Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp∗(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium This paper is dedicated to John Bercaw on the occasion of his 70th birthday

Polyhedron

Volumn 84, Issue , 2014, Pages 203-208

  Liu, Hsueh Ju ^a   Ziegler, Micah S ^a   Tilley, T Don ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Anionic carbene complexes C H activation; Cyclometalation; N heterocyclic carbene ring opening; Silylene complexes

Indexed keywords

ACTIVATION ANALYSIS; LIGANDS; ORGANIC COMPOUNDS; RUTHENIUM COMPOUNDS; SILICON COMPOUNDS;

ANIONIC CARBENE COMPLEX C-H ACTIVATION; CARBENE COMPLEXES; CYCLOMETALATION; FISCHER TYPE CARBENE COMPLEXES; IMIDAZOL; N-HETEROCYCLIC CARBENE RING-OPENING; N-HETEROCYCLIC CARBENES; N-HETEROCYLIC CARBENES; RING OPENING; SILYLENE COMPLEXES;

CHEMICAL ACTIVATION;

EID: 84911469508     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2014.08.052     Document Type: Article

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