Re-evaluating the reactive uptake of HOBr in the troposphere with implications for the marine boundary layer and volcanic plumes

Atmospheric Chemistry and Physics

Volumn 14, Issue 20, 2014, Pages 11185-11199

  Roberts, T J ^a   Jourdain, L ^a   Griffiths, P T ^b   Pirre, M ^a  

^a UNIVERSITÉ D'ORLÉANS   (France)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84908681082     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-14-11185-2014     Document Type: Article

References (48)

1. Abbatt, J. P. D. and Waschewsky, G. C.G.: Heterogeneous Interactions of HOBr, HNO 3 sub O 3 sub and NO 2 sub with Deliquescent NaCl Aerosols at Room Temperature, J. Phys. Chem. A, 102, 3719-3725, 1998.
2. Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI-heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045-8228, doi10.5194 acp-13-8045-2013, 2013.
3. Barrie, L. A., Bottenheim, J. W., Schnell, R. C., Crutzen, P. J., and Rasmussen, R. A.: Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere, Nature, 334, 138-141, 1988.
4. Beckwith, R. C., Wang, T. X., and Margerum, D. W.: Equilibrium and Kinetics of Bromine Hydrolysis, Inorg. Chem., 35, 995-1000, 1996.
5. Bobrowski, N. and Platt, U.: SO 2 sub BrO ratios studied in five volcanic plumes, J. Volcanol. Geoth. Res., 166, 147-160, doi10.1016 j.jvolgeores.2007.07.003, 2007.
6. Bobrowski, N., Honniger, G., Galle, B., and Platt, U.: Detection of bromine monoxide in a volcanic plume, Nature, 423, 273-276, doi10.1038 nature01625, 2003.
7. Bobrowski, N., von Glasow, R., Aiuppa, A., Inguaggiato, S., Louban, I., Ibrahim, O. W., and Platt, U.: Reactive halogen chemistry in volcanic plumes, J. Geophys. Res., 112, D06311, doi10.1029 2006JD007206, 2007.
8. Boichu, M., Oppenheimer, C., Roberts, T. J., Tsanev, V., and Kyle, P. R.: On bromine, nitrogen oxides and ozone depletion in the tropospheric plume of Erebus volcano (Antarctica), Atmos. Environ., 45, 3856-3866, 2011.
9. Breider, T. J., Chipperfield, M. P., Richards, N. A. D., Carslaw, K. S., Mann, G. W., and Spracklen, D. V.: Impact of BrO on dimethylsulfide in the remote marine boundary layer, Geophys. Res. Lett., 37, L02807, doi10.1029 2009GL040868, 2010.
10. Carslaw, K. S., Clegg, S. L., and Brimblecombe, P.: A thermodynamic model of the system HCl-HNO 3 sub-H 2 sub SO 4 sub-H 2 sub O, including solubilities of HBr, from 200 K to 328 K, J. Phys. Chem., 99, 11557-11574, 1995.
11. Clegg, S. L., Brimblecombe, P., and Wexler, A. S.: A thermodynamic model of the system H sup-NH 4 sup + sup-Na sup-SO 4 sup 2-sup-NO 3 sup-sup-Cl sup-sup-H 2 sub O at 298.15 K, J. Phys. Chem. A, 102, 2155-2171, 1998.
12. Eigen, M. and Kustin, K.: The Kinetics of Halogen Hydrolysis, J. Am. Chem. Soc., 84, 1355-1361, doi10.1021 ja00867a005, 1962.
13. Fickert, S., Adams, J. W., and Crowley, J. N.: Activation of Br 2 sub and BrCl via uptake of HOBr onto aqueous salt solutions, J. Geophys. Res., 104, 23719-23727, 1999.
14. Frenzel, A., Scheer, V., Sikorski, R., George, C., Behnke, W., and Zetzsch, C.: Heterogenerous Interconversion Reactions of BrNO 2 sub ClNO 2 sub Br 2 sub and Cl 2 sub J. Phys. Chem. A, 102, 1329-1337, 1998.
15. Gerritsen, C. M. and Margarem, D. W.: Non-Metal Redox Kinetics: Hypochlorite and Hypochlorous Acid Reactions with Cyanide, Inorg. Chem., 29, 2757-2762, 1990.
16. Hebestreit, K., Stutz, J., Rosen, D., Matveiv, V., Peleg, M., Luria, M., and Platt, U.: DOAS measurements of tropospheric bromine oxide in mid-latitudes, Science, 283, 55-57, 1999.
