An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks

Inorganic Chemistry Communications

Volumn 51, Issue , 2015, Pages 9-12

  Guo, Zhiyong ^a   Su, Shengqun ^a   Deng, Ruiping ^a   Zhang, Hongjie ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

Antiferromagnetic interaction; Biphenyl 3, 4 , 5 tricarboxylate (H3BPT); Crystal structure; Free carboxylic acids; Metal organic framework

Indexed keywords

EID: 84910044424     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2014.10.030     Document Type: Article

References (26)

1. H.-C. Zhou, J.R. Long, and O.M. Yaghi Introduction to metal-organic frameworks Chem. Rev. 112 2012 673 674
2. M. Li, D. Li, M. O'Keeffe, and O.M. Yaghi Topological analysis of metal-organic frameworks with polytopic linkers and/or multiple building units and the minimal transitivity principle Chem. Rev. 114 2013 1343 1370
3. Q.-R. Fang, G.-S. Zhu, Z. Jin, M. Xue, X. Wei, D.-J. Wang, and S.-L. Qiu A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters Angew. Chem. Int. Ed. 45 2006 6126 6130
4. L. Hou, J.-P. Zhang, X.-M. Chen, and S.W. Ng Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Chem. Commun. 2008 4019 4021
5. Q.-G. Zhai, C.-Z. Lu, X.-Y. Wu, and S.R. Batten Coligand modulated six-, eight-, and ten-connected Zn/Cd-1,2,4-triazolate frameworks based on mono-, bi-, tri-, penta-, and heptanuclear cluster units Cryst. Growth Des. 7 2007 2332 2342
6. S.P. Argent, A. Greenaway, M.d.C. Gimenez-Lopez, W. Lewis, H. Nowell, A.N. Khlobystov, A.J. Blake, N.R. Champness, and M. Schröder High-nuclearity metal-organic nanospheres: a Cd66 ball J. Am. Chem. Soc. 134 2011 55 58
7. 6 + cluster as secondary building units Chem. Commun. 2007 1527 1529
8. M. Park, D. Moon, J.W. Yoon, J.-S. Chang, and M.S. Lah A metal-organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior Chem. Commun. 2009 2026 2028
9. X.-L. Wang, C. Qin, E.-B. Wang, Z.-M. Su, L. Xu, and S.R. Batten An unprecedented eight-connected self-penetrating network based on pentanuclear zinc cluster building blocks Chem. Commun. 2005 4789 4791
10. X.N. Cheng, W.X. Zhang, Y.Y. Lin, Y.Z. Zheng, and X.M. Chen A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Adv. Mater. 19 2007 1494 1498
11. 4] clusters J. Am. Chem. Soc. 131 2009 10140 10150
12. II chemistry of 2,6-bis(2-pyridylcarbonyl)pyridine: an icosanuclear Co cluster exhibiting superparamagnetic relaxation Angew. Chem. Int. Ed. 45 2006 432 435
13. L.-J. Chen, J.-B. Su, R.-B. Huang, S. Lin, M.-X. Yang, and H. Huang A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate Dalton Trans. 40 2011 9731 9736
14. 8-cluster-based coordination polymers showing high-connected self-penetrating networks: syntheses, crystal structures, and magnetic properties Inorg. Chem. 52 2013 8091 8098
15. 12 building block Cryst. Growth Des. 9 2009 1271 1274
16. 2] clusters linked by an unsymmetrical pyridylbenzoate ligand Inorg. Chem. 46 2007 9021 9023
17. C. Tian, Z. Lin, and S. Du Three new three-dimensional frameworks based on hepta-, hexa-, and pentanuclear cobalt clusters derived from substituted isophthalic acids: synthesis, structures, and magnetic properties Cryst. Growth Des. 13 2013 3746 3753
18. G.-H. Wang, Y.-Q. Lei, N. Wang, R.-L. He, H.-Q. Jia, N.-H. Hu, and J.-W. Xu Construction of metal-organic frameworks with tetranuclear metal clusters: hydrothermal synthesis, structure, and magnetic properties Cryst. Growth Des. 10 2010 534 540
19. M.-H. Zeng, H.-H. Zou, S. Hu, Y.-L. Zhou, M. Du, and H.-L. Sun Unique (3,13)-connected coordination framework based on pentacobalt clusters constructed from the (3,12)-connected analogue and 4,4′-bipyridyl spacer: structural and magnetic aspects Cryst. Growth Des. 9 2009 4239 4242
20. W.-Q. Zou, M.-S. Wang, Y. Li, A.Q. Wu, F.-K. Zheng, Q.-Y. Chen, Guo, and J.-S. Huang Unprecedented (3,10)-connected 2-D metal-organic framework constructed from octanuclear cobalt(II) clusters and a new bifunctional ligand Inorg. Chem. 46 2007 6852 6854
21. Z. Guo, G. Li, L. Zhou, S. Su, Y. Lei, S. Dang, and H. Zhang Magnesium-based 3D metal-organic framework exhibiting hydrogen-sorption hysteresis Inorg. Chem. 48 2009 8069 8071
22. A.G. Wong-Foy, O. Lebel, and A.J. Matzger Porous crystal derived from a tricarboxylate linker with two distinct binding motifs J. Am. Chem. Soc. 129 2007 15740 15741
23. S. Su, Z. Guo, G. Li, R. Deng, S. Song, C. Qin, C. Pan, H. Guo, F. Cao, S. Wang, and H. Zhang Tetracarboxylate-based Co(ii), Ni(ii) and Cu(ii) three-dimensional coordination polymers: syntheses, structures and magnetic properties Dalton Trans. 39 2010 9123 9130
24. - cluster J. Am. Chem. Soc. 127 2005 16362 16363
25. T. Gadzikwa, O.K. Farha, K.L. Mulfort, J.T. Hupp, and S.T. Nguyen A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration Chem. Commun. 2009 3720 3722
26. C.-C. Ji, J. Li, Y.-Z. Li, Z.-J. Guo, and H.-G. Zheng Solvothermal synthesis, structures and physical properties of four new complexes constructed from multi-variant tricarboxylate ligand and pyridyl-based ligands CrystEngComm 13 2011 459 466