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Volumn 1, Issue 4, 2014, Pages 368-372

Palladium-catalysed regioselective hydroamination of 1,3-dienes: Synthesis of allylic amines

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; PALLADIUM;

EID: 84910016300     PISSN: 20524110     EISSN: 20524129     Source Type: Journal    
DOI: 10.1039/c4qo00023d     Document Type: Article
Times cited : (53)

References (56)
  • 10
    • 0042379988 scopus 로고    scopus 로고
    • For selected examples of telomerisation processes see
    • B. M. Trost M. L. Crawley Chem. Rev. 2003 103 2921
    • (2003) Chem. Rev. , vol.103 , pp. 2921
    • Trost, B.M.1    Crawley, M.L.2
  • 17
    • 0034226755 scopus 로고    scopus 로고
    • Catalytic anti-Markovnikov additions of nucleophiles to olefins have been described as one of the "top 10 challenges for catalysis." See
    • S. M. Maddock M. G. Finn Organometallics 2000 19 2684
    • (2000) Organometallics , vol.19 , pp. 2684
    • Maddock, S.M.1    Finn, M.G.2
  • 56
    • 84893491316 scopus 로고    scopus 로고
    • When the hydroamination reaction was performed using a 1 : 1 ratio of isoprene and amine, the reaction gave a poorer yield of the desired product. Using 4 equiv. of isoprene resulted in the complete consumption of amine and a high product yield. It should be noted that in the presence of the Pd-catalyst, isoprene easily undergoes dimerisation as well as oligo- and polymerisation reactions. For example, we observed the dimerisation of isoprene (molecular mass 136) in the GC-MS analysis of some crude reaction mixtures
    • D. Banerjee K. Junge M. Beller Angew. Chem., Int. Ed. 2014 53 1630
    • (2014) Angew. Chem., Int. Ed. , vol.53 , pp. 1630
    • Banerjee, D.1    Junge, K.2    Beller, M.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.