17. Iraci, L. T., Michelsen, R. R., Ashbourn, S. F. M., Rammer, T. A., and Golden, D. M.: Uptake of hypobromous acid (HOBr) by aqueous sulfuric acid solutions: low-temperature solubility and reaction, Atmos. Chem. Phys., 5, 1577-1587, doi10.5194 acp-5-1577-2005, 2005.
18. IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation, http: iupac.pole-ether.fr (last access: August 2014), 1999-2014.
19. Liu, Q. and Magarem, D. W.: Equilibrium and Kinetics of Bromine, Environ. Sci. Technol., 35, 1127-1133, 2001.
20. Keene, W. C., Pszenny, A. A. P., Maben, J. R., and Sander, R.: Variation of marine aerosol acidity with particle size, Geophys. Res. Lett., 29, 1101, doi10.1029 2001GL013881, 2002.
21. Keene, W. C., Long, M. S., Pszenny, A. A. P., Sander, R., Maben, J. R., Wall, A. J., O'Halloran, T. L., Kerkweg, A., Fischer, E. V., and Schrems, O.: Latitudinal variation in the multiphase chemical processing of inorganic halogens and related species over the eastern North and South Atlantic Oceans, Atmos. Chem. Phys., 9, 7361-7385, doi10.5194 acp-9-7361-2009, 2009.
22. Kelly, P. J., Kern, C., Roberts, T. J., Lopez, T., Werner, C., and Aiuppa, A.: Rapid chemical evolution of tropospheric volcanic emissions from Redoubt Volcano, Alaska, based on observations of ozone and halogen-containing gases, J. Volcanol. Geoth. Res., 259, 317-333, 2013.
23. Klassen, J. K., Hu, Z., and Williams, L. R.: Diffusion coefficients for HCl and HBr in 30 wt % to 72 wt % sulfuric acid at temperatures between 220 and 300 K, J. Geophys. Res., 103, 16197-16202, 1998.
24. Kumar, K. and Margarem, D. W.: Kinetics and Mechanism of General-Acid-Assisted Oxidation of Bromide by Hypochlorite and Hypochlorous Acid, Inorg. Chem., 26, 2706-2711, 1987.
25. Nagy, J. C., Kumar, K., and Margarem, D. W.: Non-Metal Redox Kinetics: Oxidation of Iodide by Hypochlorous Acid and by Nitrogen Trichloride Measured by the Pulsed-Accelerated-Flow Method, Inorg. Chem., 27, 2773-2780, 1988.
26. Parrella, J. P., Jacob, D. J., Liang, Q., Zhang, Y., Mickley, L. J., Miller, B., Evans, M. J., Yang, X., Pyle, J. A., Theys, N., and Van Roozendael, M.: Tropospheric bromine chemistry: implications for present and pre-industrial ozone and mercury, Atmos. Chem. Phys., 12, 6723-6740, doi10.5194 acp-12-6723-2012, 2012.
27. Pratte, P. and Rossi, M. J.: The heterogeneous kinetics of HOBr and HOCl on acidified sea salt and model aerosol at 40-90 % relative humidity and ambient temperature, Phys. Chem. Chem. Phys., 8, 3988-4001, 2006.
28. Read, K. A., Mahajan, A. S., Carpenter, L. J., Evans, M. J., Faria, B. V. E., Heard, D. E., Hopkins, J. R., Lee, L. D., Moller, S. J., Lewis, A. C., Mendes, L., McQuaid, J. B., Oetjen, H., Saiz-Lopez, A., Pilling, M. J., and Plane, J. M. C.: Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean, Nature, 453, 1232-1235, doi10.1038 nature07035, 2008.
29. Roberts, T. J., Braban, C. F., Martin, R. S., Oppenheimer, C., Adams, J. W., Cox, R. A., Jones, R. L., and Griffiths, P. T, Modelling reactive halogen formation and ozone depletion in volcanic plumes, Chem. Geol., 263, 151-163, 2009.
30. Roberts, T. J., Martin, R. S, and Jourdain, L.: Reactive halogen chemistry in Mt Etna's volcanic plume: the influence of total Br, high temperature processing, aerosol loading and plume dispersion, Atmos. Chem. Phys., in press, 2014.
31. Saiz-Lopez, A. and von Glaosw, R.: Reactive halogen chemistry in the troposphere, Chem. Soc. Rev., 41, 6448-6472, 2012.
32. Sander, R.: Compilation of Henry's Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry (Version 3), http: www.henrys-law.org (last access: November 2013), 1999.
