solution. Corros. Sci. 2014, 82:125-132.
57. Ahamad I., Prasad R., Quraishi M.A. Experimental and quantum chemical characterization of the adsorption of some Schiff base compounds of phthaloyl thiocarbohydrazide on the mild steel in acid solutions. Corros. Sci. 2010, 52:933-942.
58. Noor E.A., Al-Moubaraki A.H. Thermodynamic study of metal corrosion and inhibitor adsorption processes in mild steel/1-methyl-4[4'(-X)-styryl pyridinium iodides/hydrochloric acid systems. Mater. Chem. Phys. 2008, 110:145-154.
59. Özcan M., Solmaz R., Kardas G., Dehri I. Adsorption properties of barbiturates as green corrosion inhibitors on mild steel in phosphoric acid. Colloids Surf. A 2008, 325:57-62.
60. 4 solutions. Corros. Sci. 2011, 53:302-309.
61. El Mehdi B., Mernari B., Traisnel M., Bentiss F., Lagrenee M. Synthesis and comparative study of the inhibitive effect of some new triazole derivatives towards corrosion of mild steel in hydrochloric acid solution. Mater. Chem. Phys. 2002, 77:489-496.
62. Antropov L.I. Teoreticheskaya elektrokhimiya (Theoretical Electrochemistry) 1969, Vyssh. Shkola, Moscow.
63. Antropov L.I. Kinetics of Electrode Processes and Null Points of Metals 1960, Council of Scientific & Industrial Research, New Delhi.
64. Solmaz R. Investigation of adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by 5-4-dimethylaminobenzylidene) rhodanine. Corros. Sci. 2014, 79:169-176.
65. Lebrini M., Lagrenee M., Vezin H., Gengembre L., Bentiss F. Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium. Corros. Sci. 2005, 47:485-505.
66. Lukomska A., Sobkowski J. Potential of zero charge of monocrystalline copper electrodes in perchlorate solutions. J. Electroanal. Chem. 2004, 567:95-102.
67. Kardas G., Solmaz R. Electrochemical investigation of barbiturates as gren corrosion inhibitors for mild steel protection. Corros. Rev. 2006, 24:151-171.
68. Li W., He Q., Pei C., Hou B. Experimental and theoretical investigation of the adsorption behaviour of new triazole derivatives as inhibitors for mild steel corrosion in acid media. Electrochim. Acta 2007, 52:6386-6394.
69. 4. Corros. Sci. 2011, 53:253-275.
70. Musa A.Y., Mohamad A.B., Kadhum A.A.H., Takriff M.S., Tien L.T. Synergistic effect of potassium iodide with phthalazone on the corrosion inhibition of mild steel in 1.0M HCl. Corros. Sci. 2011, 53:3672-3677.
71. Tourabi M., Nohair K., Traisnel M., Jama C., Bentiss F. Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole. Corros. Sci. 2013, 75:123-133.
72. Sudheer, Quraishi M.A. Electrochemical and theoretical investigation of triazole derivatives on corrosion inhibition behavior of copper in hydrochloric acid medium. Corros. Sci. 2013, 70:161-169.
73. 3 catalyst as a new corrosion inhibitor for mild steel in 0.5M sulphuric acid. Corros. Sci. 2013, 71:20-31.
74. Deng Q., Shi H., Ding N., Chen B., He X., Liu G., Tang Y., Long Y., Chen G. Novel triazolyl bis-amino acid derivatives readily synthesized via click chemistry as potential corrosion inhibitors for mild steel in HCl. Corros. Sci. 2012, 57:220-227.
75. Hegazy M.A., Ahmed H.M., El-Tabei A.S. Investigation of the inhibitive effect of p-substituted 4-(N, N, N-dimethyldodecylammonium bromide)benzylidene-benzene-2-yl-amine on corrosion of carbon steel pipelines in acidic medium. Corros. Sci. 2011, 53:671-678.
76. Li W., He Q., Pei c C., Hou B. Experimental and theoretical investigation of the adsorption behaviour of new triazole derivatives as inhibitors for mild steel corrosion in acid media. Electrochim. Acta 2007, 52:6386-6394.
77. Herrag L., Hammouti B., Elkadiri S., Aouniti A., Jama C., Vezin H., Bentiss F. Adsorption properties and inhibition of mild steel corrosion in hydrochloric solution by some newly synthesized diamine derivatives: experimental and theoretical investigations. Corros. Sci. 2010, 52:3042-3051.
78. Deng S., Li X., Xie Xi. Hydroxymethyl urea and 1,3-bis(hydroxymethyl) urea as corrosion inhibitors for steel in HCl solution. Corros. Sci. 2014, 80:276-289.
79. Yüce A.O., Mert B.D., Kardaş G., Yazici B. Electrochemical and quantum chemical studies of 2-amino-4-methyl-thiazole as corrosion inhibitor for mild steel in HCl solution. Corros. Sci. 2014, 83:310-316.
80. Li X., Xie X., Deng S., Du G. Two phenylpyrimidine derivatives as new corrosion inhibitors for cold rolled steel in hydrochloric acid solution. Corros. Sci. 2014, 87:27-39.
81. Obot I.B., Obi-Egbedi N.O. Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation. Corros. Sci. 2010, 52:198-204.
82. Tian H., Li W., Cao K., Hou B. Potent inhibition of copper corrosion in neutral chloride media by novel thiadiazole derivatives. Corros. Sci. 2013, 73:281-291.
83. Hegazy M.A., Badawi A.M., Abd El Rehim S.S., Kamel W.M. Corrosion inhibition of carbon steel using novel N-(2-(2-mercapto acetoxy)ethyl)-N, N-dimethyl) dodecan-1-aminium bromide during acid pickling. Corros. Sci. 2013, 69:110-122.
84. Kovačević N., Kokalj A. The relation between adsorption bonding and corrosion inhibition of azole molecules on copper. Corros. Sci. 2013, 73:7-17.
85. El Adnani Z., Mcharfi M., Sfaira M., Benzakour M., Benjelloun A.T., Ebn Touhami M. DFT theoretical study of 7-R-3methylquinoxalin-2(1H)-thiones (R = H; CH3; Cl) as corrosion inhibitors in hydrochloric acid. Corros. Sci. 2013, 68:223-230.
86. Ju H., Kai Z.P., Li Y. Aminic nitrogen-bearing polydentate Schiff base compounds as corrosion inhibitors for iron in acidic media: a quantum chemical calculation. Corros. Sci. 2008, 50:865-871.