Rapid stiffening of a microfluidic endoskeleton via frontal polymerization

ACS Applied Materials and Interfaces

Volumn 6, Issue 21, 2014, Pages 18469-18474

  Robertson, Ian D ^a   Hernandez, Hector Lopez ^a   White, Scott R ^a,b   Moore, Jeffrey S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b University of Illinois at Urbana Champaign   (United States)

Author keywords

frontal polymerization; microfluidic endoskeleton; rapid stiffening; shape fixing

Indexed keywords

ELASTIC MODULI; MICROFLUIDICS; POLYDIMETHYLSILOXANE; SILICONES; TENSILE TESTING;

ADAPTIVE ENGINEERING; FRONTAL POLYMERIZATION; POLYDIMETHYLSILOXANE PDMS; RAPID STIFFENING; SELF PROPAGATING REACTION; SHAPE FIXING; SYSTEMATIC VARIATION; VASCULAR ARCHITECTURE;

POLYMERIZATION;

EID: 84910137085     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am5061596     Document Type: Article

References (25)

1. Bissette, A. J.; Fletcher, S. P. Mechanisms of Autocatalysis Angew. Chem., Int. Ed. 2013, 52, 12800-12826
2. Benson, S. W. The Kinetics and Thermochemistry of Chemical Oxidation with Application to Combustion and Flames Prog. Energy Combust. Sci. 1981, 7, 125-134
3. Arimitsu, K.; Miyamoto, M.; Ichimura, K. Applications of a Nonlinear Organic Reaction of Carbamates to Proliferate Aliphatic Amines Angew. Chem., Int. Ed. 2000, 112, 3567-3570
4. Chechilo, N. M.; Khvilivitskii, R. J.; Enikolopyan, N. S. Propagation of the Polymerization Reaction Dokl. Akad. Nauk SSSR 1972, 204, 1180-1181
5. Endo, M.; Abe, S.; Deguchi, Y.; Yotsuyanagi, T. Kinetic Determination of Trace Cobalt(II) by Visual Autocatalytic Indication Talanta 1998, 47, 349-353
6. Mariani, A.; Fiori, S.; Bidali, S.; Alzari, V.; Malucelli, G. Frontal Polymerization of Diurethane Diacrylates J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 3344-3352
7. Chekanov, Y.; Arrington, D.; Brust, G.; Pojman, J. A. Frontal Curing of Epoxy Resins: Comparison of Mechanical and Thermal Properties to Batch-cured Materials J. Appl. Polym. Sci. 1997, 66, 1209-1216
8. Mariani, A.; Bidali, S.; Fiori, S.; Sangermano, M.; Malucelli, G.; Bongiovanni, R.; Priola, A. UV-ignited Frontal Polymerization of an Epoxy Resin J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 2066-2072
9. Scognamillo, S.; Bounds, C.; Thakuri, S.; Mariani, A.; Wu, Q.; Pojman, J. A. Frontal Cationic Curing of Epoxy Resins in the Presence of Defoaming or Expanding Compounds J. Appl. Polym. Sci. 2014, 131, 40339-40349
10. Nagy, I. P.; Sike, L.; Pojman, J. A. Thermochromic Composite Prepared via a Propagating Polymerization Front J. Am. Chem. Soc. 1995, 117, 3611-3612
11. Washington, R. P.; Steinbock, O. Frontal Polymerization Synthesis of Temperature-Sensitive Hydrogels J. Am. Chem. Soc. 2001, 123, 7933-7934
12. Guo, X.; Wang, C.-F.; Fang, Y.; Chen, L.; Chen, S. Fast Synthesis of Versatile Nanocrystal-embedded Hydrogels Toward the Sensing of Heavy Metal Ions and Organoamines J. Mater. Chem. 2011, 21, 1124-1129
13. Sanna, R.; Alzari, V.; Nuvoli, D.; Scognamillo, S.; Marceddu, S.; Mariani, A. Polymer Hydrogels of 2-Hydroxyethyl Acrylate and Acrylic Acid Obtained by Frontal Polymerization J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1515-1520
14. Proietti, N.; Capitani, D.; Cozzolino, S.; Valentini, M.; Pedemonte, E.; Princi, E.; Vicini, S.; Segre, A. L. In Situ and Frontal Polymerization for the Consolidation of Porous Stones: A Unilateral NMR and Magnetic Resonance Imaging Study J. Phys. Chem. B 2006, 110, 23719-23728
15. Kim, C.; Teng, H.; Tucker, C. L.; White, S. R. The Continuous Curing Process for Thermoset Polymer Composites. Part 1: Modeling and Demonstration J. Compos. Mater. 1995, 29, 1222-1253
16. Mota-Morales, J. D.; Gutiérrez, M. C.; Ferrer, M. L.; Sanchez, I. C.; Elizalde-Peña, E. A.; Pojman, J. A.; Monte, F. D.; Luna-Bárcenas, G. Deep Eutectic Solvents as Both Active Fillers and Monomers for Frontal Polymerization J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1767-1773
17. Chang, S. T.; Uçar, A. B.; Swindlehurst, G. R.; Bradley, R. O.; Renk, F. J.; Velev, O. D. Materials of Controlled Shape and Stiffness with Photocurable Microfluidic Endoskeleton Adv. Mater. 2009, 21, 2803-2807
18. Nason, C.; Roper, T.; Hoyle, C.; Pojman, J. A. UV-Induced Frontal Polymerization of Multifunctional (Meth)acrylates Macromolecules 2005, 38, 5506-5512
19. Nason, C.; Pojman, J. A.; Hoyle, C. The Effect of a Trithiol and Inorganic Fillers on the Photo-induced Thermal Frontal Polymerization of a Triacrylate J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 8091-8096
20. Pojman, J. A. In Polymer Science: A Comprehensive Reference; Matyjaszewski, K.; Möller, M., Eds.; Elsevier: Amsterdam, 2012; pp 957-980.
21. Binici, B.; Fortenberry, D. I.; Leard, K. C.; Molden, M.; Olten, N.; Popwell, S.; Pojman, J. A. Spherically Propagating Thermal Polymerization Fronts J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 1387-1395
22. Goldfeder, P. M.; Volpert, V. A.; Ilyashenko, V. M.; Khan, A. M.; Pojman, J. A.; Solovyov, S. E. Mathematical Modeling of Free-Radical Polymerization Fronts J. Phys. Chem. B 1997, 101, 3474-3482
23. Siegel, A. C.; Bruzewicz, D. A.; Weibel, D. B.; Whitesides, G. M. Microsolidics: Fabrication of Three-Dimensional Metallic Microstructures in Poly(dimethylsiloxane) Adv. Mater. 2007, 19, 727-733
24. Toohey, K. S.; Sottos, N. R.; Lewis, J. A.; Moore, J. S.; White, S. R. Self-healing Materials with Microvascular Networks Nat. Mater. 2007, 6, 581-585
25. Esser-Kahn, A. P.; Thakre, P. R.; Dong, H.; Patrick, J. F.; Vlasko-Vlasov, V. K.; Sottos, N. R.; Moore, J. S.; White, S. R. Three-Dimensional Microvascular Fiber-Reinforced Composites Adv. Mater. 2011, 23, 3654-3658