Adsorption of linear alkyl benzene sulfonates on oil-water interface: Effects of Na+, Mg2+ and Ca2+ ions

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 466, Issue , 2015, Pages 18-27

  Anachkov, Svetoslav E ^a   Tcholakova, Slavka ^a   Dimitrova, Dora T ^a   Denkov, Nikolai D ^a   Subrahmaniam, Narayanan ^b   Bhunia, Panchanan ^b  

^a UNIVERSITY OF SOFIA   (Bulgaria)

^b Hindustan Lever Limited   (India)

Author keywords

Adsorption; Fluid fluid interfaces; Hardness ions; Ionic binding effects; Linear alkyl benzene sulfonates

Indexed keywords

ADSORPTION; AIR; BENZENE; CALCIUM; HARDNESS; IONS; MOLECULES; OIL SHALE; SURFACE ACTIVE AGENTS;

ADSORPTION PROPERTIES; ELECTROSTATIC ATTRACTIONS; FLUID FLUID INTERFACES; HARDNESS IONS; IONIC BINDING; LINEAR ALKYL BENZENE; OIL WATER INTERFACES; SURFACTANT ADSORPTION;

PHASE INTERFACES;

ALKYLBENZENESULFONIC ACID; CALCIUM ION; LINEAR ALKYL BENZENE SULFONATE; MAGNESIUM ION; SODIUM ION; UNCLASSIFIED DRUG; WATER OIL CREAM;

ADSORPTION; ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; DISSOLUTION; HARDNESS; TENSION;

EID: 84912572108     PISSN: 09277757     EISSN: 18734359     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2014.10.059     Document Type: Article

References (31)