33. Sander, R., Keene, W. C., Pszenny, A. A. P., Arimoto, R., Ayers, G. P., Baboukas, E., Cainey, J. M., Crutzen, P. J., Duce, R. A., Hönninger, G., Huebert, B. J., Maenhaut, W., Mihalopoulos, N., Turekian, V. C., and Van Dingenen, R.: Inorganic bromine in the marine boundary layer: a critical review, Atmos. Chem. Phys., 3, 1301-1336, doi10.5194 acp-3-1301-2003, 2003.
34. Sander, R., Baumgaertner, A., Gromov, S., Harder, H., Jöckel, P., Kerkweg, A., Kubistin, D., Regelin, E., Riede, H., Sandu, A., Taraborrelli, D., Tost, H., and Xie, Z.-Q.: The atmospheric chemistry box model CAABA MECCA-3.0, Geosci. Model Dev., 4, 373-380, doi10.5194 gmd-4-373-2011, 2011.
35. Smoydzin, L. and von Glasow, R.: Do organic surface films on sea salt aerosols influence atmospheric chemistry?-a model study, Atmos. Chem. Phys., 7, 5555-5567, doi10.5194 acp-7-5555-2007, 2007.
36. Schroeder, W. H., Anlauf, K. G., Barrie, L. A., Lu, J. Y., Steffen, A., Schneeberger, D. R., and Berg, T.: Arctic springtime depletion of mercury, Nature, 394, 331-332, doi10.1038 28530, 1998.
37. Seinfeld, J. H. and Pandis, S. N.: Atmospheric Chemistry and Physics-From Air Pollution to Climate Change, John Wiley & Sons, p. 440, 1998.
38. Simpson, W. R., von Glasow, R., Riedel, K., Anderson, P., Ariya, P., Bottenheim, J., Burrows, J., Carpenter, L. J., Frieß, U., Goodsite, M. E., Heard, D., Hutterli, M., Jacobi, H.-W., Kaleschke, L., Neff, B., Plane, J., Platt, U., Richter, A., Roscoe, H., Sander, R., Shepson, P., Sodeau, J., Steffen, A., Wagner, T., and Wolff, E.: Halogens and their role in polar boundary-layer ozone depletion, Atmos. Chem. Phys., 7, 4375-4418, doi10.5194 acp-7-4375-2007, 2007.
39. Vogt, R., Crutzen, P. J., and Sander, R.: A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer, Nature, 383, 327-330, 1996.
40. von Glasow, R.: Atmospheric Chemistry in Volcanic Plumes, P. Natl. Acad. Sci. USA, 107, 6594-6599, 2010.
41. von Glasow, R., Sander, R., Bott, A., and Crutzen, P. J.: Modeling halogen chemistry in the marine boundary layer 1. Cloud-free MBL, J. Geophy. Res., 107, 4341, doi10.1029 2001JD000942, 2002.
42. von Glasow, R., von Kuhlmann, R., Lawrence, M. G., Platt, U., and Crutzen, P. J.: Impact of reactive bromine chemistry in the troposphere, Atmos. Chem. Phys., 4, 2481-2497, doi10.5194 acp-4-2481-2004, 2004.
43. Wachsmuth, M., Gäggeler, H. W., von Glasow, R., and Ammann, M.: Accommodation coefficient of HOBr on deliquescent sodium bromide aerosol particles, Atmos. Chem. Phys., 2, 121-131, doi10.5194 acp-2-121-2002, 2002.
44. Wang, T. X. and Margarem, D. W.: Kinetics of Reversible Chlorine Hydrolysis: Temperature Dependence and General-Acid Base-Assisted Mechanisms, Inorg. Chem., 33, 1050-1055, 1994.
45. Wang, T. X., Kelley, M. D., Cooper, J. N., Beckwith, R. C., and Margerum, D. W.: Equilibrium, kinetic, and UV-spectral characteristics of aqueous bromine chloride, bromine, and chlorine species, Inorg. Chem., 33, 5872-5878, 1994.
46. Wexler, A. S. and Clegg, S. L.: Atmospheric aerosol models for systems including the ions H sup NH 4 sup SO 4 sup 2-sup NO 3 sup-sup Cl sup-sup Br sup-sup and H 2 sub O, J. Geophys. Res., 107, 4207-4220, 2002.
47. Wilson, T. R. S.: Salinity and the major elements of sea water, in: Chemical Oceanography, 1, 2 Edn., edited by: Riley, J. P. and Skirrow, G., Academic, Orlando FL, 365-413, 1975.
48. Yang, X., Cox, R. A., Warwick, N. J., Pyle, J. A., Carver, G. D., O'Connor, F. M., and Savage, N. H.: Tropospheric bromine chemistry and its impacts on ozone: A model study, J. Geophys. Res., 110, D23311, doi10.1029 2005JD006244, 2005.