1. Meader A.L., Criddle D.W. Force-area curves of surface films of soluble surface-active agents. J. Colloid Sci. 1953, 8:170.
2. Ma J.-G., Boyd B.J., Drummond C.J. Positional isomers of linear sodium dodecyl benzene sulfonate: solubility, self-assembly, and air/water interfacial activity. Langmuir 2006, 22:8646.
3. Tucker I., Penfold J., Thomas R.K., Dong C.C., Golding S., Gibson C., Grillo I. Surface and solution properties of anionic/nonionic surfactant mixtures of alkylbenzene sulfonate and triethyleneglycol decyl ether. Langmuir 2010, 26:10614.
4. Tucker I., Penfold J., Thomas R.K., Dong C.C., Golding S., Gibson C., Grillo I. The adsorption and self-assembly of mixtures of alkylbenzene sulfonate isomers and the role of divalent electrolyte. Langmuir 2011, 27:6674.
5. Li Y., He X.J., Cao W.L., Zhao G.Q., Tian X.X., Cui X.H. Molecular behavior and synergistic effects between sodium dodecylbenzene sulfonate and Triton X-100 at oil/water interface. J. Colloid Interface Sci. 2007, 307:215.
6. van Os N.M., Rupert L.A.M., Smit B., Hilbers P.A.J., Esselink K., Bohmer M.R., Koopal L.K. Surfactant adsorption at liquid/liquid interfaces. Comparison of experimental results with self-consistent field lattice calculations and molecular dynamics simulations. Colloids Surf. A 1993, 81:217.
7. Ludlum D.B. Micelle formation in solutions of some isomeric detergents. J. Phys. Chem. 1956, 60:1240.
8. van Os N.M., Daane G.J., Bolsman T.A.B.M. The effect of chemical structure upon the thermodynamics of micellization of model alkylarenesulfonates: II. Sodium p-(3-alkyl)benzenesulfonate homologs. J. Colloid Interface Sci. 1988, 123:267.
9. Sein A., Engberts J.B.F.N. Micelle to lamellar aggregate transition of an anionic surfactant in dilute aqueous solution induced by alkali metal chloride and tetraalkyl-ammonium chloride salts. Langmuir 1995, 11:455.
10. McFearin C.L., Beaman D.K., Moore F.G., Richmond G.L. From Franklin to today: toward a molecular level understanding of bonding and adsorption at the oil-water interface. J. Phys. Chem. C 2009, 113:1171.
11. Conboy J.C., Daschbach J.L., Richmond G.L. Studies of alkane/water interfaces by total internal reflection second harmonic generation. J. Phys. Chem. 1994, 98:9688.
12. Azzam R.M.A., Bashara N.M. Ellipsometry and Polarised Light 1977, North-Holland Publishing Co.
13. Russev S.C., Arguirov T.V., Gurkov T.D. Beta-casein adsorption kinetics on air-water and oil-water interfaces studied by ellipsometry. Colloids Surf. B 2000, 19:89.
14. Lee L.T., Langevin D., Farnoux B. Neutron reflectivity of an oil-water interface. Phys. Rev. Lett. 1991, 67:2678.
15. Golemanov K., Tcholakova S., Denkov N., Pelan E., Stoyanov S.D. The role of the hydrophobic phase in the unique rheological properties of saponin adsorption layers. Soft Matter 2014, 10:7034.
16. Gaonkar A.G., Borwankar R.P. Adsorption behavior of monoglycerides at the vegetable oil/water interface. J. Colloid Interface Sci. 1991, 146:525.
17. Gaonkar A.G., Borwankar R.P. Competitive adsorption of monoglycerides and lecithin at the vegetable oil-water interface. Colloids Surf. 1991, 59:331.
18. Gurkov T.D., Dimitrova D.T., Marinova K.G., Bilke-Crause C., Gerber C., Ivanov I.B. Ionic surfactants on fluid interfaces: determination of the adsorption; role of the salt and the type of the hydrophobic phase. Colloids Surf. A 2005, 261:29.
19. Dukhin S.S., Kretzschmar G., Miller R. Dynamics of Adsorption at Liquid Interfaces 1995, Elsevier, Amsterdam.
20. Adamson A.W., Gast A.W. Physical Chemistry of Surfaces 1997, Wiley, New York. sixth ed.
21. Kralchevsky P.A., Danov K.D., Broze G., Mehreteab A. Thermodynamics of ionic surfactant adsorption with account for the counterion binding: effect of salts of various valency. Langmuir 1999, 15:2351.
22. Kolev V.L., Danov K.D., Kralchevsky P.A., Broze G., Mehreteab A. Comparison of the van der Waals and Frumkin adsorption isotherms for sodium dodecyl sulfate at various salt concentrations. Langmuir 2002, 18:9106.
23. Chanda S., Das D., Das J., Ismail K. Adsorption characteristics of sodium dodecyl-sulfate and cetylpyridinium chloride at air/water, air/formamide and air/water-formamide interfaces. Colloids Surf. A 2012, 399:56.
24. Israelachvili J.N. Intermolecular and Surface Forces 2011, Academic Press, Amsterdam. third ed.
25. Ivanov I.B., Danov K.D., Dimitrova D., Boyanov M.I., Ananthapadmanabhan K.P., Lips A. Equations of state and adsorption isotherms of low molecular non-ionic surfactants. Colloids Surf. A 2010, 354:118.
26. Corrin M.L., Harkins W.D. The effect of salts on the critical concentration for the formation of micelles in colloidal electrolytes. J. Am. Chem. Soc. 1947, 69:683.
27. Penfold J., Staples E., Tucker I., Thomas R.K. Surface ordering in dilute dihexadecyl dimethyl ammonium bromide solutions at the air-water interface. Langmuir 2004, 20:2265.
28. Lu J.R., Marrocco A., Su T.J., Thomas R.K., Penfold J. Adsorption of dodecyl sulfate surfactants with monovalent metal counterions at the air-water interface studied by neutron reflection and surface tension. J. Colloid Interface Sci. 1993, 158:303.
29. Lu J.R., Purcell I.P., Lee E.M., Simister E.A., Thomas R.K., Rennie A.R., Penfold J. The composition and structure of sodium dodecyl sulfate-dodecanol mixtures adsorbed at the air-water interface: a neutron reflection study. J. Colloid Interface Sci. 1995, 174:441.
30. Das S., Bhirud R.G., Nayyar N., Narayan K.S., Kumar V.V. Chemical shift changes on micellization of linear alkyl benzenesulfonate and oleate. J. Phys. Chem. 1992, 96:7454.
31. Kralchevsky P.A., Danov K.D., Denkov N.D. Chemical physics of colloid systems and interfaces. Handbook of Surface and Colloid Chemistry 1997, CRC Press LLS, Boca Raton, (Chapter 11). K.S. Birdi (Ed.).